1-Bromo-2-(bromomethyl)-4-methoxybenzene

Modify Date: 2024-01-02 13:36:16

1-Bromo-2-(bromomethyl)-4-methoxybenzene Structure
1-Bromo-2-(bromomethyl)-4-methoxybenzene structure
Common Name 1-Bromo-2-(bromomethyl)-4-methoxybenzene
CAS Number 19614-12-1 Molecular Weight 279.957
Density 1.8±0.1 g/cm3 Boiling Point 299.6±25.0 °C at 760 mmHg
Molecular Formula C8H8Br2O Melting Point 90-94ºC(lit.)
MSDS USA Flash Point 120.3±21.7 °C
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 1-bromo-2-(bromomethyl)-4-methoxybenzene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.8±0.1 g/cm3
Boiling Point 299.6±25.0 °C at 760 mmHg
Melting Point 90-94ºC(lit.)
Molecular Formula C8H8Br2O
Molecular Weight 279.957
Flash Point 120.3±21.7 °C
Exact Mass 277.894165
PSA 9.23000
LogP 3.87
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.584

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C: Corrosive;
Risk Phrases 34
Safety Phrases 26-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3.0
Hazard Class 8.0
HS Code 2909309090

 Synthetic Route

~88%

1-Bromo-2-(bromomethyl)-4-methoxybenzene Structure

1-Bromo-2-(brom...

CAS#:19614-12-1

Literature: Tetrahedron, , vol. 60, # 49 p. 11075 - 11087 Journal of the American Chemical Society, , vol. 127, # 29 p. 10124 - 10125

~59%

1-Bromo-2-(bromomethyl)-4-methoxybenzene Structure

1-Bromo-2-(brom...

CAS#:19614-12-1

Literature: EP1466901 A1, ; Page 25 ; EP 1466901 A1

~55%

1-Bromo-2-(bromomethyl)-4-methoxybenzene Structure

1-Bromo-2-(brom...

CAS#:19614-12-1

Literature: Journal of Medicinal Chemistry, , vol. 49, # 15 p. 4721 - 4736

~10%

1-Bromo-2-(bromomethyl)-4-methoxybenzene Structure

1-Bromo-2-(brom...

CAS#:19614-12-1

Literature: Journal of Organic Chemistry, , vol. 68, # 13 p. 5193 - 5197

~94%

1-Bromo-2-(bromomethyl)-4-methoxybenzene Structure

1-Bromo-2-(brom...

CAS#:19614-12-1

Literature: Journal of Organic Chemistry, , vol. 66, # 19 p. 6286 - 6290

~%

1-Bromo-2-(bromomethyl)-4-methoxybenzene Structure

1-Bromo-2-(brom...

CAS#:19614-12-1

Literature: Tetrahedron Letters, , vol. 45, # 37 p. 6941 - 6945

~%

1-Bromo-2-(bromomethyl)-4-methoxybenzene Structure

1-Bromo-2-(brom...

CAS#:19614-12-1

Literature: Journal of Medicinal Chemistry, , vol. 49, # 15 p. 4721 - 4736

~%

1-Bromo-2-(bromomethyl)-4-methoxybenzene Structure

1-Bromo-2-(brom...

CAS#:19614-12-1

Literature: Tetrahedron Letters, , vol. 45, # 37 p. 6941 - 6945

 Customs

HS Code 2909309090
Summary 2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Synonyms

Benzene, 1-bromo-2-(bromomethyl)-4-methoxy-
4-Bromo-3-(bromomethyl)anisole
5-methoxy-2-bromo-benzyl bromide
1-bromo-2-bromomethyl-4-methoxybenzene
4-bromo-3-(bromomethyl)-1-methoxybenzene
2-bromo-3-methoxybenzyl bromide
2-Bromo-5-Methoxybenzyl Bromide
MFCD00078664
4-Bromo-3-bromomethyl anisole
2-bromo-1-bromomethyl-5-methoxybenzene
1-Bromo-2-(bromomethyl)-4-methoxybenzene
4-Bromo-3-(bromomethyl)phenyl methyl ether
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