Methyl 3-chloro-3-oxopropanoate structure
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Common Name | Methyl 3-chloro-3-oxopropanoate | ||
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CAS Number | 37517-81-0 | Molecular Weight | 136.534 | |
Density | 1.3±0.1 g/cm3 | Boiling Point | 167.5±0.0 °C at 760 mmHg | |
Molecular Formula | C4H5ClO3 | Melting Point | N/A | |
MSDS | Chinese USA | Flash Point | 80.0±0.0 °C | |
Symbol |
GHS05, GHS07 |
Signal Word | Danger |
Name | Methyl malonyl chloride |
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Synonym | More Synonyms |
Density | 1.3±0.1 g/cm3 |
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Boiling Point | 167.5±0.0 °C at 760 mmHg |
Molecular Formula | C4H5ClO3 |
Molecular Weight | 136.534 |
Flash Point | 80.0±0.0 °C |
Exact Mass | 135.992722 |
PSA | 43.37000 |
LogP | 0.56 |
Vapour Pressure | 1.7±0.3 mmHg at 25°C |
Index of Refraction | 1.425 |
Storage condition | 2-8°C |
Symbol |
GHS05, GHS07 |
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Signal Word | Danger |
Hazard Statements | H314-H335 |
Precautionary Statements | P261-P280-P305 + P351 + P338-P310 |
Personal Protective Equipment | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
Hazard Codes | C:Corrosive; |
Risk Phrases | R34 |
Safety Phrases | S26-S36/37/39-S45 |
RIDADR | UN 3265 8/PG 2 |
WGK Germany | 3 |
Packaging Group | II |
Hazard Class | 8 |
HS Code | 2918300090 |
~% Methyl 3-chloro... CAS#:37517-81-0 |
Literature: Heterocycles, , vol. 32, # 2 p. 245 - 251 |
~66% Methyl 3-chloro... CAS#:37517-81-0 |
Literature: Toke, Laszlo; Hell, Zoltan; Szabo, Gabor T.; Toth, Gabor; Bihari, Maria; Rockenbauer, Antal Tetrahedron, 1993 , vol. 49, # 23 p. 5133 - 5146 |
Precursor 2 | |
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DownStream 10 | |
HS Code | 2918300090 |
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Summary | 2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |
Synthesis and mesomorphic properties of calamitic malonates and cyanoacetates tethered to 4-cyanobiphenyls.
Beilstein J. Org. Chem. 8 , 371-8, (2012) 4-Cyano-1,1'-biphenyl derivatives bearing ω-hydroxyalkyl substituents were reacted with methyl 3-chloro-3-oxopropionate or cyanoacetic acid, giving liquid-crystalline linear malonates and cyanoacetate... |
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A general solid phase synthesis of 4-substituted quinolinones via Pd-catalyzed cross coupling. Xu C, et al.
Tetrahedron Lett. 47(28) , 4885-88, (3006)
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Solvent-free microwave-assisted Bingel reaction in carbon nanohorns. Economopoulos SP, et al.
J. Mater. Chem. 19(39) , 7326-31, (2009)
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Propanoic acid, 3-chloro-3-oxo-, methyl ester |
Methyl (Chloroformyl)acetate |
methyl chlorocarbonyl acetate |
3-methoxy-3-oxopropanoyl chloride |
METHYL CHLOROFORMYLACETATE |
methyl-3-chlorooxopropionate |
METHYL 3-CHLORO-3-OXOPROPIONATE |
Methyl Malonyl Chloride |
methyl 2-chloroformylacetate |
(Chloroformyl)acetic Acid Methyl Ester |
Methyl Malonyl chloride 25GR |
MFCD00013657 |
methoxycarbonylacetyl chloride |
EINECS 253-540-6 |
Methyl 3-chloro-3-oxopropanoate |
Mehtyl Malonyl Chloride |
3-Chloro-3-oxopropionic Acid Methyl Ester |