1-Bromobenzocyclobutene

Modify Date: 2024-01-03 20:08:12

1-Bromobenzocyclobutene Structure
1-Bromobenzocyclobutene structure
Common Name 1-Bromobenzocyclobutene
CAS Number 21120-91-2 Molecular Weight 181.02900
Density 1.45 g/mL at 25ºC(lit.) Boiling Point 90ºC10.5 mm Hg(lit.)
Molecular Formula C8H5Br Melting Point N/A
MSDS Chinese USA Flash Point 205 °F

 Names

Name 7-bromobicyclo[4.2.0]octa-1,3,5-triene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.45 g/mL at 25ºC(lit.)
Boiling Point 90ºC10.5 mm Hg(lit.)
Molecular Formula C8H5Br
Molecular Weight 181.02900
Flash Point 205 °F
Exact Mass 179.95700
LogP 2.89300
Vapour Pressure 0.168mmHg at 25°C
Index of Refraction n20/D 1.59(lit.)

 Safety Information

Personal Protective Equipment Eyeshields;Gloves
Hazard Codes Xi
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2903890090

 Synthetic Route

~6%

1-Bromobenzocyclobutene Structure

1-Bromobenzocyc...

CAS#:21120-91-2

Literature: VANDERBILT UNIVERSITY Patent: WO2008/24435 A2, 2008 ; Location in patent: Page/Page column 104 ;

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1-Bromobenzocyclobutene Structure

1-Bromobenzocyc...

CAS#:21120-91-2

Literature: Chemische Berichte, , vol. 91, p. 430,436 Journal of the American Chemical Society, , vol. 80, p. 2255

~25%

1-Bromobenzocyclobutene Structure

1-Bromobenzocyc...

CAS#:21120-91-2

Literature: DeCamp, Mark R.; Viscogliosi, Lori A. Journal of Organic Chemistry, 1981 , vol. 46, # 19 p. 3918 - 3920

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1-Bromobenzocyclobutene Structure

1-Bromobenzocyc...

CAS#:21120-91-2

Literature: Journal of the American Chemical Society, , vol. 80, p. 2255

~40%

1-Bromobenzocyclobutene Structure

1-Bromobenzocyc...

CAS#:21120-91-2

Literature: Barton, John W.; Shepherd, Michael K. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 1561 - 1566

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1-Bromobenzocyclobutene Structure

1-Bromobenzocyc...

CAS#:21120-91-2

Literature: Australian Journal of Chemistry, , vol. 29, p. 1685 - 1697

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1-Bromobenzocyclobutene Structure

1-Bromobenzocyc...

CAS#:21120-91-2

Literature: Australian Journal of Chemistry, , vol. 29, p. 1685 - 1697

~%

1-Bromobenzocyclobutene Structure

1-Bromobenzocyc...

CAS#:21120-91-2

Literature: Australian Journal of Chemistry, , vol. 29, p. 1685 - 1697

 Customs

HS Code 2903890090
Summary 2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

 Articles4

More Articles
Naphthalenes, isoquinolines, and a benzazocine from zirconocene-copper-mediated coupling of benzocyclobutadiene with nitriles and alkynes.

Org. Lett. 5(6) , 877-9, (2003)

[reaction: see text] Commercially available 1-bromobenzocyclobutene is a potentially useful synthon particularly with the application of organometallic methodology. Here we show that it is readily con...

Condensed Cyclobutane Aromatic Compounds. IX. Benzocyclobutenol and Benzocyclobutenone. Cava MP and Muth K.

J. Am. Chem. Soc. 82(3) , 652-54, (1960)

1-Bromobenzocyclobutene: a convenient entry into the benzocyclobutene ring system. DeCamp MR and Viscogliosi LA.

J. Org. Chem. 46(19) , 3918-20, (1981)

 Synonyms

Benzocyclobutenyl bromide
1-bromo-1,2-dihydro-cyclobutabenzene
AC-154
1-Bromobenzocyclobutene
MFCD00799491
1-bromocyclobutabenzene
Bicyclo[4.2.0]octa-1,3,5-triene,7-bromo
1-bromo-1,2-dihydrobenzocyclobutene
1-bromobenzocyclobutane