2-Fluorobenzyl bromide

Modify Date: 2024-01-02 11:34:44

2-Fluorobenzyl bromide Structure
2-Fluorobenzyl bromide structure
Common Name 2-Fluorobenzyl bromide
CAS Number 446-48-0 Molecular Weight 189.025
Density 1.5±0.1 g/cm3 Boiling Point 200.2±0.0 °C at 760 mmHg
Molecular Formula C7H6BrF Melting Point N/A
MSDS Chinese USA Flash Point 82.8±0.0 °C
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name 2-Fluorobenzyl bromide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 200.2±0.0 °C at 760 mmHg
Molecular Formula C7H6BrF
Molecular Weight 189.025
Flash Point 82.8±0.0 °C
Exact Mass 187.963684
LogP 2.97
Vapour Pressure 0.5±0.3 mmHg at 25°C
Index of Refraction 1.544

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H314-H335
Precautionary Statements P261-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive
Risk Phrases R34
Safety Phrases S23-S26-S27-S36/37/39-S45
RIDADR UN 3265 8/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 8
HS Code 2903999090

 Synthetic Route

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2-Fluorobenzyl bromide Structure

2-Fluorobenzyl ...

CAS#:446-48-0

Literature: Shoesmith; Slater Journal of the Chemical Society, 1926 , p. 220

~77%

2-Fluorobenzyl bromide Structure

2-Fluorobenzyl ...

CAS#:446-48-0

Literature: Kabalka, George W.; Wu, Zhongzhi; Ju, Yuhong Tetrahedron Letters, 2000 , vol. 41, # 27 p. 5161 - 5164

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2-Fluorobenzyl bromide Structure

2-Fluorobenzyl ...

CAS#:446-48-0

Literature: Mamalis,P. et al. Journal of the Chemical Society, 1965 , p. 1829 - 1843

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2-Fluorobenzyl bromide Structure

2-Fluorobenzyl ...

CAS#:446-48-0

Literature: Shoesmith; Slater Journal of the Chemical Society, 1926 , p. 220

~%

2-Fluorobenzyl bromide Structure

2-Fluorobenzyl ...

CAS#:446-48-0

Literature: v.Braun; Friedsam Chemische Berichte, 1930 , vol. 63, p. 2407,2410

~%

2-Fluorobenzyl bromide Structure

2-Fluorobenzyl ...

CAS#:446-48-0

Detail
Literature: v.Braun; Friedsam Chemische Berichte, 1930 , vol. 63, p. 2407,2410

~%

2-Fluorobenzyl bromide Structure

2-Fluorobenzyl ...

CAS#:446-48-0

Detail
Literature: Shoesmith; Slater Journal of the Chemical Society, 1926 , p. 220

 Customs

HS Code 2903999090
Summary 2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Articles3

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J. Med. Chem. 38(19) , 3884-8, (1995)

Analogues of 9-(2-fluorobenzyl)-6-(methylamino)-9H-purine (1) containing isosteric replacements of the imidazole ring atoms were synthesized and tested for anticonvulsant activity. The pyrrolo[2,3-d]-...

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 Synonyms

α-Bromo-o-fluorotoluene
FR B1E
EINECS 207-169-1
o-Fluorobenzyl bromide
α-Bromo-2-fluorotoluene
2-Fluorobenzyl bromide
Benzene, 1-(bromomethyl)-2-fluoro-
MFCD00000324
1-(Bromomethyl)-2-fluorobenzene
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