2-Acetyl-4-bromothiophene

Modify Date: 2024-01-09 18:01:40

2-Acetyl-4-bromothiophene Structure
2-Acetyl-4-bromothiophene structure
Common Name 2-Acetyl-4-bromothiophene
CAS Number 7209-11-2 Molecular Weight 205.072
Density 1.6±0.1 g/cm3 Boiling Point 284.4±25.0 °C at 760 mmHg
Molecular Formula C6H5BrOS Melting Point N/A
MSDS N/A Flash Point 125.8±23.2 °C

 Names

Name 1-(4-Bromo-2-Thienyl)Ethanone
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 284.4±25.0 °C at 760 mmHg
Molecular Formula C6H5BrOS
Molecular Weight 205.072
Flash Point 125.8±23.2 °C
Exact Mass 203.924438
PSA 45.31000
LogP 2.12
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.584

 MSDS

Name: 1-(4-Bromo-2-thienyl)ethan-1-one tech Material Safety Data Sheet
Synonym: 2-Acetyl-4-bromothiophen
CAS: 7209-11-2
Section 1 - Chemical Product MSDS Name:1-(4-Bromo-2-thienyl)ethan-1-one tech Material Safety Data Sheet
Synonym:2-Acetyl-4-bromothiophen

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7209-11-2 1-(4-Bromo-2-thienyl)ethan-1-one unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7209-11-2: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: pale yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H5BrOS
Molecular Weight: 205

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen bromide, bromine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7209-11-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-(4-Bromo-2-thienyl)ethan-1-one - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7209-11-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7209-11-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7209-11-2 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26-S36/37/39
HS Code 2934999090

 Synthetic Route

~97%

2-Acetyl-4-bromothiophene Structure

2-Acetyl-4-brom...

CAS#:7209-11-2

Literature: Gonzalez, Isabel C.; Davis, Leon N.; Smith II, Charles K. Bioorganic and Medicinal Chemistry Letters, 2004 , vol. 14, # 15 p. 4037 - 4043

~87%

2-Acetyl-4-bromothiophene Structure

2-Acetyl-4-brom...

CAS#:7209-11-2

Literature: Centre Europeen de Bioprospective-Ceb Patent: US6265423 B1, 2001 ; US 6265423 B1

~%

2-Acetyl-4-bromothiophene Structure

2-Acetyl-4-brom...

CAS#:7209-11-2

Literature: Chemical and Pharmaceutical Bulletin, , vol. 48, # 10 p. 1558 - 1566

~%

2-Acetyl-4-bromothiophene Structure

2-Acetyl-4-brom...

CAS#:7209-11-2

Literature: Chemistry of Heterocyclic Compounds, , vol. 49, # 3 p. 386 - 391 Khim. Geterotsikl. Soedin., , # 3 p. 416 - 422

~%

2-Acetyl-4-bromothiophene Structure

2-Acetyl-4-brom...

CAS#:7209-11-2

Literature: Bl. Univ. Osaka Prefect., , vol. 6, p. 127,128, 130 Nippon Kagaku Zasshi, , vol. 78, p. 950,962 Chem. Zentralbl., , vol. 129, p. 13204

~59%

2-Acetyl-4-bromothiophene Structure

2-Acetyl-4-brom...

CAS#:7209-11-2

Literature: Alvares-Insua, A. S.; Conde, S.; Corral, C. Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 713 - 716

~%

2-Acetyl-4-bromothiophene Structure

2-Acetyl-4-brom...

CAS#:7209-11-2

Literature: Doklady Akademii Nauk SSSR, , vol. 128, p. 536 Doklady Chemistry, 124-129 <1959> 767

 Customs

HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

MFCD01566552
2-Acetyl-4-bromothiophene
1-(4-bromothiophen-2-yl)ethanone
1-(4-bromothien-2-yl)ethanone
1-(4-Bromo-2-thienyl)ethanone
Ethanone, 1-(4-bromo-2-thienyl)-
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