(2-BROMO-4,5-DIMETHOXYPHENYL)METHANOL

Modify Date: 2024-01-09 17:22:09

(2-BROMO-4,5-DIMETHOXYPHENYL)METHANOL Structure
(2-BROMO-4,5-DIMETHOXYPHENYL)METHANOL structure
Common Name (2-BROMO-4,5-DIMETHOXYPHENYL)METHANOL
CAS Number 54370-00-2 Molecular Weight 247.08600
Density 1.475g/cm3 Boiling Point 326.7ºC at 760 mmHg
Molecular Formula C9H11BrO3 Melting Point 95-100ºC
MSDS N/A Flash Point 151.4ºC

 Names

Name 2-Bromo-4,5-dimethoxybenzyl alcohol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.475g/cm3
Boiling Point 326.7ºC at 760 mmHg
Melting Point 95-100ºC
Molecular Formula C9H11BrO3
Molecular Weight 247.08600
Flash Point 151.4ºC
Exact Mass 245.98900
PSA 38.69000
LogP 1.95860
Appearance of Characters Crystalline Powder | White to pink-purple
Index of Refraction 1.555

 MSDS

Name: 2-Bromo-4 5-dimethoxybenzyl alcohol 98% Material Safety Data Sheet
Synonym: 6-Bromoveratryl alcohol
CAS: 54370-00-2
Section 1 - Chemical Product MSDS Name:2-Bromo-4 5-dimethoxybenzyl alcohol 98% Material Safety Data Sheet
Synonym:6-Bromoveratryl alcohol

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
54370-00-2 2-Bromo-4,5-dimethoxybenzyl alcohol 98% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 54370-00-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: white - pink or light purple
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 95-100 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C9H11BrO3
Molecular Weight: 246.9792

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
None reported.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 54370-00-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Bromo-4,5-dimethoxybenzyl alcohol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 54370-00-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 54370-00-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 54370-00-2 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn
Risk Phrases 36/37/38-22
Safety Phrases 37/39-26
HS Code 2909499000

 Synthetic Route

~99%

(2-BROMO-4,5-DIMETHOXYPHENYL)METHANOL Structure

(2-BROMO-4,5-DI...

CAS#:54370-00-2

Literature: crombie, Leslie; Josephs, Jonathan L. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1993 , # 21 p. 2599 - 2604

~96%

(2-BROMO-4,5-DIMETHOXYPHENYL)METHANOL Structure

(2-BROMO-4,5-DI...

CAS#:54370-00-2

Literature: Krishna Mohan; Narender; Srinivasu; Kulkarni; Raghavan Synthetic Communications, 2004 , vol. 34, # 12 p. 2143 - 2152

~%

(2-BROMO-4,5-DIMETHOXYPHENYL)METHANOL Structure

(2-BROMO-4,5-DI...

CAS#:54370-00-2

Literature: Journal of Chemical Research, , # 11 p. 698 - 701

 Customs

HS Code 2909499000
Summary 2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

 Synonyms

(2-bromo-4,5-dimethoxyphenyl)methanol