Methyl 3-amino-2-thiophenecarboxylate

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Names

[ CAS No. ]:
22288-78-4

[ Name ]:
Methyl 3-amino-2-thiophenecarboxylate

[Synonym ]:
methyl-3-amino-2-thiophene formate
3-Amino-2-thiophenecarboxylic Acid Methyl Ester
3-amino-2-thiophene carboxylic acid methyl ester
3-amino-2-carbomethoxythiophene
Methyl 3-aminothiophene-2-carboxylate
3-Amino-thiophene-2-carboxylic acid methyl ester
2-Thiophenecarboxylic acid, 3-amino-, methyl ester
Methyl 3-amino-2-thiophenecarboxylate
T5SJ BVO1 CZ
3-Aminothiophene-2-carboxylic acid methyl ester
EINECS 244-895-8
MFCD00009765
3-aminothiophen-2-carboxylic acid methyl ester
2-methoxycarbonyl-3-amino-thiophene

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
334.6±0.0 °C at 760 mmHg

[ Melting Point ]:
62-64 °C(lit.)

[ Molecular Formula ]:
C6H7NO2S

[ Molecular Weight ]:
157.190

[ Flash Point ]:
138.1±22.3 °C

[ Exact Mass ]:
157.019745

[ PSA ]:
80.56000

[ LogP ]:
1.64

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.598

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39-S36/37/39-S22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
XM8347500

[ HS Code ]:
2934999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl 3-(2,2,2-trifluoroacetamido)thiophene-2-carboxylate
  • Nicotinaldehyde
  • Methyl tetrahydro-3-oxo-2-thenoate
  • Methanol
  • 3-Aminothiophene-2-carboxylic acid
  • 3-Chloroacrylonitrile
  • Methyl thioglycolate

DownStream

  • 2-(Carbomethoxy)thiophene
  • Methyl 3-chlorosulfonylthiophene-2-carboxylate
  • 3-Fluoro-2-thiophenecarboxylic acid
  • 3-Chlorothiophene-2-carboxylic acid
  • 7-Bromo-2,4-dichlorothieno[3,2-d]pyrimidine
  • 3-Acetamido-2-thiophenecarboxylic acid
  • Methyl 3-sulfamoyl-2-thiophenecarboxylate
  • Methyl 4-bromo-3-fluoro-2-thiophenecarboxylate
  • 3-TERT-BUTOXYCARBONYLAMINO-THIOPHENE-2-CARBOXYLIC ACID METHYL ESTER
  • 3-amino-2-methylthieno[3,2-d]pyrimidin-4-one

Customs

[ HS Code ]: 2934999090

[ Summary ]:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

A short synthesis of quinazolinocarboline alkaloids rutaecarpine, hortiacine, euxylophoricine A and euxylophoricine D from methyl N-(4-chloro-5H-1, 2, 3-dithiazol-5-ylidene) anthranilates. Mohanta PK and Kim K.

Tetrahedron Lett. 43(22) , 3993-96, (2002)

Synthesis and Properties of Some New 1, 4-Dihydrothieno [3, 2-e][1, 2, 4] triazepin-5-ones. Sabri SS, et al.

Z. Naturforsch. B 61(1) , 65, (2006)

The discovery and optimization of pyrimidinone-containing MCH R1 antagonists.

Bioorg. Med. Chem. Lett. 16(18) , 4723-27, (2006)

Optimization of a series of constrained melanin-concentrating hormone receptor 1 (MCH R1) antagonists has provided compounds with potent and selective MCH R1 activity. Details of the optimization proc...


More Articles

Related Compounds

  • methyl 3-amino-2-thiophenecarboxylate
  • Methyl 3-amino-2-thiophenecarboxylate hydrochloride (1:1)
  • Methyl 3-amino-5-formyl-2-thiophenecarboxylate
  • Methyl 3-amino-5-bromo-2-thiophenecarboxylate
  • Methyl 3-amino-5-phenyl-2-thiophenecarboxylate
  • Methyl 3-amino-4-methyl-2-thiophenecarboxylate hydrochloride (1:1 )
  • (2,3-Dihydro-1,4-benzoxathiin-2-yl)methanamine hydrochloride
  • (1R,2R)-2-(pyridin-4-yl)cyclopropane-1-carboxylic acid hydrochloride
  • 3-[Ethyl(2,2,2-trifluoroethyl)amino]propane-1-sulfonyl chloride hydrochloride
  • Sodium;(1R,2S)-2-imidazol-1-ylcyclohexane-1-carboxylate
  • Tert-butyl 5-(aminomethyl)-1,2-oxazole-3-carboxylate
  • 4-(3-Aminopiperidin-1-yl)benzoic acid dihydrochloride
  • 6-(6-Aminohexanamido)hexanoic acid dihydrochloride
  • 1-(2-Bromoethyl)-3,5-dimethyl-1H-pyrazole hydrobromide
  • 2-[4-(2-Methoxyacetamido)piperidin-1-yl]acetic acid
  • 1-(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)piperidin-4-yl dimethylcarbamate
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