2,2,2-Trifluoroethyl formate structure
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Common Name | 2,2,2-Trifluoroethyl formate | ||
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CAS Number | 32042-38-9 | Molecular Weight | 128.050 | |
Density | 1.3±0.1 g/cm3 | Boiling Point | 33.7±40.0 °C at 760 mmHg | |
Molecular Formula | C3H3F3O2 | Melting Point | N/A | |
MSDS | Chinese USA | Flash Point | -17.7±19.6 °C | |
Symbol |
GHS02, GHS07 |
Signal Word | Danger |
Name | 2,2,2-trifluoroethyl formate |
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Synonym | More Synonyms |
Density | 1.3±0.1 g/cm3 |
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Boiling Point | 33.7±40.0 °C at 760 mmHg |
Molecular Formula | C3H3F3O2 |
Molecular Weight | 128.050 |
Flash Point | -17.7±19.6 °C |
Exact Mass | 128.008514 |
PSA | 26.30000 |
LogP | 1.07 |
Vapour Pressure | 547.2±0.1 mmHg at 25°C |
Index of Refraction | 1.300 |
Storage condition | Flammables area |
Symbol |
GHS02, GHS07 |
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Signal Word | Danger |
Hazard Statements | H225-H302-H319 |
Precautionary Statements | P210-P305 + P351 + P338 |
Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
Hazard Codes | F,Xn |
Risk Phrases | R11 |
Safety Phrases | 26 |
RIDADR | UN 1993 3/PG 2 |
Packaging Group | II |
Hazard Class | 3.0 |
HS Code | 2915120000 |
~70% 2,2,2-Trifluoro... CAS#:32042-38-9 |
Literature: Hill, David R; Hsiao, Chi-Nung; Kurukulasuriya, Ravi; Wittenberger, Steven J Organic letters, 2002 , vol. 4, # 1 p. 111 - 113 |
~% 2,2,2-Trifluoro... CAS#:32042-38-9 |
Literature: US2002/19539 A1, ; US 20020019539 A1 |
~84% 2,2,2-Trifluoro... CAS#:32042-38-9 |
Literature: Environmental Science and Technology, , vol. 38, # 21 p. 5567 - 5576 |
~% 2,2,2-Trifluoro... CAS#:32042-38-9 |
Literature: Environmental Science and Technology, , vol. 36, # 14 p. 3118 - 3123 |
~% 2,2,2-Trifluoro... CAS#:32042-38-9 |
Literature: Chemical Physics Letters, , vol. 524, p. 32 - 37 |
~% 2,2,2-Trifluoro... CAS#:32042-38-9 |
Literature: ChemPhysChem, , vol. 14, # 16 p. 3834 - 3842 |
~% 2,2,2-Trifluoro... CAS#:32042-38-9 |
Literature: ChemPhysChem, , vol. 14, # 16 p. 3834 - 3842 |
Precursor 6 | |
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DownStream 5 | |
HS Code | 2915120000 |
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Summary | 2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0% |
2,2,2-trifluoroethyl formate: a versatile and selective reagent for the formylation of alcohols, amines, and N-hydroxylamines.
Org. Lett. 4 , 111, (2002) [reaction: see text] Treatment of a variety of alcohols, amines, and N-hydroxylamines with 2,2,2-trifluoroethyl formate gave the corresponding formylated adducts in high yields. |
Zayia's reagent |
HCOOCH2CF3 |
TFEF |
Formic Acid 2,2,2-Trifluoroethyl Ester |
Ameisensaeure-2,2,2-trifluorethylester |
Ethanol, 2,2,2-trifluoro-, formate |
2,2,2-Trifluoroethyl formate |
trifluoroethyl formate |
2,2,2-trifluoroethylformate |