Tetrahydrofurfuryl alcohol

Modify Date: 2025-08-20 16:15:20

Tetrahydrofurfuryl alcohol Structure
Tetrahydrofurfuryl alcohol structure
Common Name Tetrahydrofurfuryl alcohol
CAS Number 97-99-4 Molecular Weight 102.132
Density 1.0±0.1 g/cm3 Boiling Point 176.8±8.0 °C at 760 mmHg
Molecular Formula C5H10O2 Melting Point -80ºC
MSDS Chinese USA Flash Point 83.9±0.0 °C
Symbol GHS07 GHS08
GHS07, GHS08
Signal Word Danger

 Names

Name Tetrahydrofurfuryl Alcohol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 176.8±8.0 °C at 760 mmHg
Melting Point -80ºC
Molecular Formula C5H10O2
Molecular Weight 102.132
Flash Point 83.9±0.0 °C
Exact Mass 102.068077
PSA 29.46000
LogP -0.39
Vapour density 3.52 (vs air)
Vapour Pressure 0.3±0.7 mmHg at 25°C
Index of Refraction 1.447
Water Solubility soluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LU2450000
CHEMICAL NAME :
2-Furanmethanol, tetrahydro-
CAS REGISTRY NUMBER :
97-99-4
BEILSTEIN REFERENCE NO. :
0102723
LAST UPDATED :
199710
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C5-H10-O2
MOLECULAR WEIGHT :
102.15
WISWESSER LINE NOTATION :
T5OTJ B1Q

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,786,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4658,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4658,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2300 mg/kg
TOXIC EFFECTS :
Behavioral - general anesthetic
REFERENCE :
HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 32(2),273,1967
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
725 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FEPRA7 Federation Proceedings, Federation of American Societies for Experimental Biology. (Bethesda, MD) V.1-46, 1942-87. Volume(issue)/page/year: 8,294,1949
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4658,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4658,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4658,1982 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83085 No. of Facilities: 1654 (estimated) No. of Industries: 9 No. of Occupations: 9 No. of Employees: 2169 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83085 No. of Facilities: 5004 (estimated) No. of Industries: 41 No. of Occupations: 33 No. of Employees: 81543 (estimated) No. of Female Employees: 48075 (estimated)

 Safety Information

Symbol GHS07 GHS08
GHS07, GHS08
Signal Word Danger
Hazard Statements H319-H360Df
Precautionary Statements P201-P280-P305 + P351 + P338-P308 + P313-P337 + P313
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36
Safety Phrases S39
RIDADR NA 1993 / PGIII
WGK Germany 2
RTECS LU2450000
Packaging Group I; II; III
HS Code 29321300

 Synthetic Route

 Customs

HS Code 2932130000
Summary HS: 2932130000. (tetrahydrofuran-2-yl)methanol. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tarrif:6.0%. general tariff:20.0%

 Articles11

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Toward surfactant-free and water-free microemulsions.

J. Colloid. Interface Sci. 453 , 186-93, (2015)

It was recently demonstrated that a nano-clustering was present in the monophasic "pre-Ouzo" region of ternary liquid mixtures without surfactants. The goal of this work is to check if this nano-clust...

Enantioselective synthesis of 4-heterosubstituted cyclopentenones.

J. Org. Chem. 78(8) , 4202-6, (2013)

Racemic 4-hydroxycyclopentenone, readily derived from furfuryl alcohol, can be transformed via its O-Boc derivative to 4-acyloxy, 4-aryloxy-, 4-amino-, or 4-thio-substituted cyclopentenones with high ...

Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol.

Chem. Commun. (Camb.) (15) , 2035-7, (2009)

Direct conversion of tetrahydrofurfuryl alcohol, which is one of the biomass-derived chemicals, to 1,5-pentanediol was realized by chemoselective hydrogenolysis catalyzed by Rh/SiO(2) modified with Re...

 Synonyms

2-Furanmethanol, tetrahydro-
(Tetrahydrofuran-2-yl)methanol
Tetrahydrofuran-2-ylmethanol
EINECS 202-625-6
MFCD00005372
THFA
Tetrahydro-2-furanylmethanol
Tetrahydrofurfuryl alcohol
2-Furanmethanol,tetrahydro-
T5OTJ B1Q
TETRAHYDROFURYL ALCOHOL
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