2,4′-dibromoacetophenone

Modify Date: 2025-08-21 07:50:11

2,4′-dibromoacetophenone Structure
2,4′-dibromoacetophenone structure
Common Name 2,4′-dibromoacetophenone
CAS Number 99-73-0 Molecular Weight 277.941
Density 1.8±0.1 g/cm3 Boiling Point 310.4±22.0 °C at 760 mmHg
Molecular Formula C8H6Br2O Melting Point 108-110 °C(lit.)
MSDS Chinese USA Flash Point 114.1±8.9 °C
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 2,4'-Dibromoacetophenone
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.8±0.1 g/cm3
Boiling Point 310.4±22.0 °C at 760 mmHg
Melting Point 108-110 °C(lit.)
Molecular Formula C8H6Br2O
Molecular Weight 277.941
Flash Point 114.1±8.9 °C
Exact Mass 275.878540
PSA 17.07000
LogP 2.95
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.604
Stability Stable. Incompatible with strong bases, strong reducing agents, strong oxidizing agents.

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AM6950000
CHEMICAL NAME :
Acetophenone, 2,4'-dibromo-
CAS REGISTRY NUMBER :
99-73-0
BEILSTEIN REFERENCE NO. :
0607604
LAST UPDATED :
199709
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C8-H6-Br2-O
MOLECULAR WEIGHT :
277.96
WISWESSER LINE NOTATION :
E1VR DE

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
MEXPAG Medicina Experimentalis. (Basel, Switzerland) V.1-11, 1959-64; V.18-19, 1968-69. For publisher information, see JNMDBO. Volume(issue)/page/year: 11,137,1964
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
18 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02407 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5162 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 28 (estimated)

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C:Corrosive;
Risk Phrases R34
Safety Phrases S26-S36/37/39-S45
RIDADR UN 3261 8/PG 2
WGK Germany 2
RTECS AM6950000
Packaging Group III
Hazard Class 8
HS Code 29147090

 Synthetic Route

 Customs

HS Code 2914700090
Summary HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

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 Synonyms

2-Bromo-1-(4-bromophenyl)ethanone
BromophenacylBromide
PBPB
2,4'-Dibromoacetophenone
p-Bromophenacyl bromide
2-bromo-1-(4-bromophenyl)-1-ethanone
Ethanone, 2-bromo-1- (4-bromophenyl)-
2-bromo-4'-bromoacetophenone
2,4`-Dibromoacetophenone
2,4'-Dibromo-acetophenone
α,p-Dibromoacetophenone
Ethanone, 2-bromo-1-(4-bromophenyl)-
2,3-DIFLUOROBENZOTRIFLUORIDE
2,4′-dibromoacetophenone
MFCD00000200
p-α-Dibromoacetophenone
2-bromo-1-(4-bromophenyl)ethan-1-one
EINECS 202-783-6
p-bromophenacyl-8
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