4,7-Dihydro-1,3-dioxepin

Modify Date: 2024-01-09 16:46:21

4,7-Dihydro-1,3-dioxepin Structure
4,7-Dihydro-1,3-dioxepin structure
Common Name 4,7-Dihydro-1,3-dioxepin
CAS Number 5417-32-3 Molecular Weight 100.11600
Density 1.049 g/mL at 25ºC(lit.) Boiling Point 125-127ºC(lit.)
Molecular Formula C5H8O2 Melting Point 125-127ºC(lit.)
MSDS Chinese USA Flash Point 79 °F
Symbol GHS02
GHS02
Signal Word Warning

 Names

Name 4,7-Dihydro-1,3-dioxepine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.049 g/mL at 25ºC(lit.)
Boiling Point 125-127ºC(lit.)
Melting Point 125-127ºC(lit.)
Molecular Formula C5H8O2
Molecular Weight 100.11600
Flash Point 79 °F
Exact Mass 100.05200
PSA 18.46000
LogP 0.54690
Index of Refraction n20/D 1.457(lit.)
Storage condition 2~8℃

 Safety Information

Symbol GHS02
GHS02
Signal Word Warning
Hazard Statements H226
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi
Risk Phrases 10
Safety Phrases 16-29-33
RIDADR UN 1993 3/PG 3
Packaging Group III
Hazard Class 3.2
HS Code 2932999099

 Synthetic Route

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4,7-Dihydro-1,3-dioxepin Structure

4,7-Dihydro-1,3...

CAS#:5417-32-3

Literature: EP337756 A2, ;

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4,7-Dihydro-1,3-dioxepin Structure

4,7-Dihydro-1,3...

CAS#:5417-32-3

Literature: Timpe, H.-J.; Schmidt, M.; Fisera, L'. Journal fuer Praktische Chemie (Leipzig), 1988 , vol. 330, # 5 p. 735 - 747

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4,7-Dihydro-1,3-dioxepin Structure

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CAS#:5417-32-3

Literature: Nieuwenhuizen, M.S.; Kieboom, A.P.G.; Bekkum, H. van Synthesis, 1981 , # 8 p. 612 - 613

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4,7-Dihydro-1,3-dioxepin Structure

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CAS#:5417-32-3

Literature: Tetrahedron Letters, , vol. 31, # 44 p. 6291 - 6294

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4,7-Dihydro-1,3-dioxepin Structure

4,7-Dihydro-1,3...

CAS#:5417-32-3

Literature: Tetrahedron, , vol. 44, p. 2943

 Customs

HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles1

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Asymmetric Hydroformylation of Heterocyclic Olefins Catalyzed by Chiral Phosphine-Phosphite-Rh(I) Complexes.

J. Org. Chem. 62(13) , 4285-4292, (1997)

Asymmetric hydroformylation of heterocyclic olefins catalyzed by phosphine-phosphite-Rh(I) complexes has been investigated. Hydroformylation of symmetrical heterocyclic olefins such as 2,5-dihydrofura...

 Synonyms

4,7-dihydro-1,3-dioxepine
MFCD00003264
cis-4,7-Dihydro-1,3-dioxepin
cis-1,3-Dioxep-5-ene