2,6-Diisopropylaniline
2,6-Diisopropylaniline structure
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Common Name | 2,6-Diisopropylaniline | ||
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| CAS Number | 24544-04-5 | Molecular Weight | 177.29 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 257.3±9.0 °C at 760 mmHg | |
| Molecular Formula | C12H19N | Melting Point | −45 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 123.9±0.0 °C | |
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Organo-palladium(II) complexes bearing unsymmetrical N,N,N-pincer ligands: synthesis, structures and oxidatively induced coupling reactions.
Dalton Trans. 44(16) , 7230-41, (2015) The 2-(2′-aniline)-6-imine-pyridines, 2-(C6H4-2′-NH2)-6-(CMe=NAr)C5H3N (Ar = 4-i-PrC6H4 (HL1a), 2,6-i-Pr2C6H3 (HL1b)), have been synthesised via sequential Stille cross-coupling, deprotection and condensation steps from 6-tributylstannyl-2-(2-methyl-1,3-dioxo... |
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O,N,N-pincer ligand effects on oxidatively induced carbon-chlorine coupling reactions at palladium.
Dalton Trans. 44(13) , 6040-51, (2015) The syntheses of two families of sterically tuneable O,N,N pro-ligands are reported, namely the 2-(phenyl-2'-ol)-6-imine-pyridines, 2-(C6H4-2'-OH),6-(CMe=NAr)C5H3N [Ar = 4-i-PrC6H4 (HL1(a)), 2,6-i-Pr2C6H3 (HL1(b))] and the 2-(phenyl-2'-ol)-6-(amino-prop-2-yl)... |
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Rigid NON- and NSN-ligand complexes of tetravalent and trivalent uranium: comparison of U-OAr2 and U-SAr2 bonding.
Dalton Trans. 41(26) , 8175-89, (2012) A rigid NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene (H(2)[TXA(2)], 1) was prepared by palladium-catalyzed coupling of 2,6-diisopropylaniline with 4,5-dibromo-2,7-di-tert-butyl-9,9-dimethylthioxanthene. Depro... |
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Nickel-NHC-catalyzed alpha-arylation of acyclic ketones and amination of haloarenes and unexpected preferential N-arylation of 4-aminopropiophenone.
J. Org. Chem. 72 , 5069, (2007) Arylation of both acyclic ketones and primary and secondary amines was achieved using a new, simple, stable, and easy-to-access nickel(II)-halide complex bearing mixed PPh3/N-heterocyclic carbene ligands as a catalyst precursor. Acyclic ketones were first ary... |
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Sulfonated N-heterocyclic carbenes for Suzuki coupling in water.
Chem. Commun. (Camb.) , 2870, (2007) Sulfonated, water-soluble imidazolium and imidazolinium salts were synthesized and the respective Pd-complexes with N,N'-bis(2,6-dialkyl-4-SO(3)(-)-phenyl)imidazol-2-ylidene and N,N'-bis(2,6-dialkyl-4-SO(3)(-)-phenyl)-4,5-dihydroimidazol-2-ylidene ligands wer... |
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Remote activation of nickel catalysts for ethylene oligomerization.
Angew. Chem. Int. Ed. Engl. 44(7) , 1108-12, (2005)
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Synthesis and catalytic activity of heterogeneous rare-earth metal catalysts coordinated with multitopic Schiff-base ligands.
Dalton Trans. 41(32) , 9682-8, (2012) Four multitopic Schiff-base ligand precursors were synthesized via condensation of 4,4'-diol-3,3'-diformyl-1,1'-diphenyl or 1,3,5-tris(4-hydroxy-5-formylphenyl)benzene with 2,6-diisopropylaniline or 2,6-dimethylaniline. Amine elimination reactions of Ln[N(SiM... |
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Addition of phenylacetylene to a magnesium complex of monoiminoacenaphtheneone (dpp-mian).
Dalton Trans. 44 , 20532-41, (2015) In the presence of formic acid, acenaphthenequinone (AQ) reacts with one molar equivalent of 2,6-diisopropylaniline in toluene to give monoiminoacenaphtheneone (3, dpp-mian) in good yield. Reduction of compound 3 with an excess of magnesium in thf results in ... |
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Reactions of Bis (alkyl) yttrium Complexes Supported by Bulky N, N Ligands with 2, 6-Diisopropylaniline and Phenylacetylene. Karpov AV, et al.
Organometallics 31(15) , 5349-5357, (2012)
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Electron-deficient naphthalene diimides as efficient planar Π-acid organocatalysts for selective oxidative C-C coupling of 2, 6-di-tert-butylphenol: A temperature effect. Ke H, et al.
J. Mol. Catal. A: Chem. 385 , 26-30, (2014)
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