2,3-Dichlorotetrahydrofuran

Modify Date: 2024-01-13 12:28:31

2,3-Dichlorotetrahydrofuran Structure
2,3-Dichlorotetrahydrofuran structure
Common Name 2,3-Dichlorotetrahydrofuran
CAS Number 3511-19-1 Molecular Weight 140.99600
Density 1,34 g/cm3 Boiling Point 63 °C / 20mmHg
Molecular Formula C4H6Cl2O Melting Point N/A
MSDS N/A Flash Point 132.7ºC

 Names

Name 2,3-dichlorooxolane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1,34 g/cm3
Boiling Point 63 °C / 20mmHg
Molecular Formula C4H6Cl2O
Molecular Weight 140.99600
Flash Point 132.7ºC
Exact Mass 139.98000
PSA 9.23000
LogP 1.57900
Index of Refraction 1.472

 MSDS


Section I.Chemical Product and Company Identification
Chemical Name 2,3-Dichlorotetrahydrofuran
Portland OR
SynonymTetrahydro-2,3-dichlorofuran
Chemical FormulaC4H6Cl2O
CAS Number3511-19-1

Section II.Composition and Information on Ingredients
Chemical NameCAS Number Percent (%)TLV/PELToxicology Data
2,3-Dichlorotetrahydrofuran3511-19-1Min. 95.0 Not available.Not available.
(GC)

Section III. Hazards Identification
Acute Health EffectsNo specific information is available in our data base regarding the toxic effects of this material for humans. However,
exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if
inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling
this compound.
CARCINOGENIC EFFECTS : Not available.
Chronic Health Effects
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY: Not available.
There is no known effect from chronic exposure to this product. Repeated or prolonged exposure to this compound is
not known to aggravate existing medical conditions.

Section IV.First Aid Measures
Eye ContactCheck for and remove any contact lenses. IMMEDIATELY flush eyes with runing water for at least 15 minutes. keeping
eyelids open. COLD water may be used. DO NOT use an eye oitment. Flush eyes with running water for a minimum of
15 minutes, occasionally lifting the upper eyelids. Seek medical attention. Treat symptomatically and supportively.
Skin ContactAfter contact with skin, wash immediately with plenty of water. Gently and thorough wash the contaminated skin with
running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. COLD water
may be used. Cover the irritated skin with an emollient. Seek medical attention. Treat symptomatically and supportively.
Wash any contaminated clothing before reusing.
InhalationIf the victim is not breathing, perform artificial respiration. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, oxygen can be administered. Seek medical attention. Treat symptomatically and supportively.
INDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat.
Ingestion
Loosen tight clothing such as a collar, tie, belt, or waistband. If the victim is not breathing, administer artificial respiration.
Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material
was ingested; the absence of such signs, however, is not conclusive. Seek immediate medical attention and, if possible,
show the chemical label. Treat symptomatically and supportively.

Section V.Fire and Explosion Data
Not available.
FlammabilityMay be combustible at high temperature.Auto-Ignition
Flammable Limits
Flash PointsNot available.
Not available.
Combustion ProductsThese products are toxic carbon oxides (CO, CO 2), halogenated compounds.
WARNING: Highly toxic HCl gas is produced during combustion.
Fire Hazards
No specific information is available regarding the flammability of this compound in the presence of various materials.
Explosion HazardsRisks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
No additional information is available regarding the risks of explosion.
Fire Fighting Media
SMALL FIRE: Use DRY chemicals, CO 2, water spray or foam.
and InstructionsLARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
Continued on Next Page
2,3-Dichlorotetrahydrofuran

Section VI.Accidental Release Measures
Spill CleanupIn case of a spill and/or a leak, always shut off any sources of ignition, ventilate the area, and exercise caution. Absorb
Instructionswith an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning the spill by rinsing any
contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on
disposal.

Section VII. Handling and Storage
Handling and StorageKeep away from heat and sources of ignition. Mechanical exhaust required. When not in use, tightly seal the container
and store in a dry, cool place. Avoid excessive heat and light. Do not breathe gas, fumes, vapor or spray.
Information
Always store away from incompatible compounds such as oxidizing agents.

Section VIII. Exposure Controls/Personal Protection
Engineering ControlsProvide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location.
Personal ProtectionSplash goggles. Lab coat. Vapor and dust respirator. Gloves. Suggested protective clothing might not be sufficient;
consult a specialist BEFORE handling this product.
Exposure LimitsNot available.

Section IX. Physical and Chemical Properties
Solubility
Physical state @ 20°CLiquid.Not available.
1.34
Specific Gravity
Molecular Weight141Partition CoefficientNot available.
Boiling Point93°C @ 70mm HgVapor PressureNot available.
Melting PointNot available.Vapor DensityNot available.
Not available.VolatilityNot available.
Refractive Index
Critical TemperatureNot available.OdorNot available.
ViscosityNot available.TasteNot available.

Section X.Stability and Reactivity Data
Stability
This material is stable if stored under proper conditions. (See Section VII for instructions)
Conditions of InstabilityAvoid excessive heat and light.
Incompatibilities
Reactive with oxidizing agents.

Section XI. Toxicological Information
RTECS NumberLU0525000
Eye contact. Ingestion. Inhalation.
Routes of Exposure
Toxicity DataNot available.
Chronic Toxic EffectsCARCINOGENIC EFFECTS : Not available.
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY: Not available.
There is no known effect from chronic exposure to this product. Repeated or prolonged exposure to this compound is not
known to aggravate existing medical conditions.
Acute Toxic EffectsNo specific information is available in our data base regarding the toxic effects of this material for humans. However,
exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if
inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling
this compound.
Continued on Next Page
2,3-Dichlorotetrahydrofuran

Section XII.Ecological Information
EcotoxicityNot available.
Not available.
Environmental Fate

Section XIII. Disposal Considerations
Recycle to process, if possible. Consult your local or regional authorities. You may be able to dissolve or mix material with
Waste Disposal
a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
federal, state, and local regulations when disposing of the substance.

Section XIV. Transport Information
DOT ClassificationNot a DOT controlled material (United States).
Not applicable.
PIN Number
Proper Shipping Name
Not applicable.
Packing Group (PG)Not applicable.
DOT Pictograms

Section XV. Other Regulatory Information and Pictograms
TSCA Chemical InventoryThis product is NOT on the EPA Toxic Substances Control Act (TSCA) inventory. The following notices are required by 40
CFR 720.36 (C) for those products not on the inventory list:
(EPA)
(i) These products are supplied solely for use in research and development by or under the supervision of a technically
qualified individual as defined in 40 CFR 720.0 et sec.
(ii) The health risks of these products have not been fully determined. Any information that is or becomes available will be
supplied on an MSDS sheet.
WHMIS ClassificationNot controlled under WHMIS (Canada).
(Canada)
EINECS Number (EEC) Not available.
EEC Risk StatementsNot available.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LU0525000
CHEMICAL NAME :
Furan, 2,3-dichlorotetrahydro-
CAS REGISTRY NUMBER :
3511-19-1
LAST UPDATED :
198910
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C4-H6-Cl2-O
MOLECULAR WEIGHT :
141.00
WISWESSER LINE NOTATION :
T5OTJ BG CG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
888 mg/kg/74W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
REFERENCE :
JNCIAM Journal of the National Cancer Institute. (Washington, DC) V.1-60, 1940-78. For publisher information, see JJIND8. Volume(issue)/page/year: 48,1431,1972

 Safety Information

Risk Phrases R36/37/38:Irritating to eyes, respiratory system and skin .
Safety Phrases S26-S36/37/39
RTECS LU0525000
HS Code 2932190090

 Synthetic Route

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2,3-Dichlorotetrahydrofuran Structure

2,3-Dichlorotet...

CAS#:3511-19-1

Literature: Justus Liebigs Annalen der Chemie, , vol. 596, p. 1,86, 113 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 226, p. 185 Journal of the Chemical Society, , p. 1707,1712

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2,3-Dichlorotetrahydrofuran Structure

2,3-Dichlorotet...

CAS#:3511-19-1

Literature: Journal of the Chemical Society, , p. 136,141

~%

2,3-Dichlorotetrahydrofuran Structure

2,3-Dichlorotet...

CAS#:3511-19-1

Literature: Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 226, p. 185 Justus Liebigs Annalen der Chemie, , vol. 596, p. 1,86,113 DE703956 , ; DRP/DRBP Org.Chem.

 Customs

HS Code 2932190090
Summary 2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Synonyms

FURAN,2,3-DICHLOROTETRAHYDRO
Tetrahydro-2,3-dichlorofuran
MFCD08443596
2,3,6-TRIFLUOROBENZOPHENONE
2,3-bis(chloranyl)oxolane
2,3-Dichlor-tetrahydro-furan
2,3-dichloro-tetrahydro-furan
2,3-dichlorotetrahydrofurane
EINECS 222-513-0
opt.inaktiv. 2,3-Dichlor-tetrahydrofuran
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