Methyl 3-chloro-3-oxopropanoate
Suppliers
Names
[ CAS No. ]:
37517-81-0
[ Name ]:
Methyl 3-chloro-3-oxopropanoate
[Synonym ]:
Propanoic acid, 3-chloro-3-oxo-, methyl ester
Methyl (Chloroformyl)acetate
methyl chlorocarbonyl acetate
3-methoxy-3-oxopropanoyl chloride
METHYL CHLOROFORMYLACETATE
methyl-3-chlorooxopropionate
METHYL 3-CHLORO-3-OXOPROPIONATE
Methyl Malonyl Chloride
methyl 2-chloroformylacetate
(Chloroformyl)acetic Acid Methyl Ester
Methyl Malonyl chloride 25GR
MFCD00013657
methoxycarbonylacetyl chloride
EINECS 253-540-6
Methyl 3-chloro-3-oxopropanoate
Mehtyl Malonyl Chloride
3-Chloro-3-oxopropionic Acid Methyl Ester
Chemical & Physical Properties
[ Density]:
1.3±0.1 g/cm3
[ Boiling Point ]:
167.5±0.0 °C at 760 mmHg
[ Molecular Formula ]:
C4H5ClO3
[ Molecular Weight ]:
136.534
[ Flash Point ]:
80.0±0.0 °C
[ Exact Mass ]:
135.992722
[ PSA ]:
43.37000
[ LogP ]:
0.56
[ Vapour Pressure ]:
1.7±0.3 mmHg at 25°C
[ Index of Refraction ]:
1.425
[ Storage condition ]:
2-8°C
MSDS
Safety Information
[ Symbol ]:
GHS05, GHS07
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H314-H335
[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338-P310
[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
C:Corrosive;
[ Risk Phrases ]:
R34
[ Safety Phrases ]:
S26-S36/37/39-S45
[ RIDADR ]:
UN 3265 8/PG 2
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
8
[ HS Code ]:
2918300090
Synthetic Route
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2918300090
[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%
Articles
Beilstein J. Org. Chem. 8 , 371-8, (2012)
4-Cyano-1,1'-biphenyl derivatives bearing ω-hydroxyalkyl substituents were reacted with methyl 3-chloro-3-oxopropionate or cyanoacetic acid, giving liquid-crystalline linear malonates and cyanoacetate...
A general solid phase synthesis of 4-substituted quinolinones via Pd-catalyzed cross coupling. Xu C, et al.Tetrahedron Lett. 47(28) , 4885-88, (3006)
Solvent-free microwave-assisted Bingel reaction in carbon nanohorns. Economopoulos SP, et al.
J. Mater. Chem. 19(39) , 7326-31, (2009)