4-Benzyloxyphenylhydrazine hydrochloride

Modify Date: 2024-01-03 18:58:21

4-Benzyloxyphenylhydrazine hydrochloride Structure
4-Benzyloxyphenylhydrazine hydrochloride structure
Common Name 4-Benzyloxyphenylhydrazine hydrochloride
CAS Number 52068-30-1 Molecular Weight 250.724
Density N/A Boiling Point 395.8ºC at 760 mmHg
Molecular Formula C13H15ClN2O Melting Point 187-189ºC
MSDS N/A Flash Point 193.2ºC

 Names

Name 4-Benzyloxyphenylhydrazine hydrochloride
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 395.8ºC at 760 mmHg
Melting Point 187-189ºC
Molecular Formula C13H15ClN2O
Molecular Weight 250.724
Flash Point 193.2ºC
Exact Mass 250.087296
PSA 47.28000
LogP 4.12650
Storage condition 2~8 ℃

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: 4-Benzyloxyphenylhydrazine, HCl
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.

Section3. Composition/information on ingredients.
Ingredient name:4-Benzyloxyphenylhydrazine, HCl
CAS number:52068-30-1

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels.
Storage:

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
No data
Melting point:
Flash point:No data
Density:No data
Molecular formula:C13H14N2O.ClH
Molecular weight:250.7

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen chloride.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
Non-harzardous for air and ground transportation.

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases 20/21/22-36/37/38
Safety Phrases 26-36/37/39
HS Code 2928000090

 Synthetic Route

~96%

4-Benzyloxyphenylhydrazine hydrochloride Structure

4-Benzyloxyphen...

CAS#:52068-30-1

Literature: UNIVERSITY OF PITTSBURGH - OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATION; WIPF, Peter; WANG, Qiming, Jan Patent: WO2012/78859 A2, 2012 ; Location in patent: Page/Page column 47 ;

~94%

4-Benzyloxyphenylhydrazine hydrochloride Structure

4-Benzyloxyphen...

CAS#:52068-30-1

Literature: American Home Products Corporation Patent: US5229516 A1, 1993 ; US 5229516 A

~57%

4-Benzyloxyphenylhydrazine hydrochloride Structure

4-Benzyloxyphen...

CAS#:52068-30-1

Literature: Jasinski, Marcin; Gerding, Jason S.; Jankowiak, Aleksandra; Geibicki, Krzysztof; Romanski, Jaroslaw; Jastrzeibska, Katarzyna; Sivaramamoorthy, Ajan; Mason, Kristein; Evans, Donavan H.; Celeda, Malgorzata; Kaszynski, Piotr Journal of Organic Chemistry, 2013 , vol. 78, # 15 p. 7445 - 7454

 Customs

HS Code 2928000090
Summary 2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Synonyms

Hydrazine, [4-(phenylmethoxy)phenyl]-, hydrochloride (1:1)
ZMR DO1R &&HCl
1-[4-(Benzyloxy)phenyl]hydrazine hydrochloride
(4-phenylmethoxyphenyl)hydrazine,hydrochloride
5-Bromooxindole
[4-(Benzyloxy)phenyl]hydrazine monohydrochloride
4-Benzyloxyphenylhydrazine Hydrochloride
(4-(Benzyloxy)phenyl)hydrazine monohydrochloride
[4-(Benzyloxy)phenyl]hydrazine hydrochloride (1:1)
(4-(Benzyloxy)phenyl)hydrazine hydrochloride
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