2-(Bromomethyl)-1,3-dioxolane

Modify Date: 2025-08-21 13:01:11

2-(Bromomethyl)-1,3-dioxolane Structure
2-(Bromomethyl)-1,3-dioxolane structure
 Common Name 2-(Bromomethyl)-1,3-dioxolane
CAS Number 4360-63-8 Molecular Weight 167.001
Density 1.6±0.1 g/cm3 Boiling Point 178.7±25.0 °C at 760 mmHg
Molecular Formula C4H7BrO2 Melting Point N/A
MSDS Chinese USA Flash Point 62.8±0.0 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name 2-Bromomethyl-1,3-dioxolane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 178.7±25.0 °C at 760 mmHg
Molecular Formula C4H7BrO2
Molecular Weight 167.001
Flash Point 62.8±0.0 °C
Exact Mass 165.962936
PSA 18.46000
LogP 0.28
Vapour Pressure 1.3±0.3 mmHg at 25°C
Index of Refraction 1.473
InChIKey CKIIJIDEWWXQEA-UHFFFAOYSA-N
SMILES BrCC1OCCO1

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S24/25
WGK Germany 3
HS Code 2932999099

 Synthetic Route

Bromoacetaldehyde dimethyl acetal structure

Bromoacetaldehy...

CAS#:7252-83-7

Ethylene glycol structure

Ethylene glycol

CAS#:107-21-1

~91%

2-(Bromomethyl)-1,3-dioxolane Structure

2-(Bromomethyl)...

CAS#:4360-63-8

Literature: Diaz-Ortiz; Diez-Barra; De La Hoz; Prieto Synthetic Communications, 1993 , vol. 23, # 14 p. 1935 - 1942
Ethylene glycol structure

Ethylene glycol

CAS#:107-21-1

Bromoacetaldehyde diethyl acetal structure

Bromoacetaldehy...

CAS#:2032-35-1

~88%

2-(Bromomethyl)-1,3-dioxolane Structure

2-(Bromomethyl)...

CAS#:4360-63-8

Literature: Conole, Grainne; Mears, Richard J.; Silva, Harshani De; Whiting, Andrew Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 14 p. 1825 - 1836
1,3-Dioxolane,2-methyl- structure

1,3-Dioxolane,2...

CAS#:497-26-7

~46%

2-(Bromomethyl)-1,3-dioxolane Structure

2-(Bromomethyl)...

CAS#:4360-63-8

2-Bromoethyl acetate structure

2-Bromoethyl acetate

CAS#:927-68-4

Literature: Kotlyar; Pluzhnik-Gladyr'; Zlotskii Russian Journal of General Chemistry, 1998 , vol. 68, # 2 p. 283 - 284
1,3-Dioxolane,2-methyl- structure

1,3-Dioxolane,2...

CAS#:497-26-7

~93%

2-(Bromomethyl)-1,3-dioxolane Structure

2-(Bromomethyl)...

CAS#:4360-63-8

Literature: Kotlyar; Pluzhnik-Gladyr' Russian Journal of General Chemistry, 1998 , vol. 68, # 6 p. 914 - 916
Ethylene glycol structure

Ethylene glycol

CAS#:107-21-1

~%

2-(Bromomethyl)-1,3-dioxolane Structure

2-(Bromomethyl)...

CAS#:4360-63-8

Literature: Hill; Pidgeon Journal of the American Chemical Society, 1928 , vol. 50, p. 2723
Ethylene glycol structure

Ethylene glycol

CAS#:107-21-1

bromoacetaldehyde structure

bromoacetaldehyde

CAS#:17157-48-1

~%

2-(Bromomethyl)-1,3-dioxolane Structure

2-(Bromomethyl)...

CAS#:4360-63-8

Literature: Hill; Pidgeon Journal of the American Chemical Society, 1928 , vol. 50, p. 2723 Full Text Show Details Hibbert; Hill Journal of the American Chemical Society, 1923 , vol. 45, p. 747
Ethane,1,1'-oxybis[1,2-dibromo- structure

Ethane,1,1'-oxy...

CAS#:6304-35-4

Ethylene glycol structure

Ethylene glycol

CAS#:107-21-1

~%

2-(Bromomethyl)-1,3-dioxolane Structure

2-(Bromomethyl)...

CAS#:4360-63-8

2-Bromoethanol structure

2-Bromoethanol

CAS#:540-51-2

Literature: Hibbert; Perry; Taylor Journal of the American Chemical Society, 1929 , vol. 51, p. 1554
vinyl acetate structure

vinyl acetate

CAS#:108-05-4

Ethylene glycol structure

Ethylene glycol

CAS#:107-21-1

~%

2-(Bromomethyl)-1,3-dioxolane Structure

2-(Bromomethyl)...

CAS#:4360-63-8

Literature: Gurwitsch Zhurnal Obshchei Khimii, 1957 , vol. 27, p. 2888,2890; engl. Ausg. S. 2925
Bromoacetaldehyde diethyl acetal structure

Bromoacetaldehy...

CAS#:2032-35-1

~%

2-(Bromomethyl)-1,3-dioxolane Structure

2-(Bromomethyl)...

CAS#:4360-63-8

Literature: Lee, Kheng H.; Brumby, Steven Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 1071 - 1074

 Customs

HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles1

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 Synonyms

Bromoacetaldehyde ethylene acetal
EINECS 224-443-6
MFCD00003214
1,3-Dioxolane, 2-(bromomethyl)-
2-(Bromomethyl)-1,3-dioxolane
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