Benzenesulfenylchloride, 2,4-dinitro-

Modify Date: 2024-01-08 19:47:31

Benzenesulfenylchloride, 2,4-dinitro- Structure
Benzenesulfenylchloride, 2,4-dinitro- structure
Common Name Benzenesulfenylchloride, 2,4-dinitro-
CAS Number 528-76-7 Molecular Weight 234.61700
Density 1.68g/cm3 Boiling Point 430.1ºC at 760 mmHg
Molecular Formula C6H3ClN2O4S Melting Point 94-97 °C(lit.)
MSDS Chinese USA Flash Point 213.9ºC
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 2,4-Dinitrophenylsulfenyl Chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.68g/cm3
Boiling Point 430.1ºC at 760 mmHg
Melting Point 94-97 °C(lit.)
Molecular Formula C6H3ClN2O4S
Molecular Weight 234.61700
Flash Point 213.9ºC
Exact Mass 233.95000
PSA 116.94000
LogP 3.79530
Index of Refraction 1.662
Storage condition Store at RT.

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C
Risk Phrases 34-37
Safety Phrases S26-S36/37/39-S45
RIDADR UN 3261 8/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 8
HS Code 2930909090

 Synthetic Route

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Benzenesulfenylchloride, 2,4-dinitro- Structure

Benzenesulfenyl...

CAS#:528-76-7

Literature: Lawson; Kharasch Journal of Organic Chemistry, 1959 , vol. 24, p. 857

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Benzenesulfenylchloride, 2,4-dinitro- Structure

Benzenesulfenyl...

CAS#:528-76-7

Literature: Emde Patent: DE804572 , 1949 ; DRP/DRBP Org.Chem.

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Benzenesulfenylchloride, 2,4-dinitro- Structure

Benzenesulfenyl...

CAS#:528-76-7

Literature: Shang, Jian-Li; Guo, Hui; Li, Zai-Shun; Ren, Biao; Li, Zheng-Ming; Dai, Huan-Qin; Zhang, Li-Xin; Wang, Jian-Guo Bioorganic and Medicinal Chemistry Letters, 2013 , vol. 23, # 3 p. 724 - 727

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Benzenesulfenylchloride, 2,4-dinitro- Structure

Benzenesulfenyl...

CAS#:528-76-7

Literature: Shang, Jian-Li; Guo, Hui; Li, Zai-Shun; Ren, Biao; Li, Zheng-Ming; Dai, Huan-Qin; Zhang, Li-Xin; Wang, Jian-Guo Bioorganic and Medicinal Chemistry Letters, 2013 , vol. 23, # 3 p. 724 - 727

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Benzenesulfenylchloride, 2,4-dinitro- Structure

Benzenesulfenyl...

CAS#:528-76-7

Literature: Kharasch,N.; Langford,R.B. Journal of Organic Chemistry, 1963 , vol. 28, p. 1903 - 1905

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Benzenesulfenylchloride, 2,4-dinitro- Structure

Benzenesulfenyl...

CAS#:528-76-7

Literature: Emde Patent: DE804572 , 1949 ; DRP/DRBP Org.Chem.

~%

Benzenesulfenylchloride, 2,4-dinitro- Structure

Benzenesulfenyl...

CAS#:528-76-7

Literature: Fries Justus Liebigs Annalen der Chemie, 1927 , vol. 454, p. 306

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Benzenesulfenylchloride, 2,4-dinitro- Structure

Benzenesulfenyl...

CAS#:528-76-7

Detail
Literature: Fries Justus Liebigs Annalen der Chemie, 1927 , vol. 454, p. 306

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles4

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Structure-function studies of cholera toxin and its A and B protomers. Modification of tryptophan residues.

J. Biol. Chem. 256(11) , 5481-8, (1981)

The tryptophan residues on cholera toxin and its A and B protomers have been modified by reaction with 2-nitrophenylsulfenyl chloride and 2,4-dinitrophenylsulfenyl chloride. Modification of the trypto...

Involvement and identification of a tryptophanyl residue at the pyruvate binding site of transcarboxylase.

Biochemistry 27(16) , 5978-83, (1988)

Transcarboxylase (TC) from Propionibacterium shermanii consists of a central hexameric 12S subunit to which 6 outer dimeric 5S subunits are attached through 12 biotinyl 1.3S subunits. The enzyme catal...

Studies on the Effect of Remote Substituents on Reactivity: The Rates of Addition of 2, 4-Dinitrobenzenesulfenyl Chloride to Cyclohexenes and Norbornenes (I) 1a. Kwart H and Miller LJ.

J. Am. Chem. Soc. 83(22) , 4552-4559, (1961)

 Synonyms

MFCD00007129
EINECS 208-441-2
2,4-Dinitrobenzenesulfenyl Chloride
(2,4-dinitrophenyl) thiohypochlorite