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氯代二苯基膦

氯代二苯基膦用途

【用途一】
合成中锂化反应引入二苯基磷。

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氯代二苯基膦名称

[ CAS 号 ]:
1079-66-9

[ 中文名 ]:
二苯基氯化膦

[ 英文名 ]:
Chlorodiphenylphosphine

[中文别名 ]:

[英文别名 ]:

MFCD00000529
diphenylphosphine chloride
(C6H5)2PCl
chloro-diphenylphosphine
Diphenylphosphinous chloride
Phosphine,chlorodiphenyl
Diphenylphosphinchlorid
PH2PCL
Phosphinous chloride, P,P-diphenyl-
P-CHLORODIPHENYLPHOSPHINE

氯代二苯基膦物理化学性质

[ 密度 ]:
1.229 g/mL at 25 °C(lit.)

[ 沸点 ]:
320.0±11.0 °C at 760 mmHg

[ 熔点 ]:
14-16°C

[ 分子式 ]:
C₁₂H₁₀ClP

[ 分子量 ]:
220.635

[ 闪点 ]:
147.3±19.3 °C

[ 精确质量 ]:
220.020859

[ PSA ]:
13.59000

[ LogP ]:
5.33

[ 外观性状 ]:
透明至黄色液体

[ 蒸汽密度 ]:
7.8 (vs air)

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
n20/D 1.636(lit.)

[ 储存条件 ]:
Store at R.T.

[ 水溶解性 ]:
Reacts violently

氯代二苯基膦MSDS

氯代二苯基膦安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 补充危害声明 ]:
Reacts violently with water.

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R14;R29;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S8-S30-S25

[ 危险品运输编码 ]:
UN 3265 8/PG 2

[ WGK德国 ]:
2

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
29310095

氯代二苯基膦合成路线

氯代二苯基膦上下游产品

氯代二苯基膦上游产品

氯代二苯基膦下游产品

氯代二苯基膦海关

[ 海关编码 ]: 2931900090

[ 中文概述 ]:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

氯代二苯基膦文献

Lewis acidity enhancement of triarylborane by appended phosphine oxide groups.

Dalton Trans. 44(10) , 4765-72, (2015)

A series of mono-, di-, and tri-phosphine oxide substituted triarylboranes, Mes2BAr (1), MesBAr2 (2), and BAr3 (3) (Ar = 4-(Ph2PO)-2,6-Me2-C6H2) were prepared to investigate the effect of a phosphine ...

J. Chem. Soc. Perkin Trans. I , 1433, 2463, (1993)

Chem. Pharm. Bull. 41 , 1149, (1993)

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