TRIBUTYLPHOSPHINE SULFIDE

Modify Date: 2024-01-11 09:40:43

TRIBUTYLPHOSPHINE SULFIDE Structure
TRIBUTYLPHOSPHINE SULFIDE structure
Common Name TRIBUTYLPHOSPHINE SULFIDE
CAS Number 3084-50-2 Molecular Weight 234.38200
Density 0.906g/cm3 Boiling Point 302.1ºC at 760mmHg
Molecular Formula C12H27PS Melting Point N/A
MSDS N/A Flash Point 136.5ºC

 Names

Name tributyl(sulfanylidene)-λ5-phosphane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.906g/cm3
Boiling Point 302.1ºC at 760mmHg
Molecular Formula C12H27PS
Molecular Weight 234.38200
Flash Point 136.5ºC
Exact Mass 234.15700
PSA 41.90000
LogP 5.51680
Index of Refraction 1.467

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SZ2800000
CHEMICAL NAME :
Phosphine sulfide, tributyl-
CAS REGISTRY NUMBER :
3084-50-2
BEILSTEIN REFERENCE NO. :
1762257
LAST UPDATED :
199612
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C12-H27-P-S
MOLECULAR WEIGHT :
234.42
WISWESSER LINE NOTATION :
SP4&4&4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1119,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1119,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
930 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962

 Safety Information

Risk Phrases 36/38
WGK Germany 3
HS Code 2930909090

 Synthetic Route

~82%

TRIBUTYLPHOSPHINE SULFIDE Structure

TRIBUTYLPHOSPHI...

CAS#:3084-50-2

Literature: Ohmori, Hidenobu; Maeda, Hatsuo; Konomoto, Kohichi; Sakai, Kiyoshi; Masui, Masaichiro Chemical and Pharmaceutical Bulletin, 1987 , vol. 35, # 11 p. 4473 - 4481

~10%

TRIBUTYLPHOSPHINE SULFIDE Structure

TRIBUTYLPHOSPHI...

CAS#:3084-50-2

Literature: O'Mahoney, Caroline A.; Parkin, Ivan P.; Williams, David J.; Woollins, J. Derek Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 1179 - 1186

~%

TRIBUTYLPHOSPHINE SULFIDE Structure

TRIBUTYLPHOSPHI...

CAS#:3084-50-2

Literature: Demarcq, Michel C. Phosphorus, Sulfur and Silicon and Related Elements, 1998 , vol. 134-135, p. 307 - 320

~0%

Detail
Literature: Trofimov; Gusarova; Verkhoturova; Mikhailenko; Kazantseva; Arbuzova Russian Journal of General Chemistry, 2009 , vol. 79, # 11 p. 2453 - 2455

~%

TRIBUTYLPHOSPHINE SULFIDE Structure

TRIBUTYLPHOSPHI...

CAS#:3084-50-2

Literature: Christen; van der Linde; Hooge Recueil des Travaux Chimiques des Pays-Bas, 1959 , vol. 78, p. 161,163

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

EINECS 221-393-7
Phosphine sulfide,tributyl
Tri-n-butylphosphine sulfide
thio tri n-butylphosphine
tributylphosphane sulfide
Phosphine,tributyl-,sulfide
Tributylfosfinsulfid
Tributylphosphine sulphide
Tri-n-butylphosphinsulfid
Tributylphosphine sulfide
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