N,N-Dimethyl-3,5-dinitroaniline

Modify Date: 2024-01-05 19:55:09

N,N-Dimethyl-3,5-dinitroaniline Structure
N,N-Dimethyl-3,5-dinitroaniline structure
Common Name N,N-Dimethyl-3,5-dinitroaniline
CAS Number 46429-76-9 Molecular Weight 211.17500
Density 1.397g/cm3 Boiling Point 342.848ºC at 760 mmHg
Molecular Formula C8H9N3O4 Melting Point N/A
MSDS N/A Flash Point 161.149ºC

 Names

Name N,N-Dimethyl-3,5-dinitroaniline
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.397g/cm3
Boiling Point 342.848ºC at 760 mmHg
Molecular Formula C8H9N3O4
Molecular Weight 211.17500
Flash Point 161.149ºC
Exact Mass 211.05900
PSA 94.88000
LogP 2.61540
Index of Refraction 1.628

 MSDS

N,N-Dimethyl-3,5-dinitroaniline
SAFETY DATA SHEET

Section1. IDENTIFICATION
Product name:N,N-Dimethyl-3,5-dinitroaniline

Section2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDS
Type C
Self-reactive substances and mixtures
HEALTH HAZARDS
Category 4
Acute toxicity (Oral)
Acute toxicity (Dermal)Category 4
Category 4
Acute toxicity (Inhalation)
Skin corrosion/irritationCategory 2
Category 2A
Serious eye damage/eye irritation
ENVIRONMENTAL HAZARDSNot classified
GHS label elements, including precautionary statements
Pictograms or hazard symbols
Danger
Signal word
Hazard statementsHeating may cause a fire
Harmful if swallowed, in contact with skin or if inhaled
Causes skin irritation
Causes serious eye irritation
Precautionary statements:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
[Prevention]
Keep away from incompatible materials such as oxidizing agents.
Keep only in original container.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Use only outdoors or in a well-ventilated area.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
Wear protective gloves and eye/face protection.
N,N-Dimethyl-3,5-dinitroaniline

Section2. HAZARDS IDENTIFICATION
[Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Rinse mouth.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Gently wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Call a POISON CENTER or doctor/physician if you feel unwell.
[Storage]Store away from other materials.
Store in a well-ventilated place. Keep cool.
[Disposal]Dispose of contents/container through a waste management company authorized by
the local government.

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
N,N-Dimethyl-3,5-dinitroaniline
Components:
Percent:....
CAS Number:46429-76-9
Chemical Formula:C8H9N3O4

Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. If skin irritation or rash occurs: Get medical advice/attention.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion:Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.
A rescuer should wear personal protective equipment, such as rubber gloves and air-
Protection of first-aiders:
tight goggles.

Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, foam, water spray, carbon dioxide.
media:
Specific hazards arising Explosion risk in case of fire. Fight fire remotely due to the risk of explosion.
from the chemical:Take care as it may decompose upon combustion or in high temperatures to
generate poisonous fume.
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
spraying with water. Eliminate all ignition sources if safe to do so.
Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

Section6. ACCIDENTAL RELEASE MEASURES
Use personal protective equipment. Keep people away from and upwind of spill/leak.
Personal precautions,
protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
emergency procedures: roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
up: appropriate laws and regulations.
N,N-Dimethyl-3,5-dinitroaniline

Section6. ACCIDENTAL RELEASE MEASURES
Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
hazards:case of a fire. Use spark-proof tools and explosion-proof equipment.

Section7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment.
Be careful not to cause leakage, overflow, or dispersion. Steam should not be
generated unnecessarily. Keep away from heat/sparks/open flame/hot surfaces. -No
smoking. Take measures to prevent the build up of electrostatic charge. Use
explosion-proof equipment. Avoid shock and friction. Wash hands and face before
breaks and immediately after handling the product.
Use a local exhaust if dust or aerosol will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Storage conditions:Keep container tightly closed. Store in a cool, dark and well-ventilated place.
Be sure not to give the container unexpected impacts, such as falling down or falling
off.
Store away from other materials.
Packaging material:Comply with laws. Keep only in original container.

Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:Install a closed system or local exhaust as possible so that workers should not be
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Dust respirator. Follow local and national regulations.
Protective gloves.
Hand protection:
Eye protection:Safety glasses. A face-shield, if the situation requires.
Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Solid
Form:Crystal- Powder
Pale yellow - Reddish yellow
Colour:
Odour:No data available
pH: No data available
Melting point/freezing point:166°C
Boiling point/range:No data available
Flash point:No data available
Flammability or explosive
limits:
Lower:No data available
Upper:No data available
Relative density:No data available
Solubility(ies):
[Water]No data available
[Other solvents]No data available

Section10. STABILITY AND REACTIVITY
Chemical stability:Stable under proper conditions.
Possibility of hazardous May explosively decompose on heating, shock, friction, etc.
reactions:
Heat, Spark, Open flame, Shock, Friction
Conditions to avoid:
Incompatible materials: Oxidizing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
products:
N,N-Dimethyl-3,5-dinitroaniline

Section11. TOXICOLOGICAL INFORMATION
Acute Toxicity:No data available
Skin corrosion/irritation: No data available
Serious eyeNo data available
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
No data available
IARC =
NTP =No data available
No data available
Reproductive toxicity:

Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
Fish:No data available
Crustacea:No data available
Algae:No data available
Persistence / degradability: No data available
BioaccumulativeNo data available
potential(BCF):
Mobility in soil
Log Pow:No data available
Soil adsorption (Koc):No data available
Henry's LawNo data available
constant(PaM3/mol):

Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities and an expert of disposal. You may be able
to dissolve or mix material with a combustible solvent and little by little burn in a chemical incinerator equipped with
an afterburner and scrubber system. If a large amount of the substance is burned at a time, an explosion may
occur. Observe all federal, state and local regulations when disposing of the substance.

Section14. TRANSPORT INFORMATION
Hazards Class:4.1: Flammable solid.
UN-No:3224
Proper shipping name:Self-reactive solid type C

Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

HS Code 2921430090

 Synthetic Route

~42%

N,N-Dimethyl-3,5-dinitroaniline Structure

N,N-Dimethyl-3,...

CAS#:46429-76-9

Literature: Dutov, Mikhail D.; Serushkina, Olga V. Mendeleev Communications, 2013 , vol. 23, # 3 p. 174 - 175

~92%

N,N-Dimethyl-3,5-dinitroaniline Structure

N,N-Dimethyl-3,...

CAS#:46429-76-9

Literature: Chao, Qian; Jinqiang, Liu; Xinzhi, Chen Journal of Chemical Research, 2008 , # 2 p. 70 - 71

~%

N,N-Dimethyl-3,5-dinitroaniline Structure

N,N-Dimethyl-3,...

CAS#:46429-76-9

Literature: Lothrop et al. Journal of the American Chemical Society, 1951 , vol. 73, p. 3581

~%

N,N-Dimethyl-3,5-dinitroaniline Structure

N,N-Dimethyl-3,...

CAS#:46429-76-9

Literature: Roberts; Selby Journal of the Chemical Society, 1949 , p. 2785,2788

~%

N,N-Dimethyl-3,5-dinitroaniline Structure

N,N-Dimethyl-3,...

CAS#:46429-76-9

Literature: Roberts; Selby Journal of the Chemical Society, 1949 , p. 2785,2788

 Customs

HS Code 2921430090
Summary HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Synonyms

OXIFFLMOPHMUEE-UHFFFAOYSA
N,N-dimethyl-3,5-dinitro-aniline
Benzenamine,N,N-dimethyl-3,5-dinitro
N,N-Dimethyl-3,5-dinitro-anilin
N,N-Dimethyl-2,4-dinitro-anilin
3,4-Dinitro-N,N-dimethyl-anilin
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