Chloromethyl 4-chlorophenyl sulfide

Modify Date: 2024-01-02 10:11:59

Chloromethyl 4-chlorophenyl sulfide Structure
Chloromethyl 4-chlorophenyl sulfide structure
Common Name Chloromethyl 4-chlorophenyl sulfide
CAS Number 7205-90-5 Molecular Weight 193.094
Density 1.3±0.1 g/cm3 Boiling Point 261.9±0.0 °C at 760 mmHg
Molecular Formula C7H6Cl2S Melting Point 21.5°C
MSDS Chinese USA Flash Point 103.2±20.3 °C
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 1-chloro-4-(chloromethylsulfanyl)benzene
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 261.9±0.0 °C at 760 mmHg
Melting Point 21.5°C
Molecular Formula C7H6Cl2S
Molecular Weight 193.094
Flash Point 103.2±20.3 °C
Exact Mass 191.956726
PSA 25.30000
LogP 3.67
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.601

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CZ0200000
CHEMICAL NAME :
Benzene, 1-chloro-4-(chloromethylthio)-
CAS REGISTRY NUMBER :
7205-90-5
BEILSTEIN REFERENCE NO. :
2043507
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C7-H6-Cl2-S
MOLECULAR WEIGHT :
193.09
WISWESSER LINE NOTATION :
G1SR DG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,996,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,996,1986

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C
Risk Phrases R34
Safety Phrases S26;S27;S28;S45;S36/S37/S39
RIDADR UN 3265
WGK Germany 3
RTECS CZ0200000
Packaging Group III

 Synthetic Route

~96%

Chloromethyl 4-chlorophenyl sulfide Structure

Chloromethyl 4-...

CAS#:7205-90-5

Literature: Morgan, Kate F.; Hollingsworth, Ian A.; Bull, James A. Chemical Communications, 2014 , vol. 50, # 40 p. 5203 - 5205

~37%

Chloromethyl 4-chlorophenyl sulfide Structure

Chloromethyl 4-...

CAS#:7205-90-5

Literature: Miyamoto, Toru; Yamamoto, Izuru Agricultural and Biological Chemistry, 1980 , vol. 44, # 11 p. 2581 - 2586

~73%

Chloromethyl 4-chlorophenyl sulfide Structure

Chloromethyl 4-...

CAS#:7205-90-5

Literature: Ono, Noboru; Miyake, Hideyoshi; Saito, Tadashi; Kaji, Aritsune Synthesis, 1980 , # 11 p. 952 - 953

~89%

Chloromethyl 4-chlorophenyl sulfide Structure

Chloromethyl 4-...

CAS#:7205-90-5

Literature: Ishibashi, Hiroyuki; Nakatani, Hiroshi; Maruyama, Kazumi; Minami, Kenjiro; Ikeda, Masazumi Journal of the Chemical Society, Chemical Communications, 1987 , # 19 p. 1443 - 1445

~%

Chloromethyl 4-chlorophenyl sulfide Structure

Chloromethyl 4-...

CAS#:7205-90-5

Literature: Journal of the American Chemical Society, , vol. 77, p. 572,576

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Chloromethyl 4-chlorophenyl sulfide Structure

Chloromethyl 4-...

CAS#:7205-90-5

Literature: DE957213 , ; DE845511 , ; DRP/DRBP Org.Chem.

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Chloromethyl 4-chlorophenyl sulfide Structure

Chloromethyl 4-...

CAS#:7205-90-5

Literature: Phosphorus and Sulfur and the Related Elements, , vol. 17, p. 297 - 306

~%

Chloromethyl 4-chlorophenyl sulfide Structure

Chloromethyl 4-...

CAS#:7205-90-5

Literature: Journal of Applied Chemistry, , vol. 3, p. 266,273 Journal of Applied Chemistry, , vol. 4, p. 110,111

 Articles3

More Articles
Nucleophilic Participation in the Solvolyses of (Arylthio)methyl Chlorides and Derivatives: Application of Simple and Extended Forms of the Grunwald-Winstein Equations.

Curr. Org. Chem. 16(12) , 1502-1511, (2012)

The specific rates of solvolysis of chloromethyl phenyl sulfide [(phenylthio)methyl chloride] and its p-chloro-derivative have been determined at 0.0 _C in a wide range of hydroxylic solvents, includi...

Synthesis of α-Haloalkyl Esters from α-Arylthioalkyl Esters. Benneche T, et al.

Acta Chem. Scand. 43 , 74-77, (1988)

A new approach to the synthesis of 2-aminoimidazo [1, 2-a]pyridine derivatives through microwave-assisted N-alkylation of 2-halopyridines. Vega JA, et al.

Tetrahedron 55(8) , 2317-2326, (1999)

 Synonyms

Chloromethyl 4-chlorophenyl sulphide
Chloromethyl 4-chlorophenyl sulfide
Sulfide,chloromethyl p-chlorophenyl
MFCD00000922
Thiophenol,p-chloro-S-chloromethyl
BENZENE, 1-CHLORO-4-(CHLOROMETHYLTHIO)-
EINECS 230-578-1
1-Chloro-4-[(chloromethyl)sulfanyl]benzene
chloromethyl p-chlorophenyl sulfide
4-chlorophenylthio-methyl chloride
Chlormethyl-(4-chlor-phenyl)-sulfid
p-Chloro-S-chloromethylbenzenethiol
Benzene, 1-chloro-4-[(chloromethyl)thio]-
Sulfide, chloromethyl p-chlorophenyl
1-Chloro-4-(chloromethylthio)benzene
p-chlorophenyl chloromethyl sulfide
p-Chlorfenyl-chlormethylsulfid [Czech]