N'-Isopropylidene-2-nitrobenzenesulfonohydrazide

Modify Date: 2024-01-06 15:09:12

N'-Isopropylidene-2-nitrobenzenesulfonohydrazide Structure
N'-Isopropylidene-2-nitrobenzenesulfonohydrazide structure
Common Name N'-Isopropylidene-2-nitrobenzenesulfonohydrazide
CAS Number 6655-27-2 Molecular Weight 257.266
Density 1.4±0.1 g/cm3 Boiling Point 421.3±47.0 °C at 760 mmHg
Molecular Formula C9H11N3O4S Melting Point 131-135ºC
MSDS USA Flash Point 208.6±29.3 °C

 Names

Name N-Isopropylidene-N-2-Nitrobenzenesulfonohydrazide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 421.3±47.0 °C at 760 mmHg
Melting Point 131-135ºC
Molecular Formula C9H11N3O4S
Molecular Weight 257.266
Flash Point 208.6±29.3 °C
Exact Mass 257.047028
PSA 112.73000
LogP 1.02
Vapour Pressure 0.0±1.0 mmHg at 25°C
Index of Refraction 1.603
Storage condition <0°C

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard Codes Xi
RIDADR NONH for all modes of transport
WGK Germany 3.0

 Synthetic Route

~97%

N'-Isopropylidene-2-nitrobenzenesulfonohydrazide Structure

N'-Isopropylide...

CAS#:6655-27-2

Literature: Movassaghi, Mohammad; Piizzi, Grazia; Siegel, Dustin S.; Piersanti, Giovanni Angewandte Chemie - International Edition, 2006 , vol. 45, # 35 p. 5859 - 5863

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N'-Isopropylidene-2-nitrobenzenesulfonohydrazide Structure

N'-Isopropylide...

CAS#:6655-27-2

Literature: Bulletin of the Chemical Society of Japan, , vol. 58, # 1 p. 377 - 378

 Articles2

More Articles
N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine, a reagent for reduction of alcohols via the corresponding monoalkyl diazenes.

J. Org. Chem. 72 , 1838, (2007)

The reagent N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine (IPNBSH) is used in the reduction of alcohols via the loss of dinitrogen from transiently formed monoalkyl diazene intermediates access...

A stereospecific palladium-catalyzed route to monoalkyl diazenes for mild allylic reduction.

Angew. Chem. Int. Ed. Engl. 47 , 8909, (2008)

 Synonyms

2-nitro-N-(propan-2-ylideneamino)benzenesulfonamide
MFCD09800525
Benzenesulfonic acid, 2-nitro-, 2-(1-methylethylidene)hydrazide
N'-Isopropylidene-2-nitrobenzenesulfonohydrazide