1-(CHLOROMETHYL)-3,5-DINITROBENZENE

Modify Date: 2024-01-02 11:29:29

1-(CHLOROMETHYL)-3,5-DINITROBENZENE Structure
1-(CHLOROMETHYL)-3,5-DINITROBENZENE structure
Common Name 1-(CHLOROMETHYL)-3,5-DINITROBENZENE
CAS Number 74367-78-5 Molecular Weight 216.57900
Density 1.538 g/cm3 Boiling Point 373.4ºC at 760 mmHg
Molecular Formula C7H5ClN2O4 Melting Point 79-82ºC(lit.)
MSDS Chinese USA Flash Point 179.6ºC
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name 3,5-Dinitrobenzyl chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.538 g/cm3
Boiling Point 373.4ºC at 760 mmHg
Melting Point 79-82ºC(lit.)
Molecular Formula C7H5ClN2O4
Molecular Weight 216.57900
Flash Point 179.6ºC
Exact Mass 215.99400
PSA 91.64000
LogP 3.28820
Index of Refraction 1.614
Storage condition 2-8°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CZ0770000
CHEMICAL NAME :
Benzene, 1-(chloromethyl)-3,5-dinitro-
CAS REGISTRY NUMBER :
74367-78-5
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C7-H5-Cl-N2-O4
MOLECULAR WEIGHT :
216.59

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
50 ug/plate
REFERENCE :
SAIGBL Sangyo Igaku. Japanese Journal of Industrial Health. (Nippon Sangyo Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160, Japan) V.1- 1959- Volume(issue)/page/year: 29,34,1987

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H314-H335
Precautionary Statements P261-P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C: Corrosive;
Risk Phrases 34-36/37
Safety Phrases 26-36/37/39-45
RIDADR 3261.0
RTECS CZ0770000
Packaging Group III
HS Code 2904909090

 Synthetic Route

~85%

1-(CHLOROMETHYL)-3,5-DINITROBENZENE Structure

1-(CHLOROMETHYL...

CAS#:74367-78-5

Literature: Yang, Jye-Shane; Huang, Yao-Ting; Ho, Jinn-Hsuan; Sun, Wei-Ting; Huang, Hsin-Hau; Lin, Ying-Chih; Huang, Shing-Jong; Huang, Shou-Ling; Lu, Hsiu-Feng; Chao, Ito Organic Letters, 2008 , vol. 10, # 11 p. 2279 - 2282

~97%

1-(CHLOROMETHYL)-3,5-DINITROBENZENE Structure

1-(CHLOROMETHYL...

CAS#:74367-78-5

Literature: Newman, Stephen G.; Bryan, Christopher S.; Perez, Didier; Lautens, Mark Synthesis, 2011 , # 2 art. no. Z27210SS, p. 342 - 346

~%

1-(CHLOROMETHYL)-3,5-DINITROBENZENE Structure

1-(CHLOROMETHYL...

CAS#:74367-78-5

Literature: Journal of the American Chemical Society, , vol. 73, p. 2813,2818

 Customs

HS Code 2904909090
Summary HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Articles3

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Calixarenes. 27. Synthesis, characterization, and complexation studies of double-cavity calix [4] arenes. Gutsche CD and See KA.

J. Org. Chem. 57(16) , 4527-39, (1992)

Synthesis of non-symmetrical 3, 5-diamidobenzyl amines, ethers and sulfides. Barker D, et al.

Tetrahedron Lett. 49(10) , 1660-64, (2008)

Competitive flow immunoassay with fluorescence detection for determination of 4-nitrophenol. Nistor C, et al.

Anal. Chim. Acta 426(2) , 185-95, (2001)

 Synonyms

1-(chloromethyl)-3,5-dinitrobenzene
EINECS 277-841-7
MFCD00007234