trimethylsilyl 2-chloroacetate

Modify Date: 2024-01-03 12:59:34

trimethylsilyl 2-chloroacetate Structure
trimethylsilyl 2-chloroacetate structure
Common Name trimethylsilyl 2-chloroacetate
CAS Number 18293-71-5 Molecular Weight 166.67800
Density 1.053 g/mL at 20ºC(lit.) Boiling Point 57-58ºC/14 mmHg
Molecular Formula C5H11ClO2Si Melting Point N/A
MSDS N/A Flash Point 52ºC

 Names

Name trimethylsilyl 2-chloroacetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.053 g/mL at 20ºC(lit.)
Boiling Point 57-58ºC/14 mmHg
Molecular Formula C5H11ClO2Si
Molecular Weight 166.67800
Flash Point 52ºC
Exact Mass 166.02200
PSA 26.30000
LogP 1.60330
Vapour Pressure 2.56mmHg at 25°C
Index of Refraction n20/D 1.424

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases 10-36/37/38
Safety Phrases 16-26-27-36/37/39
RIDADR UN 2924
Packaging Group III
Hazard Class 3.2
HS Code 2931900090

 Synthetic Route

~66%

trimethylsilyl 2-chloroacetate Structure

trimethylsilyl ...

CAS#:18293-71-5

Literature: Akita, Munetaka; Kakinuma, Noboru; Moro-oka, Yoshihiko Journal of Organometallic Chemistry, 1988 , vol. 348, p. 91 - 94

~90%

trimethylsilyl 2-chloroacetate Structure

trimethylsilyl ...

CAS#:18293-71-5

Literature: Verboom, W.; Visser, G. W.; Reinhoudt, D. N. Synthesis, 1981 , # 10 p. 807 - 809

~65%

trimethylsilyl 2-chloroacetate Structure

trimethylsilyl ...

CAS#:18293-71-5

Literature: Matsumoto, Hideyuki; Hoshino, Yoshikazu; Nakabayashi, Jiro; Nakano, Taichi; Nagai, Yoichiro Chemistry Letters, 1980 , p. 1475 - 1478

~%

trimethylsilyl 2-chloroacetate Structure

trimethylsilyl ...

CAS#:18293-71-5

Literature: Gmelin Handbook: Si: MVol.C, 69, page 190 - 194

~84%

trimethylsilyl 2-chloroacetate Structure

trimethylsilyl ...

CAS#:18293-71-5

Detail
Literature: Bourgeois, Paul; Duffaut, Norbert Bulletin de la Societe Chimique de France, 1980 , vol. 2, # 3-4 p. 195 - 199

~%

trimethylsilyl 2-chloroacetate Structure

trimethylsilyl ...

CAS#:18293-71-5

Literature: Anderson Journal of the American Chemical Society, 1952 , vol. 74, p. 2371

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Synonyms

Chloracetoxy-trimethyl-silan
Trimethylsilyl chloroacetate
chloroacetate de trimethylsilyle
Monochloressigsaeuretrimethylsilylester
Chlor-essigsaeure-trimethylsilylester
chloro-acetic acid trimethylsilanyl ester