2-Amino-4-chlorophenol

Suppliers

Names

[ CAS No. ]:
95-85-2

[ Name ]:
2-Amino-4-chlorophenol

[Synonym ]:
EINECS 202-458-9
2-Amino-4-chlorophenol
5-Chloro-2-hydroxyaniline
Phenol, 2-amino-4-chloro-
MFCD00007694

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
276.8±25.0 °C at 760 mmHg

[ Melting Point ]:
136-141 °C(lit.)

[ Molecular Formula ]:
C6H6ClNO

[ Molecular Weight ]:
143.571

[ Flash Point ]:
121.2±23.2 °C

[ Exact Mass ]:
143.013794

[ PSA ]:
46.25000

[ LogP ]:
1.67

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.651

[ Water Solubility ]:
Insoluble.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SJ5700000
CHEMICAL NAME :
Phenol, 2-amino-4-chloro-
CAS REGISTRY NUMBER :
95-85-2
BEILSTEIN REFERENCE NO. :
0774859
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C6-H6-Cl-N-O
MOLECULAR WEIGHT :
143.58
WISWESSER LINE NOTATION :
ZR BQ EG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
690 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1030 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
333 ug/plate
REFERENCE :
EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 11(Suppl 12),1,1988 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82099 No. of Facilities: 28 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 168 (estimated)

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P301 + P312 + P330-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S36-S36/37/39

[ RIDADR ]:
UN 2673 6.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
SJ5700000

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
29222900

Synthetic Route

Precursor & DownStream

Precursor

  • 2-nitro-4-chlorophenol
  • Water
  • 4-Bromo-2-nitrophenol
  • 4-chloro-6-(phenylhydrazinylidene)cyclohexa-2,4-dien-1-one
  • 4-Chlorophenol
  • 5-Methyl-2-phenyl-1,2-dihydropyrazol-3-one
  • 3-Chlorophenol
  • (4-Chlorohydroxyphenyl)ammonium hydrogen sulphate

DownStream

  • 5-chloro-2-phenyl-1,3-benzoxazole
  • 2-Phenylbenzoxazole
  • 2-Naphthalenol,1-[2-(5-chloro-2-hydroxyphenyl)diazenyl]-
  • 8-Amino-2H-1,4-benzoxazin-3(4H)-one
  • 2,5-Dichlorobenzooxazole
  • 3-(5-chlorobenzoxazol-2-yl)-7-(diethylamino)-2-benzopyrone
  • 5-chloro-2-(2-phenylethyl)-1,3-benzoxazole
  • Propanamide, 2-chloro-N-(5-chloro-2-hydroxyphenyl)-
  • Phenol,4-chloro-2-[[(4-methoxyphenyl)methylene]amino]-
  • 4-(5-chloro-2-benzoxazolyl)Benzenamine

Customs

[ HS Code ]: 2922299090

[ Summary ]:
2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Metabolism of 4-chloro-2-nitrophenol in a gram-positive bacterium, Exiguobacterium sp. PMA.

Microb. Cell Fact. 11 , 150, (2012)

Chloronitrophenols (CNPs) are widely used in the synthesis of dyes, drugs and pesticides, and constitute a major group of environmental pollutants. 4-Chloro-2-nitrophenol (4C2NP) is an isomer of CNPs ...

A new way for synthesis of phenoxazine and diphenoxazine derivatives via electrochemical method.

Chem. Pharm. Bull. 59(10) , 1209-13, (2011)

Electrochemical oxidation of hydroquinone (1a) and 2,3-dimethylhydroquinone (1b) have been studied in the presence of 2-aminophenol (3a) and 2-amino-4-chlorophenol (3b), as nucleophiles in phosphate b...

Stability-indicating TLC-densitometric method for simultaneous determination of paracetamol and chlorzoxazone and their toxic impurities.

J. Chromatogr. Sci. 51(2) , 187-91, (2013)

A highly sensitive, selective and accurate thin-layer chromatographic (TLC)-densitometric method has been developed and validated for the simultaneous determination of paracetamol (PAR) and chlorzoxaz...


More Articles


Related Compounds

  • 2-Amino-4-chlorophenol
  • N-acetyl-2-amino-4-chlorophenol
  • 2-Amino-4-chlorophenol hydrochloride
  • 2-amino-4-chlorophenol-5-sulphonamide
  • 2-Amino-4-chlorophenol-6-sulfonic acid
  • 2-Amino-4-bromo-3-chlorophenol
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide
  • N-[3-(Aminooxy)propyl]-N-butyl-1-butanamine