4-Methylphenylhydrazine hydrochloride

Modify Date: 2024-01-02 16:52:14

4-Methylphenylhydrazine hydrochloride structure	Common Name	4-Methylphenylhydrazine hydrochloride
	CAS Number	637-60-5	Molecular Weight	158.629
	Density	1.18	Boiling Point	242.8ºC at 760 mmHg
	Molecular Formula	C₇H₁₁ClN₂	Melting Point	241 ºC
	MSDS	Chinese USA	Flash Point	115.3ºC
	Symbol	GHS06	Signal Word	Danger

Name	p-Tolylhydrazine Hydrochloride
Synonym	More Synonyms

Density	1.18
Boiling Point	242.8ºC at 760 mmHg
Melting Point	241 ºC
Molecular Formula	C₇H₁₁ClN₂
Molecular Weight	158.629
Flash Point	115.3ºC
Exact Mass	158.061081
PSA	38.05000
LogP	2.85590
Water Solubility	soluble

4-Methylphenylhydrazine hydrochloride MSDS(Chinese)

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MW0195000

CHEMICAL NAME :: Hydrazine, p-tolyl-, hydrochloride

CAS REGISTRY NUMBER :: 637-60-5

LAST UPDATED :: 199712

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C7-H10-N2.Cl-H

MOLECULAR WEIGHT :: 158.65

WISWESSER LINE NOTATION :: ZMR D1 &GH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 262 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Lungs, Thorax, or Respiration - cyanosis Skin and Appendages - hair

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 237 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Lungs, Thorax, or Respiration - cyanosis Skin and Appendages - hair

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1750 mg/kg/7W-I

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Vascular - tumors Lungs, Thorax, or Respiration - tumors

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 3640 mg/kg/26W-I

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Tumorigenic - tumors at site of application

TYPE OF TEST :: TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1400 mg/kg/10W-I

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 800 ug/plate

REFERENCE :: NEZAAQ Nippon Eiseigaku Zasshi. Japanese Journal of Hygiene. (Nippon Eisei Gakkai, c/o Kyoto Daigaku Igakubu, Konoe-cho, Yoshida, Sakyo-ku, Kyoto 606, Japan) V.1- 1946- Volume(issue)/page/year: 33,474,1978

Symbol	GHS06
Signal Word	Danger
Hazard Statements	H301-H315-H319-H335
Precautionary Statements	P261-P301 + P310-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes	Xn:Harmful
Risk Phrases	R22;R36/37/38;R40
Safety Phrases	S26-S36-S36/37/39
RIDADR	UN 2811 6.1/PG 3
WGK Germany	3
RTECS	MW0195000
Packaging Group	III
Hazard Class	6.1
HS Code	29280090

p-Toluidine

CAS#:106-49-0

~61%

4-Methylphenylh...

CAS#:637-60-5

Literature: UCHREZHDENIE ROSSIISKOI AKADEMII NAUK INSTITUT MOLEKULYARNOI BIOLOGII IM. V.A. ENGELGARDTA RAN (IMB RAN) Patent: EP2157088 A1, 2010 ; Location in patent: Page/Page column 41-42 ;

4-Bromotoluene

CAS#:106-38-7

~67%

4-Methylphenylh...

CAS#:637-60-5

Literature: Kurandina, Daria V.; Eliseenkov, Eugene V.; Ilyin, Petr V.; Boyarskiy, Vadim P. Tetrahedron, 2014 , vol. 70, # 26 p. 4043 - 4048

N-(4-methylphen...

CAS#:40594-88-5

~99%

4-Methylphenylh...

CAS#:637-60-5

Literature: Mauger, Christelle C.; Mignani, Gerard A. Organic Process Research and Development, 2004 , vol. 8, # 6 p. 1065 - 1071

3-(4-methylphen...

CAS#:3483-19-0

~74%

4-Methylphenylh...

CAS#:637-60-5

Literature: Kuo; Lee; Yeh Journal of the Chinese Chemical Society, 2000 , vol. 47, # 1 p. 227 - 240

4-Chlorotoluene

CAS#:106-43-4

4-Methylphenylh...

CAS#:637-60-5

Literature: Organic Process Research and Development, , vol. 8, # 6 p. 1065 - 1071

4-Iodotoluene

CAS#:624-31-7

4-Methylphenylh...

CAS#:637-60-5

Literature: RSC Advances, , vol. 4, # 7 p. 3364 - 3367

Precursor 5
CAS#:106-49-0 p-Toluidine CAS#:106-38-7 4-Bromotoluene CAS#:3483-19-0 3-(4-methylphen... CAS#:106-43-4 4-Chlorotoluene
CAS#:624-31-7 4-Iodotoluene
DownStream 10
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HS Code	2928000090
Summary	2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

A new method for N-N bond cleavage of N,N-disubstituted hydrazines to secondary amines and direct ortho amination of naphthol and its analogues.

J. Am. Chem. Soc. 130(18) , 5840-1, (2008)

An unexpected reaction of N,N-disubstituted hydrazine with naphthol and its analogues under simply thermal conditions has been disclosed. 2-Naphthol reacted with various N,N-disubstituted hydrazines u...

Studies of the tumorigenic potential of 4-substituted phenylhydrazines by the subcutaneous route.

J. Toxicol. Environ. Health A 8(1-2) , 1-9, (1981)

4-Methylphenylhydrazine hydrochloride (4-MPH) was administered to randomly bred Swiss mice as 26 weekly sc injections of 140 microgram per gram of body weight and N'-acetyl-4-(hydroxymethyl)phenylhydr...

Measurement of a genotoxic hydrazine, agaritine, and its derivatives by HPLC with fluorescence derivatization in the agaricus mushroom and its products.

Chem. Pharm. Bull. 54(6) , 922-4, (2006)

Agaricus blazei MURRILL mushroom products are sold as so-called health foods in Japan. However, a part of Agaricus is known to contain hydrazines. A sensitive and specific method for analyzing a genot...

P-methylphenylhydrazine hydrochloride

Hydrazine, p-tolyl-, monohydrochloride (8CI)

(4-Methylphenyl)hydrazinium chloride

EINECS 211-295-2

(4-methylphenyl)hydrazine hydrochloride

4-Methyl Phenyl Hydrazine Hydrochloride

Hydrazine, (4-methylphenyl)-, hydrochloride (1:1)

(4-Methylphenyl)hydrazinhydrochlorid

4-Methylphenylhydrazine hydrochloride

(4-Methylphenyl)hydrazine hydrochloride (1:1)

MFCD00012940

Shanghai Jizhi Biochemical Technology Co., Ltd
China
Product Name: 4-Methylphenylhydrazine hydrochloride
Price: ￥468.0/100g ￥158.0/25g
Purity: 98.0%
Stocking Period: 2 Day
Contact: Liu jia

Dayang Chem (Hangzhou) Co., Ltd.
China
Product Name: 4-Methylphenylhydrazine hydrochloride
Price: $Inquiry/100g $Inquiry/1kg $Inquiry/100kg $Inquiry/1000kg
Purity: 98.0%
Stocking Period: Inquiry
Contact: Ms Wang

Henan Tianfu Chemical Co., Ltd.
China
Product Name: TIANFU-CHEM 4-Methylphenylhydrazine hydrochloride
Price: $Inquiry/1kg $Inquiry/25kg $Inquiry/1000kg $Inquiry/10ton
Purity: 99.0%
Stocking Period: Inquiry
Contact: Anson

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4-Methylphenylhydrazine hydrochloride

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CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

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