1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene

Modify Date: 2025-08-20 10:07:40

1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene Structure
1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene structure
Common Name 1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene
CAS Number 31469-15-5 Molecular Weight 174.313
Density 0.9±0.1 g/cm3 Boiling Point 137.4±0.0 °C at 760 mmHg
Molecular Formula C8H18O2Si Melting Point N/A
MSDS Chinese USA Flash Point 14.4±0.0 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name (1-methoxy-2-methylprop-1-enoxy)-trimethylsilane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 137.4±0.0 °C at 760 mmHg
Molecular Formula C8H18O2Si
Molecular Weight 174.313
Flash Point 14.4±0.0 °C
Exact Mass 174.107605
PSA 18.46000
LogP 3.27
Vapour Pressure 8.8±0.2 mmHg at 25°C
Index of Refraction 1.419
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi: Irritant;
Risk Phrases R10
Safety Phrases S16-S26-S36
RIDADR UN 3271 3/PG 3
WGK Germany 3
Packaging Group III
Hazard Class 3
HS Code 2931900090

 Synthetic Route

~85%

1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene Structure

1-Methoxy-1-(Tr...

CAS#:31469-15-5

Literature: Paquette, Leo A.; Parker, Gregory D.; Tei, Takahiro; Dong, Shuzhi Journal of Organic Chemistry, 2007 , vol. 72, # 19 p. 7124 - 7134

~83%

1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene Structure

1-Methoxy-1-(Tr...

CAS#:31469-15-5

Literature: Revis, Anthony; Hilty, Terrence K. Journal of Organic Chemistry, 1990 , vol. 55, # 9 p. 2972 - 2973

~20%

1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene Structure

1-Methoxy-1-(Tr...

CAS#:31469-15-5

Literature: Oesterle, Thomas; Simchen, Gerhard Liebigs Annalen der Chemie, 1987 , p. 687 - 692

~94%

1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene Structure

1-Methoxy-1-(Tr...

CAS#:31469-15-5

Literature: Schulz, William J.; Speier, John L. Synthesis, 1989 , # 3 p. 163 - 166

~95%

1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene Structure

1-Methoxy-1-(Tr...

CAS#:31469-15-5

Literature: Schulz, William J.; Speier, John L. Synthesis, 1989 , # 3 p. 163 - 166

~4%

1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene Structure

1-Methoxy-1-(Tr...

CAS#:31469-15-5

Detail
Literature: Tetrahedron Letters, , vol. 28, # 41 p. 4809 - 4812

~%

1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene Structure

1-Methoxy-1-(Tr...

CAS#:31469-15-5

Literature: Journal of the Chemical Society [Section] D: Chemical Communications, , p. 136 - 137

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles7

More Articles
Chiral Brønsted acid catalyzed enantioselective Mannich-type reaction.

J. Am. Chem. Soc. 129 , 6756, (2007)

Mannich-type reaction of ketene silyl acetals with aldimines proceeded catalytically by means of a phosphoric acid diester, derived from (R)-BINOL, as a chiral Brønsted acid to afford beta-amino ester...

Aldrichimica Acta 17 , 41, (1984)

Polymer J. Tokyo 26 , 169, (1994)

 Synonyms

MTDA
[(1-Methoxy-2-methylprop-1-en-1-yl)oxy](trimethyl)silane
2-methyl-1-methoxy-1-trimethylsilyloxypropene
1-Propene, 1-methoxy-2-methyl-1-(trimethylsilyloxy)-
methoxy-1-trimethylsilyloxy-2,2-dimethylethylene
1-Methoxy-1-trimethylsilyloxy-2-methyl-1-propene
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene
1-methoxy-2-methyl-1-trimethylsiloxy-1-propene
MFCD00010232
1-methoxy-1-trimethylsilyloxy-2-methylpropene
methyl trimethylsilyl dimethylketene acetal
DiMethylketene Methyl TriMethylsilyl Acetal
X1-2231 Fluid
Silane, ((1-methoxy-2-methyl-1-propenyl)oxy)trimethyl-
Silane, [(1-methoxy-2-methyl-1-propen-1-yl)oxy]trimethyl-
[(1-Methoxy-2-methyl-1-propen-1-yl)oxy](trimethyl)silane
1-Methoxy-2-methyl-1-(trimethylsilyloxy)-1-propene
1-Methoxy-1-(Trimethylsiloxy)-2-Methyl-1-Propene
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