1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE

Modify Date: 2024-01-03 19:17:44

1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Structure
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE structure
Common Name 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
CAS Number 54125-02-9 Molecular Weight 172.297
Density 0.9±0.1 g/cm3 Boiling Point 181.7±0.0 °C at 760 mmHg
Molecular Formula C8H16O2Si Melting Point N/A
MSDS Chinese USA Flash Point 45.0±0.0 °C
Symbol GHS02
GHS02
Signal Word Warning

 Names

Name 1-Methoxy-3-Trimethylsiloxy-1,3-Butadiene
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 181.7±0.0 °C at 760 mmHg
Molecular Formula C8H16O2Si
Molecular Weight 172.297
Flash Point 45.0±0.0 °C
Exact Mass 172.091949
PSA 18.46000
LogP 1.98
Vapour Pressure 1.1±0.3 mmHg at 25°C
Index of Refraction 1.429
Storage condition 2-8°C

 Safety Information

Symbol GHS02
GHS02
Signal Word Warning
Hazard Statements H226
Personal Protective Equipment Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
Risk Phrases R10
Safety Phrases S23-S24/25
RIDADR UN 1993
WGK Germany 3
Packaging Group III
Hazard Class 3
HS Code 2931900090

 Synthetic Route

~87%

1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Structure

1-METHOXY-3-TRI...

CAS#:54125-02-9

Literature: Cui, Yi; Jiang, Hao; Li, Zhengtao; Wu, Na; Yang, Zhen; Quan, Junmin Organic Letters, 2009 , vol. 11, # 20 p. 4628 - 4631

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1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Structure

1-METHOXY-3-TRI...

CAS#:54125-02-9

Literature: Journal of the American Chemical Society, , vol. 125, # 13 p. 3793 - 3798

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles9

More Articles
Flexible protocol for the chemo- and regioselective building of pyrroles and pyrazoles by reactions of Danishefsky's dienes with 1,2-diaza-1,3-butadienes.

Org. Lett. 10(10) , 1983-6, (2008)

The versatility of the Mukaiyama-Michael-type addition/heterocyclization of Danishefsky's diene with 1,2-diaza-1,3-butadienes was applied to the synthesis of both 4 H-1-aminopyrroles and 4,5 H-pyrazol...

Highly selective Diels-Alder reactions of directly connected enyne dienophiles.

J. Am. Chem. Soc. 129 , 645, (2007)

The paper describes the course of cycloadditions of Diels-Alder dienophiles containing linked enyne sites, each substituted with activating groups. Consistently, it was found that in the enyne cases t...

Cross-Diels-Alder reactions of 6-oxo-1-sulfonyl-1,6-dihydropyridine-3-carboxylates.

J. Org. Chem. 72 , 2364, (2007)

Electron-poor 6-oxo-1-sulfonyl-1,6-dihydropyridine-3-carboxylates 1b-d undergo cross-Diels-Alder reactions with electron-rich dienes 4a-f under hyperbaric conditions, reacting either as dienophiles to...

 Synonyms

Silane, ((3-methoxy-1-methylene-2-propenyl)oxy)trimethyl-
{[(3E)-4-Methoxy-1,3-butadien-2-yl]oxy}(trimethyl)silane
1-Methoxy-3-(trimethylsiloxy)-1,3-butadiene
Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-, (E)-
Silane, [[(2E)-3-methoxy-1-methylene-2-propen-1-yl]oxy]trimethyl-
[(3-Methoxy-1-methylene-2-propenyl)oxy]trimethylsilane
1-Methoxy-3-trimethylsilyloxy-1,3-butadiene
1-Methoxy-3-trimethylsiloxy-1,3-butadiene
([(2E)-3-Methoxy-1-methylene-2-propenyl]oxy)(trimethyl)silane
{[(3E)-4-Methoxybuta-1,3-dien-2-yl]oxy}(trimethyl)silane
Danishefsky's diene
[(3E)-4-methoxybuta-1,3-dien-2-yl]oxy-trimethylsilane
1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene
MFCD00008498
1-Methoxy-3-(trimethylsilyloxy)butadiene
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