Diethyl ethoxymethylenemalonate

Modify Date: 2025-08-21 07:18:52

Diethyl ethoxymethylenemalonate Structure
Diethyl ethoxymethylenemalonate structure
 Common Name Diethyl ethoxymethylenemalonate
CAS Number 87-13-8 Molecular Weight 216.231
Density 1.1±0.1 g/cm3 Boiling Point 280.0±0.0 °C at 760 mmHg
Molecular Formula C10H16O5 Melting Point -33°C
MSDS Chinese USA Flash Point 155.0±0.0 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name Diethyl ethoxymethylenemalonate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 280.0±0.0 °C at 760 mmHg
Melting Point -33°C
Molecular Formula C10H16O5
Molecular Weight 216.231
Flash Point 155.0±0.0 °C
Exact Mass 216.099777
PSA 61.83000
LogP 1.44
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.447
Storage condition Refrigerator
Water Solubility insoluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OO1100000
CHEMICAL NAME :
Malonic acid, (ethoxymethylene)-, diethyl ester
CAS REGISTRY NUMBER :
87-13-8
BEILSTEIN REFERENCE NO. :
0880058
LAST UPDATED :
199709
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C10-H16-O5
MOLECULAR WEIGHT :
216.26
WISWESSER LINE NOTATION :
2OVYVO2&U1O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,37,1990 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
925 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Behavioral - somnolence (general depressed activity) Gastrointestinal - other changes
REFERENCE :
ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 1,37,1990
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2227 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 60,1810,1971
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
44 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: 30101,11,1945

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn:Harmful
Risk Phrases R42/43
Safety Phrases S26-S36/37/39-S27-S24/25
RIDADR NONH for all modes of transport
WGK Germany 1
RTECS OO1100000
HS Code 2918990090

 Synthetic Route

 Customs

HS Code 2918990090
Summary 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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 Synonyms

2OVYVO2&U1O2
Propanedioic acid, 2-(ethoxymethylene)-, diethyl ester
Diethyl ethoxymethylenemalonate
Diethyl (ethoxymethylene)malonate
diethyl 2-(ethoxymethylidene)propanedioate
EINECS 201-725-7
MFCD00009148
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