Bis(2,2,2-trichloroethyl)Azodicarboxylate structure
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Common Name | Bis(2,2,2-trichloroethyl)Azodicarboxylate | ||
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CAS Number | 38857-88-4 | Molecular Weight | 380.82500 | |
Density | 1.78g/cm3 | Boiling Point | 380.7ºC at 760 mmHg | |
Molecular Formula | C6H4Cl6N2O4 | Melting Point | 109-111ºC(lit.) | |
MSDS | Chinese USA | Flash Point | 184.1ºC | |
Symbol |
GHS07 |
Signal Word | Warning |
Name | Bis(2,2,2-trichloroethyl) Azodicarboxylate |
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Synonym | More Synonyms |
Density | 1.78g/cm3 |
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Boiling Point | 380.7ºC at 760 mmHg |
Melting Point | 109-111ºC(lit.) |
Molecular Formula | C6H4Cl6N2O4 |
Molecular Weight | 380.82500 |
Flash Point | 184.1ºC |
Exact Mass | 377.83000 |
PSA | 77.32000 |
LogP | 4.45220 |
Index of Refraction | 1.566 |
Storage condition | 2-8°C |
Symbol |
GHS07 |
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Signal Word | Warning |
Hazard Statements | H315-H319-H335 |
Precautionary Statements | P261-P305 + P351 + P338 |
Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
Hazard Codes | Xi: Irritant; |
Risk Phrases | 36/37/38 |
Safety Phrases | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | 3 |
HS Code | 2927000090 |
Precursor 1 | |
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DownStream 1 | |
HS Code | 2927000090 |
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Summary | 2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |
Catalytic and enantioselective aza-ene and hetero-Diels-Alder reactions of alkenes and dienes with azodicarboxylates.
Org. Biomol. Chem. 3(12) , 2344-9, (2005) Lewis acids such as Cu(OTf)(2), Zn(OTf)(2), Yb(OTf)(3) and Nd(OTf)(3) catalyze the aza-ene reaction of alkenes with azodicarboxylates, giving the allylic amination adducts. The use of bis(2,2,2-trichl... |
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Stereoselective formation of carbon-carbon bonds via SN2-displacement: synthesis of substituted cycloalkyl[b]indoles.
J. Org. Chem. 70(21) , 8385-94, (2005) A general asymmetric synthesis of substituted cycloalkyl[b]indoles has been accomplished. The key features of this approach are (1) the utilization of a Japp-Klingemann condensation/Fischer cyclizatio... |
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A convenient synthesis of N-acetyllactosamine derivatives from lactal.
Carbohydr. Res. 247 , 159-64, (1993) In a thermal inverse-type hetero-Diels-Alder reaction of O-silyl-protected lactal 1 and bis(2,2,2-trichloroethyl) azodicarboxylate (2), the dihydrooxadiazine derivative 3 was obtained in a very high y... |
2,2,2-trichloroethyl N-(2,2,2-trichloroethoxycarbonylimino)carbamate |
MFCD00010607 |
Azodicarboxylic Acid Bis(2,2,2-trichloroethyl) Ester |