Triallate

Modify Date: 2024-01-03 09:22:09

Triallate Structure
Triallate structure
Common Name Triallate
CAS Number 2303-17-5 Molecular Weight 304.664
Density 1.3±0.1 g/cm3 Boiling Point 322.1±52.0 °C at 760 mmHg
Molecular Formula C10H16Cl3NOS Melting Point 29-30°C
MSDS Chinese USA Flash Point 148.6±30.7 °C
Symbol GHS07 GHS08 GHS09
GHS07, GHS08, GHS09
Signal Word Warning

 Use of Triallate


Triallate is a selective preemergence herbicide for the control of wild oats in barley, spring wheat, Durum wheat, winter wheat, and sugar beets. Triallate inhibits fatty acid elongation and surface lipid (wax) biosynthesis[1][2].

 Names

Name tri-allate
Synonym More Synonyms

 Triallate Biological Activity

Description Triallate is a selective preemergence herbicide for the control of wild oats in barley, spring wheat, Durum wheat, winter wheat, and sugar beets. Triallate inhibits fatty acid elongation and surface lipid (wax) biosynthesis[1][2].
Related Catalog
References

[1]. Charles E Healy, et al. A Review of the Genotoxicity of Triallate. Int J Toxicol. May-Jun 2003;22(3):233-51.

[2]. Roberto Busi, et al. Cross-resistance to Prosulfocarb and Triallate in Pyroxasulfone-Resistant Lolium Rigidum. Pest Manag Sci. 2013 Dec;69(12):1379-84.

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 322.1±52.0 °C at 760 mmHg
Melting Point 29-30°C
Molecular Formula C10H16Cl3NOS
Molecular Weight 304.664
Flash Point 148.6±30.7 °C
Exact Mass 303.001831
PSA 45.61000
LogP 6.18
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.532
Water Solubility 4.0 g/mL

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
EZ8575000
CHEMICAL NAME :
Carbamic acid, diisopropylthio-, S-(2,3,3-trichloroallyl) ester
CAS REGISTRY NUMBER :
2303-17-5
LAST UPDATED :
199701
DATA ITEMS CITED :
25
MOLECULAR FORMULA :
C10-H16-Cl3-N-O-S
MOLECULAR WEIGHT :
304.68
WISWESSER LINE NOTATION :
GYGUYG1SVNY1&1&Y1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1471 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
930 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - excitement Behavioral - muscle contraction or spasticity
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
832 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
>20 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - cat
DOSE/DURATION :
400 mg/m3/4H
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal)
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2225 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
2251 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
17493 mg/kg/17W-I
TOXIC EFFECTS :
Related to Chronic Data - death
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
40 mg/m3/4H/17W-I
TOXIC EFFECTS :
Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol)

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
20 umol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 85,45,1981 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

 Safety Information

Symbol GHS07 GHS08 GHS09
GHS07, GHS08, GHS09
Signal Word Warning
Hazard Statements H302-H317-H373-H410
Precautionary Statements P273-P280-P501
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xn: Harmful;N: Dangerous for the environment;
Risk Phrases R22;R43;R48/22;R50/53
Safety Phrases S24-S37-S60-S61-S36-S26-S16
RIDADR UN 3077
RTECS EZ8575000
Packaging Group I; II; III
Hazard Class 6.1
HS Code 2930200013

 Synthetic Route

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Triallate Structure

Triallate

CAS#:2303-17-5

Literature: Synthesis, , # 8 p. 622 - 623

 Customs

HS Code 2930200013
Summary 2930200013 (z)-s-(2,3-dichloroallyl) diisopropylcarbamothioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

 Articles25

More Articles
Carry-over of dinitramine, triallate, and trifluralin to the following spring in soils treated at different times during the fall.

Bull. Environ. Contam. Toxicol. 29(4) , 483-6, (1982)

Volatilization modeling of two herbicides from soil in a wind tunnel experiment under varying humidity conditions.

Environ. Sci. Technol. 46(22) , 12527-33, (2012)

Volatilization of pesticides from the bare soil surface is drastically reduced when the soil is under dry conditions (i.e., water content lower than the permanent wilting point). This effect is caused...

Body mass index and bromoxynil exposure in a sample of rural residents during spring herbicide application.

J. Toxicol. Environ. Health A 67(17) , 1321-52, (2004)

Bromoxynil (3,5-dibromo-4-hydroxybenzonitrile), a phenolic herbicide, is widely used in production of cereals and other crops. Little is known, however, about bromoxynil exposure in humans. Results of...

 Synonyms

S-(2,3,3-trichloro-2-propen-1-yl) N,N-bis(1-methylethyl)carbamothioate
s-2,3,3-trichloroallyl diisopropylthiocarbamate
S-(2,3,3-trichloroprop-2-en-1-yl) dipropan-2-ylcarbamothioate
Triamyl
Diisopropylthiocarbamate de S-(2,3,3-trichloro-2-propèn-1-yle)
N,N-diisopropylthiocarbamic acid 2,3,3-trichloroallyl ester
S-(2,3,3-trichloroprop-2-en-1-yl) di(propan-2-yl)carbamothioate
S-(2,3,3-trichloroprop-2-enyl) N,N-di(propan-2-yl)carbamothioate
S-(2,3,3-Trichloroprop-2-en-1-yl) diisopropylcarbamothioate
Triallate
Bis(1-methylethyl)carbamothioic acid S-(2,3,3-trichloro-2-propenyl) ester
S-2,3,3-trichloroallyl diisopropyl(thiocarbamate)
MFCD00078730
S-(2,3,3-Trichloro-2-propenyl) bis(1-methylethyl)carbamothioate (9CI)
S-(2,3,3-Trichloroallyl) diisopropylthiocarbamate (8CI)
Caswell No. 870A
Far-Go
EINECS 218-962-7
S-(2,3,3-Trichlorprop-2-en-1-yl)-diisopropylthiocarbamat
Carbamothioic acid, N,N-bis(1-methylethyl)-, S-(2,3,3-trichloro-2-propen-1-yl) ester
S-(2,3,3-Trichlor-2-propen-1-yl)-diisopropylthiocarbamat
S-(2,3,3-trichloroprop-2-en-1-yl) diisopropylthiocarbamate
S-(2,3,3-Trichloro-2-propen-1-yl) diisopropylcarbamothioate
Carbamothioic acid, bis(1-methylethyl)-, S-(2,3,3-trichloro-2-propenyl) ester
Triallat
Avadex BW
S-(2,3,3-trichloroprop-2-en-1-yl) bis(1-methylethyl)thiocarbamate
S-2,3,3-trichloroallyl diisopropyl thiocarbamate
Dipthal
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