tert-Butyl 3-(hydroxymethyl)benzylcarbamate

Modify Date: 2024-01-09 17:22:15

tert-Butyl 3-(hydroxymethyl)benzylcarbamate Structure
tert-Butyl 3-(hydroxymethyl)benzylcarbamate structure
Common Name tert-Butyl 3-(hydroxymethyl)benzylcarbamate
CAS Number 226070-69-5 Molecular Weight 237.295
Density 1.1±0.1 g/cm3 Boiling Point 395.7±30.0 °C at 760 mmHg
Molecular Formula C13H19NO3 Melting Point 51ºC
MSDS N/A Flash Point 193.1±24.6 °C

 Names

Name tert-butyl N-[[3-(hydroxymethyl)phenyl]methyl]carbamate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 395.7±30.0 °C at 760 mmHg
Melting Point 51ºC
Molecular Formula C13H19NO3
Molecular Weight 237.295
Flash Point 193.1±24.6 °C
Exact Mass 237.136490
PSA 58.56000
LogP 1.71
Vapour Pressure 0.0±1.0 mmHg at 25°C
Index of Refraction 1.529
Storage condition 2-8°C

 MSDS

Name: (3-Hydroxymethyl-benzyl)-carbamic acid tert-butyl ester Material Safety Data Sheet
Synonym: none know
CAS: 226070-69-5
Section 1 - Chemical Product MSDS Name:(3-Hydroxymethyl-benzyl)-carbamic acid tert-butyl ester Material Safety Data Sheet
Synonym:none know

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
226070-69-5 (3-Hydroxymethyl-benzyl)-carbamic acid 97+% unlisted
Hazard Symbols: XN
Risk Phrases: 20/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Section 7 - HANDLING and STORAGE
Handling:
Use with adequate ventilation. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 226070-69-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: White
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 39 - 41 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C13H19NO3
Molecular Weight: 237.3

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 226070-69-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(3-Hydroxymethyl-benzyl)-carbamic acid tert-butyl ester - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 226070-69-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 226070-69-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 226070-69-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases 20/22-36/37/38
Safety Phrases 22-26-36/37/39
HS Code 2924299090

 Synthetic Route

 Customs

HS Code 2924299090
Summary 2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

(3-Hydroxymethyl-benzyl)-carbamic acid tert-butyl ester
(3-tert-butoxycarbonylaminomethylphenyl)methanol
2-Methyl-2-propanyl [3-(hydroxymethyl)benzyl]carbamate
3-tert-butoxycarbonylaminomethylbenzyl alcohol
Carbamic acid, N-[[3-(hydroxymethyl)phenyl]methyl]-, 1,1-dimethylethyl ester
tert-Butyl 3-(hydroxymethyl)benzylcarbamate
1,1-dimethylethyl {[3-(hydroxymethyl)phenyl]methyl}carbamate
tert-butyl N-{[3-(hydroxymethyl)phenyl]methyl}carbamate
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