Fmoc-Glu-OtBu

Modify Date: 2025-08-22 13:56:37

Fmoc-Glu-OtBu Structure
Fmoc-Glu-OtBu structure
 Common Name Fmoc-Glu-OtBu
CAS Number 84793-07-7 Molecular Weight 425.474
Density 1.2±0.1 g/cm3 Boiling Point 638.1±55.0 °C at 760 mmHg
Molecular Formula C24H27NO6 Melting Point 110 °C
MSDS N/A Flash Point 339.7±31.5 °C

 Use of Fmoc-Glu-OtBu


N-(9-Fluorenylmethoxycarbonyl)glutamic acid α-tert-butyl ester is a glutamic acid derivative[1].

 Names

Name (4S)-4-(9H-fluoren-9-ylmethoxycarbonylamino)-5-[(2-methylpropan-2-yl)oxy]-5-oxopentanoic acid
Synonym More Synonyms

 Fmoc-Glu-OtBu Biological Activity

Description N-(9-Fluorenylmethoxycarbonyl)glutamic acid α-tert-butyl ester is a glutamic acid derivative[1].
Related Catalog
In Vitro Amino acids and amino acid derivatives have been commercially used as ergogenic supplements. They influence the secretion of anabolic hormones, supply of fuel during exercise, mental performance during stress related tasks and prevent exercise induced muscle damage. They are recognized to be beneficial as ergogenic dietary substances[1].
References

[1]. Luckose F, et al. Effects of amino acid derivatives on physical, mental, and physiological activities. Crit Rev Food Sci Nutr. 2015;55(13):1793-1144.

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 638.1±55.0 °C at 760 mmHg
Melting Point 110 °C
Molecular Formula C24H27NO6
Molecular Weight 425.474
Flash Point 339.7±31.5 °C
Exact Mass 425.183838
PSA 101.93000
LogP 5.26
Vapour Pressure 0.0±2.0 mmHg at 25°C
Index of Refraction 1.571
Storage condition Store at RT.

 MSDS

Material Safety Data Sheet
Section1. Identification of the substance
Product Name: Fmoc-Glu-OtBu
Synonyms:Fmoc-L-glutamic acid, alfa-tert-butyl ester
Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
Section3. Composition/information on ingredients.
Ingredient name:Fmoc-Glu-OtBu
CAS number:84793-07-7
Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.
Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.
Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.
Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels, refrigerated.
Storage:
Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.
Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
No data
Melting point:
Flash point:No data
Density:No data
Molecular formula:C24H27NO6
Molecular weight:425.5
Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides.
Section11. Toxicological information
No data.
Section12. Ecological information
No data.
Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.
Section14. Transportation information
Non-harzardous for air and ground transportation.
Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.

SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes C
Risk Phrases R34:Causes burns.
Safety Phrases S26-S36/37/39
RIDADR UN 3261 8/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 8

 Synthetic Route

H-Glu-OtBu structure

H-Glu-OtBu

CAS#:45120-30-7

Fmoc-Osu structure

Fmoc-Osu

CAS#:82911-69-1

~86%

Fmoc-Glu-OtBu Structure

Fmoc-Glu-OtBu

CAS#:84793-07-7

Literature: Abraham; Nair; Kisliuk; Gaumont; Galivan Journal of Medicinal Chemistry, 1990 , vol. 33, # 2 p. 711 - 717
(S)-2-(9H-fluoren-9-ylmethoxycarbonylamino)pentanedioic acid 5-benzyl ester 1-tert-butyl ester structure

(S)-2-(9H-fluor...

CAS#:157108-58-2

~%

Fmoc-Glu-OtBu Structure

Fmoc-Glu-OtBu

CAS#:84793-07-7

Literature: Journal of the Chemical Society. Perkin Transactions 1, , # 8 p. 1042 - 1049
Fmoc-Glu(OBzl)-OH structure

Fmoc-Glu(OBzl)-OH

CAS#:123639-61-2

~%

Fmoc-Glu-OtBu Structure

Fmoc-Glu-OtBu

CAS#:84793-07-7

Literature: Journal of the Chemical Society. Perkin Transactions 1, , # 8 p. 1042 - 1049
L-glutamic acid structure

L-glutamic acid

CAS#:56-86-0

9H-fluoren-9-ylmethyl 2,5-dioxopyrrolidine-1-carboxylate structure

9H-fluoren-9-yl...

CAS#:102774-86-7

Isobutylene structure

Isobutylene

CAS#:115-11-7

~%

Fmoc-Glu-OtBu Structure

Fmoc-Glu-OtBu

CAS#:84793-07-7

Detail
Literature: Synthesis, , # 7 p. 571 - 572

 Synonyms

(2S)-2-{[(9H-Fluoren-9-ylmethoxy)carbonyl]amino}-5-[(2-methyl-2-propanyl)oxy]-5-oxopentanoic acid
Fmoc-L-Glutamicacid1-tert-butylester
(4S)-4-{[(9H-Fluoren-9-ylmethoxy)carbonyl]amino}-5-[(2-methyl-2-propanyl)oxy]-5-oxopentanoic acid
(2S)-5-tert-Butoxy-2-{[(9H-fluoren-9-ylmethoxy)carbonyl]amino}-5-oxopentanoic acid (non-preferred name)
L-Glutamic acid, N-[(9H-fluoren-9-ylmethoxy)carbonyl]-, 1-(1,1-dimethylethyl) ester
Fmoc-L-Glu-O-t-Bu
(4S)-5-tert-Butoxy-4-{[(9H-fluoren-9-ylmethoxy)carbonyl]amino}-5-oxopentanoic acid (non-preferred name)
FMOC-GLU-OBUT
Fmoc-Glu-OtBu
L-Glutamic acid, N-[(9H-fluoren-9-ylmethoxy)carbonyl]-, 5-(1,1-dimethylethyl) ester
MFCD00065648
N-α-FMOC-L-glutamic acid α-tert-butyl ester
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