di-t-Bu-XPhos structure
|
Common Name | di-t-Bu-XPhos | ||
---|---|---|---|---|
CAS Number | 564483-19-8 | Molecular Weight | 424.641 | |
Density | N/A | Boiling Point | 493.5±45.0 °C at 760 mmHg | |
Molecular Formula | C29H45P | Melting Point | 148-151ºC(lit.) | |
MSDS | USA | Flash Point | 267.7±35.0 °C |
Name | 2‘-DI-Tert-Butylphosphino-2,4,6-Triisopropylbiphenyl |
---|---|
Synonym | More Synonyms |
Boiling Point | 493.5±45.0 °C at 760 mmHg |
---|---|
Melting Point | 148-151ºC(lit.) |
Molecular Formula | C29H45P |
Molecular Weight | 424.641 |
Flash Point | 267.7±35.0 °C |
Exact Mass | 424.325897 |
PSA | 13.59000 |
LogP | 10.80 |
Appearance of Characters | Crystalline Powder | White |
Vapour Pressure | 0.0±1.2 mmHg at 25°C |
Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
---|---|
Hazard Codes | Xi |
Risk Phrases | 36/37/38 |
Safety Phrases | 26-36/37/39 |
RIDADR | NONH for all modes of transport |
WGK Germany | 3 |
HS Code | 2902909090 |
~31% di-t-Bu-XPhos CAS#:564483-19-8 |
Literature: Journal of the American Chemical Society, , vol. 125, # 22 p. 6653 - 6655 |
HS Code | 2902909090 |
---|---|
Summary | 2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0% |
Palladium-catalyzed direct carboxylation of aryl bromides with carbon dioxide.
J. Am. Chem. Soc. 131 , 15974, (2009) A novel protocol for the direct carbon dioxide insertion (CO(2)) into aryl halides in a catalytic manner is presented herein. Unlike other carboxylation methods using CO(2), there is no need for the s... |
|
The selective reaction of aryl halides with KOH: synthesis of phenols, aromatic ethers, and benzofurans.
J. Am. Chem. Soc. 128 , 10694, (2006) The direct and selective synthesis of phenols from aryl/heteroaryl halides and KOH has been achieved through the use of highly active monophosphine-based catalysts derived from Pd(2)dba(3) and ligands... |
tert-Butyl X-Phos |
Bis(2-methyl-2-propanyl)(2',4',6'-triisopropyl-2-biphenylyl)phosphine |
di-t-Bu-XPhos |
MFCD06411306 |
Phosphine, bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]- |
ditert-butyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane |
2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl |