4-Chlorphenyl-2,4,5-trichlorphenylsulfid

Modify Date: 2024-01-04 20:39:47

4-Chlorphenyl-2,4,5-trichlorphenylsulfid Structure
4-Chlorphenyl-2,4,5-trichlorphenylsulfid structure
Common Name 4-Chlorphenyl-2,4,5-trichlorphenylsulfid
CAS Number 2227-13-6 Molecular Weight 324.05
Density 1.6±0.1 g/cm3 Boiling Point 408.1±45.0 °C at 760 mmHg
Molecular Formula C12H6Cl4S Melting Point N/A
MSDS Chinese USA Flash Point 185.9±25.9 °C
Symbol GHS07
GHS07
Signal Word Warning

 Use of 4-Chlorphenyl-2,4,5-trichlorphenylsulfid


Tetrasul is an acaricide. Tetrasul inhibits Tetranychus urticae and aphids on hops. Tetrasul has also been used in research of erythematous (type one) rosacea[1].

 Names

Name tetrasul
Synonym More Synonyms

 4-Chlorphenyl-2,4,5-trichlorphenylsulfid Biological Activity

Description Tetrasul is an acaricide. Tetrasul inhibits Tetranychus urticae and aphids on hops. Tetrasul has also been used in research of erythematous (type one) rosacea[1].
Related Catalog
Target

Tetranychus urticae and aphids[1].

References

[1]. Cone W W. Two-Spotted Spider Mite and Hop Aphid Control on Cluster Hops with Acaricides. J Econ Entomol. 1968, 61(6): 1685-1689.

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 408.1±45.0 °C at 760 mmHg
Molecular Formula C12H6Cl4S
Molecular Weight 324.05
Flash Point 185.9±25.9 °C
Exact Mass 321.894440
PSA 25.30000
LogP 7.27
Vapour Pressure 0.0±0.9 mmHg at 25°C
Index of Refraction 1.679

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WQ3850000
CHEMICAL NAME :
Sulfide, p-chlorophenyl 2,4,5-trichlorophenyl
CAS REGISTRY NUMBER :
2227-13-6
BEILSTEIN REFERENCE NO. :
1884271
LAST UPDATED :
199612
DATA ITEMS CITED :
19
MOLECULAR FORMULA :
C12-H6-Cl4-S
MOLECULAR WEIGHT :
324.04
WISWESSER LINE NOTATION :
GR DSR BG DG EG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3960 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
BESAAT Bulletin of the Entomological Society of America. (Entomological Soc. of America, 4603 Calvert Rd., College Park, MD 20740) V.1- 1955- Volume(issue)/page/year: 15,129,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>6810 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,63,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5010 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,495,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>6810 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,63,1973
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1350 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,63,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
SPEADM Special Publication of the Entomological Society of America. (4603 Calvert Rd., College Park, MD 20740) Volume(issue)/page/year: 78-1,55,1978
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,63,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
8200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976 Volume(issue)/page/year: -,-,1971/1976
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
550 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity)
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,63,1973 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
406000 mg/kg/116W-C
TOXIC EFFECTS :
Liver - changes in liver weight Endocrine - thyroid weight (goiter) Endocrine - changes in thyroid weight
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,63,1973
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4200 mg/kg/12W-C
TOXIC EFFECTS :
Liver - other changes Liver - changes in liver weight Endocrine - changes in thyroid weight
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,113,1973
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2016 mg/kg/12W-C
TOXIC EFFECTS :
Liver - other changes Liver - changes in liver weight Endocrine - changes in thyroid weight
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,103,1973
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2520 mg/kg/12W-C
TOXIC EFFECTS :
Liver - changes in liver weight Endocrine - changes in thyroid weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,103,1973
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - pig
DOSE/DURATION :
3444 mg/kg/12W-C
TOXIC EFFECTS :
Liver - changes in liver weight Endocrine - changes in thyroid weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,103,1973
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
5040 mg/kg/12W-C
TOXIC EFFECTS :
Liver - other changes Liver - changes in liver weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,103,1973
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
14700 mg/kg/12W-C
TOXIC EFFECTS :
Liver - changes in liver weight Endocrine - changes in thyroid weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,103,1973 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
18 gm/kg
SEX/DURATION :
male 17 week(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - testes, epididymis, sperm duct Reproductive - Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females)
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,63,1973
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
18 gm/kg
SEX/DURATION :
female 17 week(s) pre-mating
TOXIC EFFECTS :
Reproductive - Maternal Effects - ovaries, fallopian tubes Reproductive - Fertility - female fertility index (e.g. # females pregnant per # sperm positive females; # females pregnant per # females mated)
REFERENCE :
TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 1,63,1973 *** REVIEWS *** TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 56,107,1975

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H312-H412
Precautionary Statements P273-P280
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn: Harmful;
Risk Phrases R21
Safety Phrases S36
RIDADR NONH for all modes of transport
RTECS WQ3850000
HS Code 2930909090

 Synthetic Route

~%

4-Chlorphenyl-2,4,5-trichlorphenylsulfid Structure

4-Chlorphenyl-2...

CAS#:2227-13-6

Literature: Chemosphere, , vol. 38, # 15 p. 3529 - 3539

~%

4-Chlorphenyl-2,4,5-trichlorphenylsulfid Structure

4-Chlorphenyl-2...

CAS#:2227-13-6

Literature: Chemosphere, , vol. 38, # 15 p. 3529 - 3539

~%

4-Chlorphenyl-2,4,5-trichlorphenylsulfid Structure

4-Chlorphenyl-2...

CAS#:2227-13-6

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 80, p. 1057 - 1065

~%

4-Chlorphenyl-2,4,5-trichlorphenylsulfid Structure

4-Chlorphenyl-2...

CAS#:2227-13-6

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 80, p. 1057 - 1065

~%

4-Chlorphenyl-2,4,5-trichlorphenylsulfid Structure

4-Chlorphenyl-2...

CAS#:2227-13-6

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 77, p. 103,112, 114

~%

4-Chlorphenyl-2,4,5-trichlorphenylsulfid Structure

4-Chlorphenyl-2...

CAS#:2227-13-6

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 77, p. 103,112, 114

~%

4-Chlorphenyl-2,4,5-trichlorphenylsulfid Structure

4-Chlorphenyl-2...

CAS#:2227-13-6

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 77, p. 103,112, 114

~%

4-Chlorphenyl-2,4,5-trichlorphenylsulfid Structure

4-Chlorphenyl-2...

CAS#:2227-13-6

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 80, p. 1057 - 1065

~%

4-Chlorphenyl-2,4,5-trichlorphenylsulfid Structure

4-Chlorphenyl-2...

CAS#:2227-13-6

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 77, p. 103,112, 114

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

4-Chlorphenyl-2,4,5-trichlorphenylsulfid
Animert V-101
Benzene, 1,2,4-trichloro-5-[(4-chlorophenyl)thio]-
p-chlorophenyl-2,4,5-trichlorophenylsulphide [Tetrasul]
EINECS 218-761-4
1,2,4-trichloro-5-(4-chlorophenyl)sulfanylbenzene
1,2,4-trichloro-5-[(4-chlorophenyl)thio]benzene
MFCD00018649
1,2,4-Trichloro-5-[(4-chlorophenyl)sulfanyl]benzene
(4-Chlor-phenyl)-(2,4,5-trichlor-phenyl)-sulfid
Caswell No. 213
Animert
2,4,4',5-TETRACHLORODIPHENYL SULFIDE
TETRASUL
diphenylsulphide
Philips-duphar V-101
2,4,5-Trichlorophenyl 4-chlorophenyl sulfide
Tetrasul [BSI:ISO]
4-Chlorophenyl 2,4,5-trichlorophenyl sulfide
(4-chloro-phenyl)-(2,4,5-trichloro-phenyl)-sulfide
Animert V-10K
Animert V-10
tetradisul
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