Methyl methoxyacetate

Modify Date: 2024-01-02 16:22:45

Methyl methoxyacetate Structure
Methyl methoxyacetate structure
Common Name Methyl methoxyacetate
CAS Number 51673-84-8 Molecular Weight 104.104
Density 1.0±0.1 g/cm3 Boiling Point 63.9±20.0 °C at 760 mmHg
Molecular Formula C4H8O3 Melting Point N/A
MSDS Chinese Flash Point -18.4±8.2 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 2,2-Dimethoxyacetaldehyde
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 63.9±20.0 °C at 760 mmHg
Molecular Formula C4H8O3
Molecular Weight 104.104
Flash Point -18.4±8.2 °C
Exact Mass 104.047340
PSA 35.53000
LogP -0.13
Vapour Pressure 167.9±0.1 mmHg at 25°C
Index of Refraction 1.378
Storage condition 2-8°C
Water Solubility Fully miscible in water.

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H317
Precautionary Statements P280
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R43
Safety Phrases S24-S37
RIDADR UN 2398 3/PG 2
WGK Germany -
HS Code 2912499000

 Synthetic Route

~68%

Methyl methoxyacetate Structure

Methyl methoxya...

CAS#:51673-84-8

Literature: Degussa AG Patent: EP1460052 A1, 2004 ; Location in patent: Page 4; 5 ;

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Methyl methoxyacetate Structure

Methyl methoxya...

CAS#:51673-84-8

Literature: Camps Bres, Flora; Guerard-Helaine, Christine; Fernandes, Carlos; Castillo, Jose A.; Lemaire, Marielle Tetrahedron Asymmetry, 2013 , vol. 24, # 18 p. 1175 - 1181

~%

Methyl methoxyacetate Structure

Methyl methoxya...

CAS#:51673-84-8

Literature: The United States of America as represented by the Secretary of the Department of Health and Human Services Patent: US6376521 B1, 2002 ; US 6376521 B1

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Methyl methoxyacetate Structure

Methyl methoxya...

CAS#:51673-84-8

Literature: International Flavors and Fragrances Inc. Patent: US4124644 A1, 1978 ;

~0%

Detail
Literature: DEGUSSA AG Patent: US2004/186304 A1, 2004 ; Location in patent: Page 3 ;

~%

Methyl methoxyacetate Structure

Methyl methoxya...

CAS#:51673-84-8

Literature: International Flavors and Fragrances Inc. Patent: US4205186 A1, 1980 ;

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Detail
Literature: BASF AKTIENGESELLSCHAFT Patent: WO2005/23743 A1, 2005 ; Location in patent: Page/Page column 17-23, chart 1/2; 2/2 ;

~%

Methyl methoxyacetate Structure

Methyl methoxya...

CAS#:51673-84-8

Literature: Haneda,A. et al. Synthetic Communications, 1976 , vol. 6, p. 141 - 146

~%

Methyl methoxyacetate Structure

Methyl methoxya...

CAS#:51673-84-8

Literature: Khan, Imran A.; Saxena, Anil K. Journal of Organic Chemistry, 2013 , vol. 78, # 23 p. 11656 - 11669

 Customs

HS Code 2912499000
Summary 2912499000. other aldehyde-ethers, aldehyde-phenols and aldehydes with other oxygen function. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

 Articles3

More Articles
Catalyst-Free Aldol Additions of 1,3-Dicarbonyl Compounds. Rohr K and Mahrwald R.

Adv. Synth. Catal. 350(18) , 2877-2880, (2008)

Synthesis and activity of isoxazoline vinyl ester pseudopeptides as proteasome inhibitors. Marastoni M, et al.

J. Pept. Sci. 20(4) , 258-265, (2014)

Design and synthesis of Pictet-Spengler condensation products that exhibit oncogenic-RAS synthetic lethality and induce non-apoptotic cell death. Skouta R, et al.

Bioorg. Med. Chem. Lett. 22(17) , 5707-5713, (2012)

 Synonyms

Acetic acid, 2-methoxy-, methyl ester
Methyl methoxyacetate
Glyoxal 1-(dimethyl acetal)
EINECS 421-890-0
Acetaldehyde, 2,2-dimethoxy-
Glyoxal dimethyl acetal
Dimethoxyacetaldehyde
2,2-dimethoxyacetaldehyde
MFCD00134410
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