Ethyl methylphenylglycidate

Modify Date: 2025-08-20 17:50:32

Ethyl methylphenylglycidate structure	Common Name	Ethyl methylphenylglycidate
	CAS Number	77-83-8	Molecular Weight	206.238
	Density	1.1±0.1 g/cm3	Boiling Point	273.5±30.0 °C at 760 mmHg
	Molecular Formula	C₁₂H₁₄O₃	Melting Point	N/A
	MSDS	Chinese USA	Flash Point	109.4±19.2 °C
	Symbol	GHS02, GHS07	Signal Word	Warning

Name	Ethyl 3-Methyl-3-Phenylglycidate
Synonym	More Synonyms

Density	1.1±0.1 g/cm3
Boiling Point	273.5±30.0 °C at 760 mmHg
Molecular Formula	C₁₂H₁₄O₃
Molecular Weight	206.238
Flash Point	109.4±19.2 °C
Exact Mass	206.094299
PSA	38.83000
LogP	2.43
Vapour Pressure	0.0±0.6 mmHg at 25°C
Index of Refraction	1.525

Ethyl methylphenylglycidate MSDS(Chinese)

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MW5250000

CHEMICAL NAME :: Hydrocinnamic acid, alpha,beta-epoxy-beta-methyl-, ethyl ester

CAS REGISTRY NUMBER :: 77-83-8

BEILSTEIN REFERENCE NO. :: 0012299

LAST UPDATED :: 199710

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C12-H14-O3

MOLECULAR WEIGHT :: 206.26

WISWESSER LINE NOTATION :: T3OTJ B1 BR& CVO2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5470 mg/kg

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - somnolence (general depressed activity) Skin and Appendages - hair

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 4050 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Gastrointestinal - other changes

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 182 gm/kg/2Y-C

TOXIC EFFECTS :: Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases Nutritional and Gross Metabolic - weight loss or decreased weight gain

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Ovary

DOSE/DURATION :: 16 mg/L

REFERENCE :: EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 10(Suppl 10),1,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83193 No. of Facilities: 35 (estimated) No. of Industries: 2 No. of Occupations: 18 No. of Employees: 2735 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83193 No. of Facilities: 1032 (estimated) No. of Industries: 8 No. of Occupations: 17 No. of Employees: 17149 (estimated) No. of Female Employees: 11946 (estimated)

Symbol	GHS02, GHS07
Signal Word	Warning
Hazard Statements	H226-H315-H319-H335
Precautionary Statements	P261-P305 + P351 + P338
Personal Protective Equipment	Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	Xi:Irritant
Risk Phrases	R10;R36/37/38
Safety Phrases	S16-S26-S36/37/39
RIDADR	UN 1993 3/PG 3
WGK Germany	2
RTECS	MW5250000
HS Code	2918990090

ethyl chloroacetate

CAS#:105-39-5

Acetophenone

CAS#:98-86-2

~88%

Ethyl methylphe...

CAS#:77-83-8

Literature: McCarthy, Daniel G.; Hegarty, Anthony F. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 579 - 591

ethyl dibromoacetate

CAS#:617-33-4

Acetophenone

CAS#:98-86-2

~90%

Ethyl methylphe...

CAS#:77-83-8

Literature: Concellon, Jose M.; Concellon, Carmen; Diaz, Pamela European Journal of Organic Chemistry, 2006 , # 9 p. 2197 - 2200

EDA

CAS#:623-73-4

Acetophenone

CAS#:98-86-2

~58%

Ethyl methylphe...

CAS#:77-83-8

Literature: Zhu, Zuolin; Espenson, James H. Journal of the American Chemical Society, 1996 , vol. 118, # 41 p. 9901 - 9907

Acetophenone

CAS#:98-86-2

Ethyl methylphe...

CAS#:77-83-8

Literature: Journal of Organometallic Chemistry, , vol. 336, p. C33 - C36

ethyl 2-chloro-...

CAS#:91767-65-6

~76%

Ethyl methylphe...

CAS#:77-83-8

Literature: Fuerstner, Alois Journal of Organometallic Chemistry, 1987 , vol. 336, p. C33 - C36

Precursor 5
CAS#:105-39-5 ethyl chloroacetate CAS#:98-86-2 Acetophenone CAS#:617-33-4 ethyl dibromoacetate CAS#:623-73-4 EDA
CAS#:91767-65-6 ethyl 2-chloro-...
DownStream 4
CAS#:492-37-5 DL-2-Phenylprop... CAS#:26304-51-8 3-Methyl-2-carb... CAS#:7306-12-9 hawthorn acetate CAS#:59647-78-8 2-Phenylpropion...

HS Code	2918990090
Summary	2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Long-term toxicity study of ethyl methylphenylglycidate (strawberry aldehyde) in the rat.

Food Cosmet. Toxicol. 19(6) , 691-9, (1981)

EINECS 201-061-8

2-Oxiranecarboxylic acid, 3-methyl-3-phenyl-, ethyl ester

3-Methyl-3-phenylglycidic acid ethyl ester

MFCD00022338

ethyl 3-methyl-3-phenyloxirane-2-carboxylate

Strawberry aldehyde

Ethyl methylphenylglycidate

Ethyl 3-methyl-2,3-epoxy-hydrocinamic acid

Ethyl 3-methyl-3-phenylglycidate

Ethyl 3-methyl-3-phenyl-2-oxiranecarboxylate

Ethyl 3-methyl-3-phenyl glycidate

Aldehyde C-16

3-Phenyl-2,3-epoxybutyic acid ethyl ester

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China
Product Name: Ethyl methylphenylglycidate
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China
Product Name: Ethyl methylphenylglycidate
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Dayang Chem (Hangzhou) Co., Ltd.
China
Product Name: Ethyl 3-methyl-3-phenylglycidate
Price: $Inquiry/100g $Inquiry/1kg $Inquiry/100kg $Inquiry/1000kg
Purity: 98.0%
Delivery: Inquiry
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Henan Tianfu Chemical Co., Ltd.
China
Product Name: 77-83-8
Price: $Inquiry/1kg $Inquiry/25kg $Inquiry/1000kg $Inquiry/10ton
Purity: 99.0%
Delivery: Inquiry
Contact: Anson
Email: info@tianfuchem.com

Zhongshan Xingrui Chemical Co. , Ltd.
China
Product Name: Ethyl methylphenylglycidate
Price: ￥Inquiry/25kg
Purity: 98.0%
Delivery: Inquiry
Contact: Wang Jie
Email: 3096638339@qq.com

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Ethyl methylphenylglycidate

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Chemical & Physical Properties

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

Safety Information

Synthetic Route

Precursor & DownStream

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