2-(Difluoromethoxy)benzaldehyde
2-(Difluoromethoxy)benzaldehyde structure
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Common Name | 2-(Difluoromethoxy)benzaldehyde | ||
|---|---|---|---|---|
| CAS Number | 71653-64-0 | Molecular Weight | 172.129 | |
| Density | 1.3±0.1 g/cm3 | Boiling Point | 226.6±30.0 °C at 760 mmHg | |
| Molecular Formula | C8H6F2O2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 88.4±19.4 °C | |
| Name | 2-(Difluoromethoxy)benzaldehyde |
|---|---|
| Synonym | More Synonyms |
| Density | 1.3±0.1 g/cm3 |
|---|---|
| Boiling Point | 226.6±30.0 °C at 760 mmHg |
| Molecular Formula | C8H6F2O2 |
| Molecular Weight | 172.129 |
| Flash Point | 88.4±19.4 °C |
| Exact Mass | 172.033585 |
| PSA | 26.30000 |
| LogP | 1.89 |
| Vapour Pressure | 0.1±0.4 mmHg at 25°C |
| Index of Refraction | 1.498 |
| Personal Protective Equipment | Eyeshields;Gloves |
|---|---|
| Hazard Codes | Xi:Irritant; |
| Risk Phrases | R36/38 |
| Safety Phrases | S26-S36-S37/39 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
| HS Code | 2913000090 |
|
~%
2-(Difluorometh... CAS#:71653-64-0 |
| Literature: US2002/35147 A1, ; US 20020035147 A1 |
|
~92%
2-(Difluorometh... CAS#:71653-64-0 |
| Literature: Shelyazhenko, S. V.; Fialkov, Yu. A.; Yagupol'skii, L. M. Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 8.1 p. 1317 - 1324 Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 8 p. 1652 - 1660 |
|
~74%
2-(Difluorometh... CAS#:71653-64-0 |
| Literature: Li, Lingchun; Wang, Fei; Ni, Chuanfa; Hu, Jinbo Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12390 - 12394 Angew. Chem., 2013 , vol. 125, # 47 p. 12616 - 12620,5 |
| Precursor 3 | |
|---|---|
| DownStream 10 | |
![5-acetyl-4-[2-(difluoromethoxy)phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one structure](https://image.chemsrc.com/caspic/190/112002-56-9.png)
CAS#:112002-56-9![methyl 6-[2-(difluoromethoxy)phenyl]-3,4-dimethyl-2-oxo-1,6-dihydropyrimidine-5-carboxylate structure](https://image.chemsrc.com/caspic/016/111983-60-9.png)
CAS#:111983-60-9![bis(2-methylpropyl) 4-[2-(difluoromethoxy)phenyl]-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate structure](https://image.chemsrc.com/caspic/366/110544-72-4.png)
CAS#:110544-72-4![3-[2-(DIFLUOROMETHOXY)PHENYL]ACRYLIC ACID structure](https://image.chemsrc.com/caspic/451/127842-71-1.png)
CAS#:127842-71-1
CAS#:127842-69-7![ethyl 5-cyano-4-[2-(difluoromethoxy)phenyl]-2,6-dimethyl-1,4-dihydropyridine-3-carboxylate structure](https://image.chemsrc.com/caspic/285/100507-48-0.png)
CAS#:100507-48-0![4-[2-(difluoromethoxy)phenyl]-2,6-dimethyl-3-N,5-N-diphenyl-1,4-dihydropyridine-3,5-dicarboxamide structure](https://image.chemsrc.com/caspic/271/100568-69-2.png)
CAS#:100568-69-2![methyl 5-cyano-4-[2-(difluoromethoxy)phenyl]-2,6-dimethyl-1,4-dihydropyridine-3-carboxylate structure](https://image.chemsrc.com/caspic/333/100507-47-9.png)
CAS#:100507-47-9![ethyl 4-[2-(difluoromethoxy)phenyl]-6-methyl-2-sulfanylidene-3,4-dihydro-1H-pyrimidine-5-carboxylate structure](https://image.chemsrc.com/caspic/475/121112-80-9.png)
CAS#:121112-80-9![ditetradecyl 4-[2-(difluoromethoxy)phenyl]-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate structure](https://image.chemsrc.com/caspic/368/117654-54-3.png)
CAS#:117654-54-3| HS Code | 2913000090 |
|---|---|
| Summary | HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0% |
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Effect of acyl chain length and branching on the enantioselectivity of Candida rugosa lipase in the kinetic resolution of 4-(2-difluoromethoxyphenyl)-substituted 1,4-dihydropyridine 3,5-diesters.
J. Org. Chem. 67(2) , 401-10, (2002) Since 2,6-dimethyl-4-aryl-1,4-dihydropyridine 3,5-diesters themselves are not hydrolyzed by commercially available hydrolases, derivatives with spacers containing a hydrolyzable group were prepared. S... |
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Synthesis of 3-alkoxycarbonyl-6-alkylsulfanyl-4-[2-(difluoromethoxy) phenyl]-1, 4-dihydropyridines and related derivatives as analogs of cognition enhancer cerebrocrast. Krauze A, et al.
Chem. Heterocycl. Comp. 49(4) , 566-73, (2013)
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Synthesis and enantioselective lipase-catalyzed kinetic resolution of methyl 6-(methoxycarbonyl-methyl) sulfanyl-1, 4-dihydropyridine-3-carboxylates. Andzans Z, et al.
Chem. Heterocycl. Comp. 49(13) , 421-27, (2013)
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| Benzaldehyde, 2-(difluoromethoxy)- |
| MFCD00042251 |
| 2-(Difluoromethoxy)benzaldehyde |
| α,α-Difluoro-o-anisaldehyde |
| VHR BOYFF |
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