2,2',4'-Trichloroacetophenone

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Names

[ CAS No. ]:
4252-78-2

[ Name ]:
2,2',4'-Trichloroacetophenone

[Synonym ]:
A,2,4-TRICHLOROACETOPHENONE
MFCD00000934
ω,2,4-Trichloroacetophenone
2,4-dichlorophenyl chloromethyl ketone
EINECS 224-218-2
2,2',4'-trichloro acetophenone
TRICHLOROACETOPHENON
2,4,W-Trichloroacetophenon
2-Chloro-1-(2,4-dichlorophenyl)ethanone
2,4-Dichlorophenacyl Chloride
2,4-dichlorphenacylchloride
2,2',4'-Trichloroacetophenone
TRICHLOROACETOPHENONE
2,2,4,6-TETRACHLORO-2,2-DIHYDRO-1,3,5,2-TRIAZAPHOSPHORINE
Ethanone, 2-chloro-1-(2,4-dichlorophenyl)-
G1VR BG DG

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
292.2±25.0 °C at 760 mmHg

[ Melting Point ]:
47-54 °C(lit.)

[ Molecular Formula ]:
C8H5Cl3O

[ Molecular Weight ]:
223.484

[ Flash Point ]:
122.1±23.7 °C

[ Exact Mass ]:
221.940598

[ PSA ]:
17.07000

[ LogP ]:
2.97

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.565

[ Water Solubility ]:
60 mg/L (20 ºC)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H315-H317-H318-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R23/24/25;R34;R51/53

[ Safety Phrases ]:
S26-S36/37/39-S61-S45-S37/39

[ RIDADR ]:
1759

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
29147090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2',4'-Dichloroacetophenone
  • Chloroacetyl chloride
  • 1,3-Dichlorobenzene
  • 1-(2,4-Dichlorophenyl)ethanol
  • 2,2,2',4'-tetrachloroacetophenone
  • Aluminium chloride

DownStream

  • 2,4-Dichlorobenzoic acid
  • 1-(2,4-DICHLOROPHENYL)-2-(1H-IMIDAZOLE-1-YL) ETHANONE
  • 1H-Imidazolium,1,3-bis[2-(2,4-dichlorophenyl)-2-oxoethyl]-,chloride (9CI)
  • 2',4'-Dichloro-2-imidazole Acetophenone
  • 2',4'-Dichloroacetophenone
  • 4-(2,4-Dichlorophenyl)thiazol-2-amine
  • (Z)-2'-(1H-Imidazole-1-yl)-2,4-dichloroacetophenone oxime
  • 2-CHLORO-1-(2,4-DICHLOROPHENYL)ETHANOL
  • 1-(2,4-Dichlorophenyl)-2-(1H-imidazol-1-yl)ethanol
  • Isoconazole

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Glutathione-dependent reductive dehalogenation of 2,2',4'-trichloroacetophenone to 2',4'-dichloroacetophenone.

Biochem. Pharmacol. 31(23) , 3885-90, (1982)

alpha-Haloketones are highly reactive compounds, which are known to undergo enzymatic reduction to methyl ketones. The objective of this research was to characterize the enzymes involved in this react...

Clean and efficient microwave-solvent-free synthesis of 1-(2', 4'-dichlorophenacyl) azoles. Pérez ER, et al.

Tetrahedron 59(6) , 865-70, (2003)


More Articles

Related Compounds

  • 2-(2',4',6'-trinitrophenyl)-4,6-dinitrobenzotriazole 1-oxide
  • 2,2',4'-TRIHYDROXYCHALCONE
  • 2-(2',4'-dimethoxyphenyl)-1-phenylethan-1-one
  • 2-(2',4'-dimethoxyphenyl)-3-(4'-chlorophenyl)-1,2,3,4-tetrahydroquinazoline-4-one
  • 2-(2',4'-dichlorophenyl)-3-nitro-4-methyl pyridine
  • 2,2',4',5'-tetrachloroacetophenone