Pyridine,2-(2-propen-1-yloxy)-

Modify Date: 2024-01-09 15:10:57

Pyridine,2-(2-propen-1-yloxy)- Structure
Pyridine,2-(2-propen-1-yloxy)- structure
Common Name Pyridine,2-(2-propen-1-yloxy)-
CAS Number 5831-77-6 Molecular Weight 135.16300
Density 1.002g/cm3 Boiling Point 194ºC at 760mmHg
Molecular Formula C8H9NO Melting Point N/A
MSDS N/A Flash Point 69.4ºC

 Names

Name 2-prop-2-enoxypyridine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.002g/cm3
Boiling Point 194ºC at 760mmHg
Molecular Formula C8H9NO
Molecular Weight 135.16300
Flash Point 69.4ºC
Exact Mass 135.06800
PSA 22.12000
LogP 1.64640
Index of Refraction 1.505

 MSDS

Version 1.0
Regulation (EC) No 1907/2006

1 - Product and Company Information

Product Name2-ALLYLOXYPYRIDINE - 50mg

2 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Harmful if swallowed. Irritating to respiratory system and skin.
Risk of serious damage to eyes.

3 - Composition/Information on Ingredients

Product NameCAS #EC noAnnex I
Index Number
2-ALLYLOXYPYRIDINE5831-77-6 227-409-9 None
FormulaC8H9NO
Molecular Weight 135,1600 AMU
SynonymsPyridine, 2-(2-propenyloxy)-

4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately.

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5 - Fire Fighting Measures

EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Absorb on sand or vermiculite and place in closed containers for
disposal. Ventilate area and wash spill site after material
pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Do not breathe vapor. Do not get
in eyes, on skin, on clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed.

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Wash thoroughly after
handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Where risk assessment shows air-purifying respirators
are appropriate use a full-face respirator with multi-purpose
combination (US) or type ABEK (EN 14387) respirator cartridges as
a backup to engineering controls. If the respirator is the sole
means of protection, use a full-face supplied air respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.

9 - Physical and Chemical Properties

AppearancePhysical State: Liquid
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PropertyValueAt Temperature or Pressure
pH N/A
BP/BP RangeN/A
MP/MP RangeN/A
Flash PointN/A
FlammabilityN/A
Autoignition TempN/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion LimitsN/A
Vapor PressureN/A
Partition Coefficient Log Kow: 1,728
ViscosityN/A
Vapor DensityN/A
Saturated Vapor Conc. N/A
Evaporation RateN/A
Bulk DensityN/A
Decomposition Temp.N/A
Solvent ContentN/A
Water ContentN/A
Surface TensionN/A
ConductivityN/A
Miscellaneous DataN/A
SolubilityN/A

10 - Stability and Reactivity

STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide,
and nitrogen oxides.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

11 - Toxicological Information

SENSITIZATION
Sensitization: Possible sensitizer.
Skin: Prolonged or repeated exposure may cause allergic
reactions in certain sensitive individuals. The preceding data,
or interpretation of data, was determined using Quantitative
Structure Activity Relationship (QSAR) modeling.
ROUTE OF EXPOSURE
Skin Contact: Causes skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes severe eye irritation.
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract. May be harmful if inhaled.
Ingestion: Toxic if swallowed.

12 - Ecological Information

No data available.
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13 - Disposal Considerations

SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.

14 - Transport Information

RID/ADR
UN#: 2810
Class: 6.1
PG: III
Proper Shipping Name: Toxic liquid, organic, n.o.s.
IMDG
UN#: 2810
Class: 6.1
PG: III
Proper Shipping Name: Toxic liquid, organic, n.o.s.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 2810
Class: 6.1
PG: III
Proper Shipping Name: Toxic liquid, organic, n.o.s.
Inhalation Packing Group I: No
Technical Name: Required

15 - Regulatory Information

CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: Xn
Harmful.
R-PHRASES: 22-37/38-41
Harmful if swallowed. Irritating to respiratory system and
skin. Risk of serious damage to eyes.
S-PHRASES: 26-36/37/39
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. Wear suitable protective
clothing, gloves, and eye/face protection.

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
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Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
ALDRICHwww.molbase.com


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Risk Phrases 20/21/22-36/37/38
Safety Phrases 26-36/37/39
HS Code 2933399090

 Synthetic Route

~95%

Pyridine,2-(2-propen-1-yloxy)- Structure

Pyridine,2-(2-p...

CAS#:5831-77-6

Literature: Yadav; Subba Reddy; Reddy, M. Muralidhar Tetrahedron Letters, 2000 , vol. 41, # 15 p. 2663 - 2665

~%

Pyridine,2-(2-propen-1-yloxy)- Structure

Pyridine,2-(2-p...

CAS#:5831-77-6

Literature: Vavilina; Zicmanis; Mekss; Klavins Chemistry of Heterocyclic Compounds, 2008 , vol. 44, # 5 p. 549 - 558 Khim. Geterotsikl. Soedin., 2008 , # 5 p. 699 - 710

~%

Pyridine,2-(2-propen-1-yloxy)- Structure

Pyridine,2-(2-p...

CAS#:5831-77-6

Literature: Vavilina; Zicmanis; Mekss; Klavins Chemistry of Heterocyclic Compounds, 2008 , vol. 44, # 5 p. 549 - 558 Khim. Geterotsikl. Soedin., 2008 , # 5 p. 699 - 710

~%

Pyridine,2-(2-propen-1-yloxy)- Structure

Pyridine,2-(2-p...

CAS#:5831-77-6

Literature: Westwell, Andrew D.; Williams, Jonathan M. J. Tetrahedron, 1997 , vol. 53, # 38 p. 13063 - 13078

~%

Pyridine,2-(2-propen-1-yloxy)- Structure

Pyridine,2-(2-p...

CAS#:5831-77-6

Literature: Michant'ew et al. Zhurnal Obshchei Khimii, 1959 , vol. 29, p. 1874;engl.Ausg.S.1844

 Customs

HS Code 2933399090
Summary 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

2-Allyloxy-pyridin
2-ALLYLOXYPYRIDINE
Allyl 2-pyridyl ether
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