3′-Fluoro-4′-methoxyacetophenone

Modify Date: 2024-01-02 16:47:12

3′-Fluoro-4′-methoxyacetophenone Structure
3′-Fluoro-4′-methoxyacetophenone structure
 Common Name 3′-Fluoro-4′-methoxyacetophenone
CAS Number 455-91-4 Molecular Weight 168.165
Density 1.1±0.1 g/cm3 Boiling Point 262.9±20.0 °C at 760 mmHg
Molecular Formula C9H9FO2 Melting Point 92-94 °C(lit.)
MSDS Chinese USA Flash Point 109.4±16.7 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name 3-Fluoro-4-methoxyacetophenone
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 262.9±20.0 °C at 760 mmHg
Melting Point 92-94 °C(lit.)
Molecular Formula C9H9FO2
Molecular Weight 168.165
Flash Point 109.4±16.7 °C
Exact Mass 168.058655
PSA 26.30000
LogP 1.79
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.488

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39-S36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2914700090

 Synthetic Route

2-Fluoroanisole structure

2-Fluoroanisole

CAS#:321-28-8

Acetyl chloride structure

Acetyl chloride

CAS#:75-36-5

~94%

3′-Fluoro-4′-methoxyacetophenone Structure

3′-Fluoro-4′-me...

CAS#:455-91-4

Literature: G. D. Searle and Co. Patent: US6342510 B1, 2002 ; Location in patent: Page column 28 ;
2-Fluoroanisole structure

2-Fluoroanisole

CAS#:321-28-8

~69%

3′-Fluoro-4′-methoxyacetophenone Structure

3′-Fluoro-4′-me...

CAS#:455-91-4

Literature: Displaytech, Inc. Patent: US5422037 A1, 1995 ;
3'-Fluoro-4'-hydroxyacetophenone structure

3'-Fluoro-4'-hy...

CAS#:403-14-5

Dimethyl sulfate structure

Dimethyl sulfate

CAS#:77-78-1

~%

3′-Fluoro-4′-methoxyacetophenone Structure

3′-Fluoro-4′-me...

CAS#:455-91-4

Literature: Yerande, Swapnil G.; Shendage, Deepak M.; Wakchaure, Prasad B.; Phadtare, Ganesh R.; Bhoite, Madhavrao Y.; Gangopadhyay, Ashok Kumar; Nagarajan, Kuppuswamy; Rupp, Richard Helmut Tetrahedron Letters, 2014 , vol. 55, # 15 p. 2426 - 2429
Acetanisole structure

Acetanisole

CAS#:100-06-1

~48%

3′-Fluoro-4′-methoxyacetophenone Structure

3′-Fluoro-4′-me...

CAS#:455-91-4

Literature: Stavber, Stojan; Zupan, Marko Tetrahedron Letters, 1996 , vol. 37, # 20 p. 3591 - 3594
2-Fluoroanisole structure

2-Fluoroanisole

CAS#:321-28-8

Ethanoic anhydride structure

Ethanoic anhydride

CAS#:108-24-7

~%

3′-Fluoro-4′-methoxyacetophenone Structure

3′-Fluoro-4′-me...

CAS#:455-91-4

Literature: English; Mead; Niemann Journal of the American Chemical Society, 1940 , vol. 62, p. 350,353
(2-fluorophenyl) acetate structure

(2-fluorophenyl...

CAS#:29650-44-0

~%

3′-Fluoro-4′-methoxyacetophenone Structure

3′-Fluoro-4′-me...

CAS#:455-91-4

Literature: Yerande, Swapnil G.; Shendage, Deepak M.; Wakchaure, Prasad B.; Phadtare, Ganesh R.; Bhoite, Madhavrao Y.; Gangopadhyay, Ashok Kumar; Nagarajan, Kuppuswamy; Rupp, Richard Helmut Tetrahedron Letters, 2014 , vol. 55, # 15 p. 2426 - 2429
2-Fluorophenol structure

2-Fluorophenol

CAS#:367-12-4

~%

3′-Fluoro-4′-methoxyacetophenone Structure

3′-Fluoro-4′-me...

CAS#:455-91-4

Literature: Yerande, Swapnil G.; Shendage, Deepak M.; Wakchaure, Prasad B.; Phadtare, Ganesh R.; Bhoite, Madhavrao Y.; Gangopadhyay, Ashok Kumar; Nagarajan, Kuppuswamy; Rupp, Richard Helmut Tetrahedron Letters, 2014 , vol. 55, # 15 p. 2426 - 2429
Carbon disulphide structure

Carbon disulphide

CAS#:75-15-0

Aluminium chloride structure

Aluminium chloride

CAS#:7446-70-0

2-Fluoroanisole structure

2-Fluoroanisole

CAS#:321-28-8

Ethanoic anhydride structure

Ethanoic anhydride

CAS#:108-24-7

~%

Detail
Literature: English; Mead; Niemann Journal of the American Chemical Society, 1940 , vol. 62, p. 350,353

 Customs

HS Code 2914700090
Summary HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

 Articles1

More Articles
Synthesis of some Fluorine-Containing Analogs and Derivatives of Medicinals. Minor JT and Vanderwerf CA.

J. Org. Chem. 17(11) , 1425-30, (1952)

 Synonyms

Ethanone, 1-(3-fluoro-4-methoxyphenyl)-
MFCD00026219
1-(3-Fluoro-4-methoxyphenyl)-1-ethanone
3'-Fluoro-4'-methoxyacetophenone
3′-Fluoro-4′-methoxyacetophenone
1-(3-Fluoro-4-methoxyphenyl)ethanone
1-(3-fluoro-4-methoxyphenyl)ethan-1-one
EINECS 207-253-8
1VR CF DO1
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Chemsrc provides 3′-Fluoro-4′-methoxyacetophenone(CAS#:455-91-4) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Articles of 3′-Fluoro-4′-methoxyacetophenone are included as well.>> amp version: 3′-Fluoro-4′-methoxyacetophenone

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