2,6-Diisopropylaniline

Modify Date: 2024-01-02 04:05:13

2,6-Diisopropylaniline Structure
2,6-Diisopropylaniline structure
 Common Name 2,6-Diisopropylaniline
CAS Number 24544-04-5 Molecular Weight 177.29
Density 0.9±0.1 g/cm3 Boiling Point 257.3±9.0 °C at 760 mmHg
Molecular Formula C12H19N Melting Point −45 °C(lit.)
MSDS Chinese USA Flash Point 123.9±0.0 °C

 Use of 2,6-Diisopropylaniline


2,6-Diisopropylaniline is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

 Names

Name 2,6-di(propan-2-yl)aniline
Synonym More Synonyms

 2,6-Diisopropylaniline Biological Activity

Description 2,6-Diisopropylaniline is a biochemical reagent that can be used as a biological material or organic compound for life science related research.
Related Catalog
In Vitro 2,6-Diisopropylaniline 用作生产碳化二亚胺稳定剂、合成树脂、抗氧化剂和药物活性成分的中间体。它还用于制备多主题席夫碱配体前体和 4,5-b is(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene。与三乙酰甲烷缩合生成-[1-(2,6-二异丙基苯基氨基)乙烯]戊烷-2,4-二酮。此外，它还用于制备 N-杂环卡宾络合物，用于无环酮的 α-芳基化、卤代芳烃的胺化和水性铃木偶联。除此之外，它还用于制备基于萘二酰亚胺的有机催化剂。

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 257.3±9.0 °C at 760 mmHg
Melting Point −45 °C(lit.)
Molecular Formula C12H19N
Molecular Weight 177.29
Flash Point 123.9±0.0 °C
Exact Mass 177.151749
PSA 26.02000
LogP 3.61
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.526
Water Solubility <0.20 g/L

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BX4025000
CHEMICAL NAME :
Aniline, 2,6-diisopropyl-
CAS REGISTRY NUMBER :
24544-04-5
BEILSTEIN REFERENCE NO. :
2208763
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C12-H19-N
MOLECULAR WEIGHT :
177.32
WISWESSER LINE NOTATION :
1Y1&R BZ CY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3204 mg/kg
TOXIC EFFECTS :
Liver - other changes Blood - changes in bone marrow (not otherwise specified) Blood - changes in spleen
REFERENCE :
FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 3,285,1983 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4005 mg/kg/5D-C
TOXIC EFFECTS :
Liver - changes in liver weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 3,285,1983

 Safety Information

Hazard Statements H412
Precautionary Statements P273
Personal Protective Equipment Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S61-S37/39-S26
RIDADR NONH for all modes of transport
WGK Germany 2
RTECS BX4025000
HS Code 29214980

 Synthetic Route

propene structure

propene

CAS#:187737-37-7
structure

CAS#:74497-02-2

~52%

2,6-Diisopropylaniline Structure

2,6-Diisopropyl...

CAS#:24544-04-5
Literature: LONZA LTD; LADNAK, Viktor; OTT, Lothar; SCHLENK, Stefan; WASSERSCHEID, Peter Patent: WO2011/12300 A1, 2011 ; Location in patent: Page/Page column 21-22; 25 ;
2,6-diisopropylcyclohexylamine structure

2,6-diisopropyl...

CAS#:71757-58-9
Palladium structure

Palladium

CAS#:7440-05-3

~93%

2,6-Diisopropylaniline Structure

2,6-Diisopropyl...

CAS#:24544-04-5
Literature: BASF Aktiengesellschaft Patent: US4429155 A1, 1984 ;
N-[2,6-di(propan-2-yl)phenyl]methanimine structure

N-[2,6-di(propa...

CAS#:60090-48-4

~0%

1,3-Diisopropylbenzene structure

1,3-Diisopropyl...

CAS#:99-62-7
2,6-Diisopropylaniline Structure

2,6-Diisopropyl...

CAS#:24544-04-5
Literature: Giumanini, Angelo G.; Verardo, Giancarlo; Gorassini, Fausto; Strazzolini, Paolo Recueil des Travaux Chimiques des Pays-Bas, 1995 , vol. 114, # 7 p. 311 - 316
N-[2,6-di(propan-2-yl)phenyl]methanimine structure

N-[2,6-di(propa...

CAS#:60090-48-4

~3%

2,6-Diisopropylaniline Structure

2,6-Diisopropyl...

CAS#:24544-04-5

2,6-diisopropyl-n,n-dimethylaniline structure

2,6-diisopropyl...

CAS#:2909-77-5
N/A structure

N/A

CAS#:103110-98-1
Literature: Journal fuer Praktische Chemie (Leipzig), , vol. 330, # 2 p. 161 - 174
N-(2,6-diisopropyl-phenyl)-3-hydroxy-picolinamide structure

N-(2,6-diisopro...

CAS#:160938-52-3

~%

2,6-Diisopropylaniline Structure

2,6-Diisopropyl...

CAS#:24544-04-5
Literature: Tetrahedron, , vol. 50, # l p. 6307 - 6332
N/A structure

N/A

CAS#:136213-18-8

~6%

2,6-Diisopropylaniline Structure

2,6-Diisopropyl...

CAS#:24544-04-5

Benzene, 2-isocyano-1,3-bis(1-methylethyl)- (9CI) structure

Benzene, 2-isoc...

CAS#:2008-61-9
2,6-di-iso-propylphenyl isocyanate structure

2,6-di-iso-prop...

CAS#:28178-42-9
Detail
Literature: Journal of Organic Chemistry, , vol. 65, # 2 p. 624 - 626
N-(dichlorosilyl)-N-(2,6-diisopropylphenyl)-1,1,1-trimethylsilanamine structure

N-(dichlorosily...

CAS#:1309944-27-1

~%

2,6-Diisopropylaniline Structure

2,6-Diisopropyl...

CAS#:24544-04-5
Literature: Organometallics, , vol. 31, # 21 p. 7339 - 7342

 Customs

HS Code 2921420090
Summary HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Articles10

More Articles
Organo-palladium(II) complexes bearing unsymmetrical N,N,N-pincer ligands: synthesis, structures and oxidatively induced coupling reactions.

Dalton Trans. 44(16) , 7230-41, (2015)

The 2-(2′-aniline)-6-imine-pyridines, 2-(C6H4-2′-NH2)-6-(CMe=NAr)C5H3N (Ar = 4-i-PrC6H4 (HL1a), 2,6-i-Pr2C6H3 (HL1b)), have been synthesised via sequential Stille cross-coupling, deprotection and cond...
O,N,N-pincer ligand effects on oxidatively induced carbon-chlorine coupling reactions at palladium.

Dalton Trans. 44(13) , 6040-51, (2015)

The syntheses of two families of sterically tuneable O,N,N pro-ligands are reported, namely the 2-(phenyl-2'-ol)-6-imine-pyridines, 2-(C6H4-2'-OH),6-(CMe=NAr)C5H3N [Ar = 4-i-PrC6H4 (HL1(a)), 2,6-i-Pr2...
Rigid NON- and NSN-ligand complexes of tetravalent and trivalent uranium: comparison of U-OAr2 and U-SAr2 bonding.

Dalton Trans. 41(26) , 8175-89, (2012)

A rigid NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene (H(2)[TXA(2)], 1) was prepared by palladium-catalyzed coupling of 2,6-diisopropylaniline with 4,...

 Synonyms

2,5-DIHYDRO-5-OXO-1-(3-TRIFLUOROMETHYLPHENYL)-1H-1,2,4-TRIAZOLE-3-CARBOXYLIC ACID DIMETHYLAMIDE
2,6-Diisopropylaniline (DIPA)
Aniline,2,6-diisopropyl
EINECS 246-305-4
2,6-Dilsopropylaniline
2,6-bis(1-methylethyl)aniline
2,6-Diisopropyl-phenylamine
2,6-bis(1-methylethyl)benzenamine
2,6-DIISOPROPYLPHENYLAMINE
MFCD00008887
2,6-(i-Pr)2PhNH2
2,6-di(propan-2-yl)aniline
(2,6-iPr2C6H3)NH2
Benzenamine, 2,6-bis(1-methylethyl)-
2,6-Diisopropylaniline
Benzenamine,2,6-bis(1-methylethyl)
2,6-di-i-propylaniline
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Related Compounds: More...
4-NO2-2,6-diisopropylaniline
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4-Chloro-2,6-diisopropylaniline
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4,4'-Methylenebis(2,6-diisopropylaniline)
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