(Aminooxy)(trimethyl)silane

Modify Date: 2024-01-02 09:10:56

(Aminooxy)(trimethyl)silane Structure
(Aminooxy)(trimethyl)silane structure
Common Name (Aminooxy)(trimethyl)silane
CAS Number 22737-36-6 Molecular Weight 105.211
Density 0.9±0.1 g/cm3 Boiling Point 99.0±0.0 °C at 760 mmHg
Molecular Formula C3H11NOSi Melting Point N/A
MSDS Chinese USA Flash Point 8.9±0.0 °C
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

 Use of (Aminooxy)(trimethyl)silane




 Names

Name O-trimethylsilylhydroxylamine
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 99.0±0.0 °C at 760 mmHg
Molecular Formula C3H11NOSi
Molecular Weight 105.211
Flash Point 8.9±0.0 °C
Exact Mass 105.060989
PSA 35.25000
LogP 1.11
Vapour Pressure 39.0±0.1 mmHg at 25°C
Index of Refraction 1.399
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger
Hazard Statements H225-H314
Precautionary Statements P210-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable;C:Corrosive;
Risk Phrases R11;R34
Safety Phrases S16-S26-S36/37/39-S45
RIDADR UN 2733 3/PG 2
WGK Germany 3
Packaging Group II
Hazard Class 3.1
HS Code 2931900090

 Synthetic Route

~80%

(Aminooxy)(trimethyl)silane Structure

(Aminooxy)(trim...

CAS#:22737-36-6

Literature: Synthetic Communications, , vol. 15, # 14 p. 1333 - 1336

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(Aminooxy)(trimethyl)silane Structure

(Aminooxy)(trim...

CAS#:22737-36-6

Literature: Journal of the American Chemical Society, , vol. 95, p. 3987 - 3994

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(Aminooxy)(trimethyl)silane Structure

(Aminooxy)(trim...

CAS#:22737-36-6

Literature: Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, , vol. 270, p. 240 - 242

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(Aminooxy)(trimethyl)silane Structure

(Aminooxy)(trim...

CAS#:22737-36-6

Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 11 p. 2699 - 2704

 Preparation


 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles2

More Articles
Trimethylsilyl chloride promoted synthesis of α-branched amines by nucleophilic addition of organozinc halides to nitrones.

Org. Biomol. Chem. 10(38) , 7669-72, (2012)

A general procedure for the nucleophilic addition of organozinc halides with nitrones in the presence of trimethylsilyl chloride has been developed. Trimethylsilyl chloride was found to be both an ind...

Chemoselective addition of organometallics to oxime ethers. Tavakol H,et al.

J. Organomet. Chem. 692(10) , 1924-27, (2007)

 Synonyms

Silane, (aminooxy)trimethyl-
O-(Trimethylsilyl)hydroxylamine
(Aminooxy)(trimethyl)silane
Aminoxytrimethylsilane
0-Trimethylsilylhydroxylamine
trimethylsiloxyamine
trimethylsilyloxy amine
MFCD00010872