Methyl 3-chloro-3-oxopropanoate

Methyl 3-chloro-3-oxopropanoate Structure
Methyl 3-chloro-3-oxopropanoate structure
Common Name Methyl 3-chloro-3-oxopropanoate
CAS Number 37517-81-0 Molecular Weight 136.534
Density 1.3±0.1 g/cm3 Boiling Point 167.5±0.0 °C at 760 mmHg
Molecular Formula C4H5ClO3 Melting Point N/A
MSDS Chinese USA Flash Point 80.0±0.0 °C
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

Synthesis and mesomorphic properties of calamitic malonates and cyanoacetates tethered to 4-cyanobiphenyls.

Beilstein J. Org. Chem. 8 , 371-8, (2012)

4-Cyano-1,1'-biphenyl derivatives bearing ω-hydroxyalkyl substituents were reacted with methyl 3-chloro-3-oxopropionate or cyanoacetic acid, giving liquid-crystalline linear malonates and cyanoacetates. These compounds formed monotropic nematic phases at 62 °...

A general solid phase synthesis of 4-substituted quinolinones via Pd-catalyzed cross coupling. Xu C, et al.

Tetrahedron Lett. 47(28) , 4885-88, (3006)

Solvent-free microwave-assisted Bingel reaction in carbon nanohorns. Economopoulos SP, et al.

J. Mater. Chem. 19(39) , 7326-31, (2009)