methyl (phenylsulfinyl)acetate

Modify Date: 2024-01-21 08:44:13

methyl (phenylsulfinyl)acetate Structure
methyl (phenylsulfinyl)acetate structure
Common Name methyl (phenylsulfinyl)acetate
CAS Number 14090-83-6 Molecular Weight 198.23900
Density 1.29g/cm3 Boiling Point 130-131ºC0.5 mm Hg(lit.)
Molecular Formula C9H10O3S Melting Point 52-54ºC(lit.)
MSDS Chinese USA Flash Point 164.2ºC

 Names

Name methyl 2-(benzenesulfinyl)acetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.29g/cm3
Boiling Point 130-131ºC0.5 mm Hg(lit.)
Melting Point 52-54ºC(lit.)
Molecular Formula C9H10O3S
Molecular Weight 198.23900
Flash Point 164.2ºC
Exact Mass 198.03500
PSA 62.58000
LogP 1.83290
Vapour Pressure 8.15E-05mmHg at 25°C
Index of Refraction 1.584

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Safety Phrases S22-S24/25
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2930909090

 Synthetic Route

~10%

methyl (phenylsulfinyl)acetate Structure

methyl (phenyls...

CAS#:14090-83-6

Literature: Khodaei, Mohammad Mehdi; Bahrami, Kiumars; Arabi, Mehdi Sheikh Journal of Sulfur Chemistry, 2010 , vol. 31, # 2 p. 83 - 88

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methyl (phenylsulfinyl)acetate Structure

methyl (phenyls...

CAS#:14090-83-6

Literature: Journal of the American Chemical Society, , vol. 101, # 24 p. 7373 - 7379

~78%

methyl (phenylsulfinyl)acetate Structure

methyl (phenyls...

CAS#:14090-83-6

Literature: Shainyan, B. A.; Mirskova, A. N. Journal of Organic Chemistry USSR (English Translation), 1985 , vol. 21, # 2 p. 283 - 287 Zhurnal Organicheskoi Khimii, 1985 , vol. 21, # 2 p. 317 - 322

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methyl (phenylsulfinyl)acetate Structure

methyl (phenyls...

CAS#:14090-83-6

Literature: Tetrahedron, , vol. 57, # 48 p. 9669 - 9676

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methyl (phenylsulfinyl)acetate Structure

methyl (phenyls...

CAS#:14090-83-6

Literature: Tetrahedron Letters, , vol. 24, # 12 p. 1281 - 1284

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methyl (phenylsulfinyl)acetate Structure

methyl (phenyls...

CAS#:14090-83-6

Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 21, # 2 p. 283 - 287 Zhurnal Organicheskoi Khimii, , vol. 21, # 2 p. 317 - 322

~49%

methyl (phenylsulfinyl)acetate Structure

methyl (phenyls...

CAS#:14090-83-6

Literature: Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 45, p. 31 - 34

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methyl (phenylsulfinyl)acetate Structure

methyl (phenyls...

CAS#:14090-83-6

Literature: Polish Journal of Chemistry, , vol. 56, # 10-12 p. 1297 - 1312

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles3

More Articles

J. Chem. Soc. Perkin Trans. I , 2683, (1991)

Phase-Transfer Catalyzed Alkylative Elimination of Methyl 2-Phenylsulfinylacetate. A One-Pot Synthesis of Substituted Cinnamates. Chong-ying X, et al.

Synth. Commun. 17(15) , 1839-43, (1987)

New Synthetic reactions. Alkylative elimination. Trost BM, et al.

J. Am. Chem. Soc. 96(22) , 7165-67, (1974)

 Synonyms

MFCD00002087
methyl benzenesulfinylacetate
Methyl 2-phenylsulfinylacetate
EINECS 237-936-6
Methyl(phenylsulfinyl)acetate
DL-methyl (phenylsulfinyl)acetate
GNF-Pf-1921