(1R)-(-)-Menthyl glyoxylate hydrate

Modify Date: 2024-01-06 17:21:32

(1R)-(-)-Menthyl glyoxylate hydrate Structure
(1R)-(-)-Menthyl glyoxylate hydrate structure
 Common Name (1R)-(-)-Menthyl glyoxylate hydrate
CAS Number 26315-61-7 Molecular Weight 230.301
Density 1,182 g/cm3 Boiling Point 95-96°C 0,3mm
Molecular Formula C12H22O4 Melting Point 76-78°C
MSDS N/A Flash Point 95-96°C/0.3mm

 Names

Name (1R)-(-)-Menthyl glyoxylate hydrate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1,182 g/cm3
Boiling Point 95-96°C 0,3mm
Melting Point 76-78°C
Molecular Formula C12H22O4
Molecular Weight 230.301
Flash Point 95-96°C/0.3mm
Exact Mass 230.151810
PSA 52.60000
LogP 2.12500
Vapour Pressure 0.00344mmHg at 25°C
Index of Refraction 1.458
Storage condition 2-8℃

 Safety Information

Risk Phrases R51/53
Safety Phrases S61
RIDADR 3077
Packaging Group III
Hazard Class 9
HS Code 2918300090

 Synthetic Route

L-Menthol structure

L-Menthol

CAS#:2216-51-5

Glyoxylic acid structure

Glyoxylic acid

CAS#:298-12-4

~%

(1R)-(-)-Menthyl glyoxylate hydrate Structure

(1R)-(-)-Menthy...

CAS#:26315-61-7

Literature: RANBAXY LABORATORIES LIMITED; KSHIRSAGAR, Prakash Bhimaji; BHOGE, Satish Manohar; RICHHARIYA, Santosh; SINGH, Kaptan Patent: WO2011/107920 A1, 2011 ; Location in patent: Page/Page column 9 ;
(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 2-chloro-2-oxoacetate structure

(1R,2S,5R)-2-is...

CAS#:81529-62-6

~%

(1R)-(-)-Menthyl glyoxylate hydrate Structure

(1R)-(-)-Menthy...

CAS#:26315-61-7

Literature: Blanco, Jose M.; Caamano, Olga; Fernandez, Franco; Garcia-Mera, Xerardo; Lopez, Carmen; Rodriguez-Borges, Jose E.; Hergueta, Antonio R. Synthesis, 1998 , # 11 p. 1590 - 1592
L-Menthol structure

L-Menthol

CAS#:2216-51-5

~%

(1R)-(-)-Menthyl glyoxylate hydrate Structure

(1R)-(-)-Menthy...

CAS#:26315-61-7

Literature: Ebeling, Sabine C.; Matthies, D. Journal fuer Praktische Chemie/Chemiker-Zeitung, 1994 , vol. 336, # 3 p. 271 - 272
(-)-Menthyl hydroxyacetate structure

(-)-Menthyl hyd...

CAS#:64850-52-8

~70%

(1R)-(-)-Menthyl glyoxylate hydrate Structure

(1R)-(-)-Menthy...

CAS#:26315-61-7

Literature: Ebeling, Sabine C.; Matthies, D. Journal fuer Praktische Chemie/Chemiker-Zeitung, 1994 , vol. 336, # 3 p. 271 - 272
(1R,2S,5R)-5-Methyl-2-(1-methylethyl)cyclohexyl dihydroxy-acetate structure

(1R,2S,5R)-5-Me...

CAS#:111969-64-3

~%

(1R)-(-)-Menthyl glyoxylate hydrate Structure

(1R)-(-)-Menthy...

CAS#:26315-61-7

Literature: Blanco, Jose M.; Caamano, Olga; Fernandez, Franco; Garcia-Mera, Xerardo; Lopez, Carmen; Rodriguez-Borges, Jose E.; Hergueta, Antonio R. Synthesis, 1998 , # 11 p. 1590 - 1592
(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 2-chloro-2-oxoacetate structure

(1R,2S,5R)-2-is...

CAS#:81529-62-6

~%

(1R)-(-)-Menthyl glyoxylate hydrate Structure

(1R)-(-)-Menthy...

CAS#:26315-61-7

(1R,2S,5R)-5-Methyl-2-(1-methylethyl)cyclohexyl dihydroxy-acetate structure

(1R,2S,5R)-5-Me...

CAS#:111969-64-3

Literature: Blanco, Jose M.; Caamano, Olga; Fernandez, Franco; Garcia-Mera, Xerardo; Lopez, Carmen; Rodriguez-Borges, Jose E.; Hergueta, Antonio R. Synthesis, 1998 , # 11 p. 1590 - 1592
(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 2-(nitrooxy)acetate structure

(1R,2S,5R)-2-is...

CAS#:32815-16-0

~%

(1R)-(-)-Menthyl glyoxylate hydrate Structure

(1R)-(-)-Menthy...

CAS#:26315-61-7

Literature: Jurczak,J.; Zamojski,A. Roczniki Chemii, 1970 , vol. 44, p. 2257 - 2260
menthyl 2-bromoacetate structure

menthyl 2-bromo...

CAS#:16832-20-5

~%

(1R)-(-)-Menthyl glyoxylate hydrate Structure

(1R)-(-)-Menthy...

CAS#:26315-61-7

Literature: Jurczak,J.; Zamojski,A. Roczniki Chemii, 1970 , vol. 44, p. 2257 - 2260

 Customs

HS Code 2918300090
Summary 2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Synonyms

MFCD00792503
l-menthyl glyoxylate
(1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl oxoacetate hydrate (1:1)
Acetic acid, 2-oxo-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, hydrate (1:1)
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