tert-Amyl methyl ether

Modify Date: 2024-01-02 13:07:10

tert-Amyl methyl ether Structure
tert-Amyl methyl ether structure
Common Name tert-Amyl methyl ether
CAS Number 994-05-8 Molecular Weight 102.17500
Density 0.77 g/mL at 25 °C(lit.) Boiling Point 85-86 °C(lit.)
Molecular Formula C6H14O Melting Point N/A
MSDS Chinese USA Flash Point 11 °F
Symbol GHS02 GHS06 GHS08
GHS02, GHS06, GHS08
Signal Word Danger

 Names

Name tert-Amyl methyl ether
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.77 g/mL at 25 °C(lit.)
Boiling Point 85-86 °C(lit.)
Molecular Formula C6H14O
Molecular Weight 102.17500
Flash Point 11 °F
Exact Mass 102.10400
PSA 9.23000
LogP 1.82140
Index of Refraction n20/D 1.389(lit.)
Storage condition Flammables area

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
EK4421000
CHEMICAL NAME :
Butane, 2-methoxy-2-methyl-
CAS REGISTRY NUMBER :
994-05-8
LAST UPDATED :
199806
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C6-H14-O

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 15,313,1995 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
14 gm/kg/28D-I
TOXIC EFFECTS :
Kidney, Ureter, Bladder - changes in bladder weight Endocrine - changes in adrenal weight
REFERENCE :
JJATDK JAT, Journal of Applied Toxicology. (John Wiley & Sons Ltd., Baffins Lane, Chichester, W. Sussex PO19 1UD, UK) V.1- 1981- Volume(issue)/page/year: 15,313,1995
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2000 ppm/6H/4W-I
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - coma Liver - liver function tests impaired
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0535711

 Safety Information

Symbol GHS02 GHS06 GHS08
GHS02, GHS06, GHS08
Signal Word Danger
Hazard Statements H225-H301 + H311 + H331-H370
Precautionary Statements P210-P260-P280-P301 + P310 + P330-P308 + P311-P403 + P233
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F,Xn,T
Risk Phrases R11;R20/22;R36/38
Safety Phrases S16-S26-S39-S45-S36/37
RIDADR UN 3271 3/PG 2
WGK Germany 3
RTECS EK4421000
Packaging Group II
Hazard Class 3.1
HS Code 2909199090

 Synthetic Route

 Customs

HS Code 2909199090
Summary 2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

 Articles26

More Articles
Degradation of fuel oxygenates and their main intermediates by Aquincola tertiaricarbonis L108.

Microbiology 154(Pt 5) , 1414-21, (2008)

Growth of Aquincola tertiaricarbonis L108 on the fuel oxygenates methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE) and tert-amyl methyl ether (TAME), as well as on their main metabolites t...

Air-water transfer of MTBE, its degradation products, and alternative fuel oxygenates: the role of temperature.

Environ. Sci. Technol. 38(20) , 5405-12, (2004)

The gasoline oxygenate methyl tert-butyl ether (MTBE) has become one of the world's mostwidespread groundwater and surface water contaminants. As a result, there has been increasing interest in the en...

Simultaneous determination of methyl tert-butyl ether, its degradation products and other gasoline additives in soil samples by closed-system purge-and-trap gas chromatography-mass spectrometry.

J. Chromatogr. A. 1132(1-2) , 28-38, (2006)

A new protocol for the simultaneous determination of methyl tert-butyl ether (MTBE); its main degradation products: tert-butyl alcohol (TBA) and tert-butyl formate (TBF); other gasoline additives, oxy...

 Synonyms

Tertiary Amyl Methyl Ether
METHYL-TERT-AMYLETHER
2-methoxy-2-methylbutane
EINECS 213-611-4
MFCD00010186
TERT-AMYLMETHYLETHER
BUTANE,2-METHOXY-2-METHYL-
NA-TOSYL-L-ARGININE METHYL ESTER HYDROCHLORIDE
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