Methyl 2-(bromomethyl)acrylate

Modify Date: 2025-08-25 21:24:25

Methyl 2-(bromomethyl)acrylate Structure
Methyl 2-(bromomethyl)acrylate structure
Common Name Methyl 2-(bromomethyl)acrylate
CAS Number 4224-69-5 Molecular Weight 179.012
Density 1.5±0.1 g/cm3 Boiling Point 187.1±0.0 °C at 760 mmHg
Molecular Formula C5H7BrO2 Melting Point N/A
MSDS Chinese USA Flash Point 78.3±0.0 °C
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name Methyl 2-(bromomethyl)acrylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 187.1±0.0 °C at 760 mmHg
Molecular Formula C5H7BrO2
Molecular Weight 179.012
Flash Point 78.3±0.0 °C
Exact Mass 177.962936
PSA 26.30000
LogP 1.88
Vapour Pressure 0.6±0.3 mmHg at 25°C
Index of Refraction 1.471
Storage condition 2-8°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AS4900000
CHEMICAL NAME :
Acrylic acid, 2-(bromomethyl)-, methyl ester
CAS REGISTRY NUMBER :
4224-69-5
LAST UPDATED :
199710
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C5-H7-Br-O2
MOLECULAR WEIGHT :
179.03

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-1090-1048S

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H315-H318-H335
Precautionary Statements P261-P280-P305 + P351 + P338
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36-S37/39
RIDADR UN 2810 6.1/PG 2
WGK Germany 3
RTECS AS4900000
HS Code 2916190090

 Synthetic Route

~86%

Methyl 2-(bromomethyl)acrylate Structure

Methyl 2-(bromo...

CAS#:4224-69-5

Literature: Luehr, Susan; Holz, Jens; Zayas, Odalys; Seidelmann, Oliver; Domke, Lutz; Boerner, Armin Tetrahedron Asymmetry, 2013 , vol. 24, # 7 p. 395 - 401

~89%

Methyl 2-(bromomethyl)acrylate Structure

Methyl 2-(bromo...

CAS#:4224-69-5

Literature: Barrera, Jaime Bermejo; Silva, Margarita Hernandez; De Mon, Melchor Alvarez; Ranieri, Juan Pablo Pivel Patent: US2003/199575 A1, 2003 ;

~94%

Methyl 2-(bromomethyl)acrylate Structure

Methyl 2-(bromo...

CAS#:4224-69-5

Literature: Charlton, J. L.; Sayeed, V. A.; Lypka, G. N. Synthetic Communications, 1981 , vol. 11, # 11 p. 931 - 934

~69%

Methyl 2-(bromomethyl)acrylate Structure

Methyl 2-(bromo...

CAS#:4224-69-5

Literature: Khazaei, Ardeshir; Vaghei, Ramin Ghorbani; Karkhanei, Ebrahim Synthetic Communications, 2002 , vol. 32, # 14 p. 2107 - 2113

~76%

Methyl 2-(bromomethyl)acrylate Structure

Methyl 2-(bromo...

CAS#:4224-69-5

Literature: Drewes, Siegfried E.; Loizou, Georgia; Roos, Gregory H. P. Synthetic Communications, 1987 , vol. 17, # 3 p. 291 - 298

~%

Methyl 2-(bromomethyl)acrylate Structure

Methyl 2-(bromo...

CAS#:4224-69-5

Literature: Yu, Haibo; Yang, Huibin; Cui, Dongliang; Lv, Liang; Li, Bin Journal of Agricultural and Food Chemistry, 2011 , vol. 59, # 21 p. 11718 - 11726

 Customs

HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

 Articles4

More Articles
Structure-activity relationships of tulipalines, tuliposides, and related compounds as inhibitors of MurA.

Bioorg. Med. Chem. Lett. 20 , 5757-62, (2010)

The enzyme MurA performs an essential step in peptidoglycan biosynthesis and is therefore a target for the discovery of novel antibacterial compounds. We report here the inhibition of MurA by natural ...

Diastereocontrolled synthesis of enantioenriched 3,4-disubstituted beta-prolines.

J. Org. Chem. 72 , 398, (2007)

Enantioenriched 3,4-disubstituted beta-prolines have been prepared with a high diastereocontrol through a carbometalation reaction or through a domino Michael addition/carbometalation reaction.

Use of methyl 2-(bromomethyl) acrylate as a chain-transfer agent to yield functionalized macromonomers via conventional and living radical polymerizations. Bon, SAF, et al.

Macromolecules 33(16) , 5819-5824, (2000)

 Synonyms

Methyl 2-(bromomethyl)acrylate
2-Propenoic acid, 2-(bromomethyl)-, methyl ester (9CI)
2-(Bromomethyl)acrylic Acid Methyl Ester
methyl 2-(bromomethyl)prop-2-enoate
2-Propenoic acid, 2-(bromomethyl)-, methyl ester
MFCD00011697
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