di-t-Bu-XPhos

Modify Date: 2024-01-02 16:46:44

di-t-Bu-XPhos Structure
di-t-Bu-XPhos structure
Common Name di-t-Bu-XPhos
CAS Number 564483-19-8 Molecular Weight 424.641
Density N/A Boiling Point 493.5±45.0 °C at 760 mmHg
Molecular Formula C29H45P Melting Point 148-151ºC(lit.)
MSDS USA Flash Point 267.7±35.0 °C

 Names

Name 2‘-DI-Tert-Butylphosphino-2,4,6-Triisopropylbiphenyl
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 493.5±45.0 °C at 760 mmHg
Melting Point 148-151ºC(lit.)
Molecular Formula C29H45P
Molecular Weight 424.641
Flash Point 267.7±35.0 °C
Exact Mass 424.325897
PSA 13.59000
LogP 10.80
Appearance of Characters Crystalline Powder | White
Vapour Pressure 0.0±1.2 mmHg at 25°C

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard Codes Xi
Risk Phrases 36/37/38
Safety Phrases 26-36/37/39
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2902909090

 Synthetic Route

~31%

di-t-Bu-XPhos Structure

di-t-Bu-XPhos

CAS#:564483-19-8

Literature: Journal of the American Chemical Society, , vol. 125, # 22 p. 6653 - 6655

 Customs

HS Code 2902909090
Summary 2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

 Articles2

More Articles
Palladium-catalyzed direct carboxylation of aryl bromides with carbon dioxide.

J. Am. Chem. Soc. 131 , 15974, (2009)

A novel protocol for the direct carbon dioxide insertion (CO(2)) into aryl halides in a catalytic manner is presented herein. Unlike other carboxylation methods using CO(2), there is no need for the s...

The selective reaction of aryl halides with KOH: synthesis of phenols, aromatic ethers, and benzofurans.

J. Am. Chem. Soc. 128 , 10694, (2006)

The direct and selective synthesis of phenols from aryl/heteroaryl halides and KOH has been achieved through the use of highly active monophosphine-based catalysts derived from Pd(2)dba(3) and ligands...

 Synonyms

tert-Butyl X-Phos
Bis(2-methyl-2-propanyl)(2',4',6'-triisopropyl-2-biphenylyl)phosphine
di-t-Bu-XPhos
MFCD06411306
Phosphine, bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]-
ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane
2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl