2-bromotetrafluoroethyltrifluorovinylether

Modify Date: 2024-01-02 13:25:17

2-bromotetrafluoroethyltrifluorovinylether Structure
2-bromotetrafluoroethyltrifluorovinylether structure
Common Name 2-bromotetrafluoroethyltrifluorovinylether
CAS Number 85737-06-0 Molecular Weight 276.93500
Density 1.902g/cm3 Boiling Point 84.1ºC at 760mmHg
Molecular Formula C4BrF7O Melting Point N/A
MSDS N/A Flash Point 1.1ºC

 Names

Name 1-bromo-1,1,2,2-tetrafluoro-2-(1,2,2-trifluoroethenoxy)ethane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.902g/cm3
Boiling Point 84.1ºC at 760mmHg
Molecular Formula C4BrF7O
Molecular Weight 276.93500
Flash Point 1.1ºC
Exact Mass 275.90200
PSA 9.23000
LogP 3.61860
Index of Refraction 1.344
Storage condition 2-8°C

 MSDS

2-Bromotetrafluoroethyl Trifluorovinyl Ether (stabilized Revision number: 5.3
with MEHQ)
SAFETY DATA SHEET

Section1. IDENTIFICATION
Product name:2-Bromotetrafluoroethyl Trifluorovinyl Ether (stabilized with MEHQ)
5.3

Section2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDSNot classified
HEALTH HAZARDS
Skin corrosion/irritationCategory 2
Category 2A
Serious eye damage/eye irritation
ENVIRONMENTAL HAZARDSNot classified
GHS label elements, including precautionary statements
Pictograms or hazard symbols
Warning
Signal word
Hazard statementsCauses skin irritation
Causes serious eye irritation
Precautionary statements:
Wash hands thoroughly after handling.
[Prevention]
Wear protective gloves/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
[Response]
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Gently wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash before reuse.
Other hazards which do notMay cause polimerization.
result in classification

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
2-Bromotetrafluoroethyl Trifluorovinyl Ether (stabilized with MEHQ)
Components:
Percent:>98.0%(GC)
85737-06-0
CAS Number:
Chemical Formula:C4BrF7O
2-Bromotetrafluoroethyl Trifluorovinyl Ether
(stabilized with MEHQ)

Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell.
Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. If skin irritation or rash occurs: Get medical advice/attention.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth.
A rescuer should wear personal protective equipment, such as rubber gloves and air-
Protection of first-aiders:
tight goggles.

Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, foam, water spray, carbon dioxide.
media:
Specific hazards arising This substance may polimerize explosively when heated or involved in a fire.
from the chemical:Container may explode when heated. Combat fire from a sheltered position.
Take care as it may decompose upon combustion or in high temperatures to
generate poisonous fume.
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
spraying with water. Eliminate all ignition sources if safe to do so.
Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions,Use personal protective equipment. Keep people away from and upwind of spill/leak.
protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
emergency procedures: around the leakage area by roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into a
containment and cleaning covered container. In case of large amount of spillage, contain a spill by bunding.
up: Adhered or collected material should be promptly disposed of, in accordance with
appropriate laws and regulations.

Section7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent generation of vapour or mist. Wash hands and face thoroughly after
handling.
Use a ventilation, local exhaust if vapour or aerosol will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Keep container tightly closed. Store in a refrigerator.
Storage conditions:
Store away from incompatible materials such as oxidizing agents.
Heat-sensitive
Packaging material:Comply with laws.

Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:Install a closed system or local exhaust as possible so that workers should not be
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Vapor respirator. Follow local and national regulations.
Protective gloves.
Hand protection:
2-Bromotetrafluoroethyl Trifluorovinyl Ether
(stabilized with MEHQ)

Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Eye protection:Safety glasses. A face-shield, if the situation requires.
Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Liquid
Form:Clear
Colour:Colorless - Almost colorless
Odour:No data available
pH: No data available
Melting point/freezing point:No data available
Boiling point/range:No data available
Flash point:No data available
Flammability or explosive
limits:
Lower:No data available
Upper:No data available
Relative density:1.80
Solubility(ies):
[Water]No data available
[Other solvents]No data available

Section10. STABILITY AND REACTIVITY
Chemical stability:Polymerization may occur under the influences of heat, light or on contact with
polymelization initiators such as peroxides etc.
Possibility of hazardous No special reactivity has been reported.
reactions:
Conditions to avoid:Heat, Light
Incompatible materials: Oxidizing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen fluoride, Hydrogen bromide
products:

Section11. TOXICOLOGICAL INFORMATION
Acute Toxicity:No data available
Skin corrosion/irritation: No data available
Serious eyeNo data available
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
IARC =No data available
NTP =No data available
Reproductive toxicity:No data available

Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
No data available
Fish:
Crustacea:No data available
No data available
Algae:
Persistence / degradability: No data available
No data available
Bioaccumulative
potential(BCF):
Mobility in soil
Log Pow:No data available
No data available
Soil adsorption (Koc):
Henry's LawNo data available
constant(PaM3/mol):
2-Bromotetrafluoroethyl Trifluorovinyl Ether
(stabilized with MEHQ)

Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. Observe all federal, state and local
regulations when disposing of the substance.

Section14. TRANSPORT INFORMATION
Hazards Class:Does not correspond to the classification standard of the United Nations
UN-No:Not listed

Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases 26-36/37/39
HS Code 2909199090

 Synthetic Route

~69%

2-bromotetrafluoroethyltrifluorovinylether Structure

2-bromotetraflu...

CAS#:85737-06-0

Literature: DAIKIN INDUSTRIES, LTD. Patent: US2007/185355 A1, 2007 ; Location in patent: Page/Page column 8 ;

 Precursor & DownStream

Precursor  1

DownStream  0

 Customs

HS Code 2909199090
Summary 2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

 Synonyms

PC9642
EINECS 288-516-4
MFCD02183517
2-Bromotetrafluoroethyl trifluorovinyl ether
CF2=CFOCF2CF2Br
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