ethyl alpha-oxo[1,1'-biphenyl]-4-acetate

Modify Date: 2025-09-18 07:12:12

ethyl alpha-oxo[1,1'-biphenyl]-4-acetate Structure
ethyl alpha-oxo[1,1'-biphenyl]-4-acetate structure
 Common Name ethyl alpha-oxo[1,1'-biphenyl]-4-acetate
CAS Number 6244-53-7 Molecular Weight 254.28100
Density 1.141g/cm3 Boiling Point 395ºC at 760 mmHg
Molecular Formula C16H14O3 Melting Point N/A
MSDS USA Flash Point 185.3ºC

 Names

Name ethyl 2-oxo-2-(4-phenylphenyl)acetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.141g/cm3
Boiling Point 395ºC at 760 mmHg
Molecular Formula C16H14O3
Molecular Weight 254.28100
Flash Point 185.3ºC
Exact Mass 254.09400
PSA 43.37000
LogP 3.09940
Index of Refraction 1.558
InChIKey JSNHSBCQHIQENB-UHFFFAOYSA-N
SMILES CCOC(=O)C(=O)c1ccc(-c2ccccc2)cc1

 Safety Information

HS Code 2918300090

 Synthetic Route

Diethyloxalate structure

Diethyloxalate

CAS#:95-92-1

~54%

ethyl alpha-oxo[1,1'-biphenyl]-4-acetate Structure

ethyl alpha-oxo...

CAS#:6244-53-7

Literature: UNIVERSITY OF CONNECTICUT Patent: WO2008/13963 A2, 2008 ; Location in patent: Page/Page column 96 ; WO 2008/013963 A2
4-Bromobiphenyl structure

4-Bromobiphenyl

CAS#:92-66-0

Diethyloxalate structure

Diethyloxalate

CAS#:95-92-1

~%

ethyl alpha-oxo[1,1'-biphenyl]-4-acetate Structure

ethyl alpha-oxo...

CAS#:6244-53-7

Literature: WO2009/52319 A1, ; Page/Page column 140 ; WO 2009/052319 A1
Biphenyl structure

Biphenyl

CAS#:92-52-4

Ethoxalyl chloride structure

Ethoxalyl chloride

CAS#:4755-77-5

~60%

ethyl alpha-oxo[1,1'-biphenyl]-4-acetate Structure

ethyl alpha-oxo...

CAS#:6244-53-7

Literature: Neidlein; Hofmann Arzneimittel-Forschung, 1983 , vol. 33, # 5 p. 691 - 693
Ethanol structure

Ethanol

CAS#:64-17-5

1-(biphenyl-4-yl)-2,2-dibromoethanone structure

1-(biphenyl-4-y...

CAS#:28179-30-8

~71%

ethyl alpha-oxo[1,1'-biphenyl]-4-acetate Structure

ethyl alpha-oxo...

CAS#:6244-53-7

Literature: Raghunadh, Akula; Meruva, Suresh Babu; Kumar, Nuka Anil; Kumar, Gudla Santosh; Rao, L. Vaikunta; Syamkumar Synthesis, 2012 , vol. 2012, # 2 p. 283 - 289
4-Iodobiphenyl structure

4-Iodobiphenyl

CAS#:1591-31-7

~%

ethyl alpha-oxo[1,1'-biphenyl]-4-acetate Structure

ethyl alpha-oxo...

CAS#:6244-53-7

Literature: Journal of Organic Chemistry, , vol. 55, # 10 p. 3114 - 3118
4-Ethylbiphenyl structure

4-Ethylbiphenyl

CAS#:5707-44-8

ethyl acetate structure

ethyl acetate

CAS#:141-78-6

~52%

ethyl alpha-oxo[1,1'-biphenyl]-4-acetate Structure

ethyl alpha-oxo...

CAS#:6244-53-7

Literature: Tada, Norihiro; Ban, Kazunori; Nobuta, Tomoya; Hirashima, Shin-Ichi; Miura, Tsuyoshi; Itoh, Akichika Synlett, 2011 , # 10 art. no. U01411ST, p. 1381 - 1384
4-Biphenylmagnesium bromide solution structure

4-Biphenylmagne...

CAS#:3315-91-1

Diethyloxalate structure

Diethyloxalate

CAS#:95-92-1

~%

ethyl alpha-oxo[1,1'-biphenyl]-4-acetate Structure

ethyl alpha-oxo...

CAS#:6244-53-7

Literature: Angewandte Chemie - International Edition, , vol. 52, # 47 p. 122414 - 122417 Angew. Chem., , p. 12640 - 12643,4

 Customs

HS Code 2918300090
Summary 2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Synonyms

ethyl 4-phenylphenylglyoxylate
EINECS 228-355-9
biphenyl-4-yl-glyoxylic acid ethyl ester
Ethyl 4-biphenylylglyoxylate
ethyl 2-([1,1'-biphenyl]-4-yl)-2-oxoacetate
ETHYL 4-PHENYLBENZOYLFORMATE
ethyl |A-oxo(1,1'-biphenyl)-4-acetate
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